Takeuchi Analytical Chemistry

Session Lectures Presented at the Twentysixth International Congress of Pure and Applied Chemistry, Tokyo, Japan, 4-10 September 1977
1. Auflage 2013
ISBN: 978-1-4831-5097-0
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 64 Seiten, Web PDF

26th International Congress of Pure and Applied Chemistry, Volume 3: Analytical Chemistry is a collection of session lectures presented at the 26th International Congress of Pure and Applied Chemistry, held in Tokyo, Japan on September 4-10, 1977. This book is divided into six chapters and begins with the features of the general purpose microcomputer data system, which is a cost-effective means to bring the power of machine intelligence to a wide variety of chemical instruments. The succeeding chapters deal with the application of sequential as kinetics by relaxation and correlation NMR spectroscopy and the design of chelating ligands for metal buffering in aqueous solution. These topics are followed by a discussion of the applications of collisional activation/mass spectrometry to ion and molecular structure determination and to the analysis of complex mixtures. The last chapter describes the advantages and limitations of atomic fluorescence spectroscopy as a trace metal analytical technique. This book is of great value to analytical and organic chemists, researchers, and students.

Autoren/Hrsg.

Takeuchi, T.

Inhaltsverzeichnis

1;Front Cover;1
2;Analytical Chemistry: Session lectures presented at the Twentysixth International Congress of Pure and Applied Chemistry Tokyo, Japan, 4-10 September 1977
;4
3;Copyright Page;5
4;Table of Contents;6
5;Chapter 1. GENERAL PURPOSE MICROCOMPUTERS IN LABORATORY AUTOMATION;8
5.1;Abstract;8
5.2;INTRODUCTION;8
5.3;DESIGN FEATURES;8
5.4;HARDWARE COMPONENTS;10
5.5;SOFTWARE DEVELOPMENT TECHNIQUES AND RESOURCES;13
5.6;APPLICATIONS;14
5.7;APPLICATIONS IN PROGRESS;20
5.8;Acknowledgement;22
5.9;REFERENCES;22
6;Chapter 2. SEQUENTIAL FAST KINETICS BY RELAXATION: APPLICATION IN CHEMISTRY AND BIOCHEMISTRY;24
6.1;Abstract;24
6.2;INTRODUCTION;24
6.3;PRINCIPLE OF TRANSIENT RELAXATION METHODS;25
6.4;LASER T-JUMP: PRINCIPLE AND APPLICATIONS2,3;26
6.5;INCREASING THE SENSITIVITY OF THE JOULE-HEATED T-JUMP SPECTROPHOTOMETER;28
6.6;CONCLUSION;34
6.7;Acknowledgement;35
6.8;REFERENCES;35
7;Chapter 3. CORRELATION NMR SPECTROSCOPY AND ITS APPLICATIONS;36
7.1;Abstract;36
7.2;1.Floating-point arithmetic;37
7.3;2.Tilted baseline problem;37
7.4;3.Minimum number of sampling points required;38
7.5;4.Measurements of spin-lattice relaxation times;38
7.6;5.Selective excitation of a weakly coupled non-equilibrium spin system;39
7.7;6.Application to non-invasive analysis of biological systems;40
7.8;REFERENCES;43
8;Chapter 4. CHELATING AGENTS FOR METAL BUFFERING AND ANALYSIS IN SOLUTION;44
8.1;Abstract;44
8.2;INTRODUCTION;44
8.3;LIGAND DESIGN;45
8.4;POLYAMINOPOLYCARBOXYLATES;47
8.5;VARIATION OF FUNCTIONAL GROUPS OF AMINOPOLYCARBOXYLATE LIGANDS;49
8.6;COUPLED BIDENTATE DONOR GROUPS;53
8.7;CATECHOLS;55
8.8;AMIDES AS COORDINATING LIGANDS;56
8.9;CONCLUSIONS;59
8.10;ABBREVIATIONS;59
8.11;Acknowledgement;59
8.12;REFERENCES;59
9;Chapter 5. CURRENT TOPICS IN ORGANIC MASS SPECTROMETRY;62
9.1;Abstract;62
9.2;INTRODUCTION;62
9.3;LIQUID CHROMATOGRAPHY/MASS SPECTROMETRY;62
9.4;COMPUTER IDENTIFICATION OF UNKNOWN MASS SPECTRA;63
9.5;COLLISIONAL ACTIVATION MASS SPECTROMETRY;64
9.6;Acknowledgment;65
9.7;REFERENCES;65
10;Chapter 6. SOME RECENT DEVELOPMENTS IN ATOMIC FLUORESCENCE SPECTROSCOPY;68
10.1;Abstract;68
10.2;SOURCES FOR FLUORESCENCE;71
10.3;ATOMIZERS FOR FLUORESCENCE;71
10.4;INSTRUMENTAL MODES OF FLUORESCENCE;72
10.5;REFERENCES;74