Sandler / Karo / Blomquist Organic Functional Group Preparations

1. Auflage 2013
ISBN: 978-1-4832-7563-5
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 510 Seiten, Web PDF

Organic Functional Group Preparations, Volume II describes 17 organic functional groups and presents a critical review of their available methods of synthesis with preparative examples of each. The book puts special attention to the presentation of specific laboratory directions for the many name reactions used in describing the synthesis of these functional groups. Each chapter deals with the preparation of a given functional group by various reaction types (condensation, elimination, oxidation, reduction) and a variety of starting materials. Ynamines, enamines, allenes, and N-nitroso compounds are some of the organic functional groups described in the text. Organic chemists will find the book invaluable.

Wolf Karo was a winner of the Westinghouse Science Talent Search. He holds a number of patents, and has been active in developing applications of monodispersed microspheres in diagnostic testing and other areas of biotechnology. Karo received his Ph.D. in Organic Chemistry from Cornell University.

Autoren/Hrsg.

Sandler, Stanley R.

Karo, Wolf

Blomquist, Alfred T.

Inhaltsverzeichnis

1;Front Cover
;1
2;Organic Functional Group Preparations;4
3;Copyright Page
;5
4;Table of Contents;6
5;Preface;10
6;Acknowledgments;12
7;Contents of Volume I;14
8;Chapter 1. ALLENES;18
8.1;1. Introduction;19
8.2;2. Elimination Reactions;20
8.3;3. Rearrangement Reactions;30
8.4;4. Miscellaneous Methods;51
8.5;References;52
9;Chapter 2.
ORTHO ESTERS;58
9.1;1. Introduction;58
9.2;2. Alcoholysis Reactions;60
9.3;3. Condensation Reactions;72
9.4;4. Elimination Reactions;77
9.5;5. Reduction Reactions;78
9.6;6. Miscellaneous Methods;79
9.7;References;81
10;Chapter 3.
SULFITES;86
10.1;1. Introduction;86
10.2;2. Condensation Reactions;87
10.3;3. Miscellaneous Methods;98
10.4;References;98
11;Chapter 4.
ENAMINES;100
11.1;1. Introduction;100
11.2;2. Condensation Reactions;103
11.3;3. Elimination Reactions;120
11.4;4. Oxidation Reactions;123
11.5;5. Reduction Reactions;127
11.6;6. Miscellaneous Methods;129
11.7;References;130
12;Chapter 5.
YNAMINES;136
12.1;1. Introduction;136
12.2;2. Condensation Reactions;138
12.3;3. Elimination Reactions;143
12.4;4. Oxidation Reactions;146
12.5;5. Rearrangement Reactions;147
12.6;6. Miscellaneous Reactions;148
12.7;References;149
13;Chapter 6.
UREAS;151
13.1;1. Introduction;152
13.2;2. Condensation Reactions;152
13.3;3. Oxidation Reactions;174
13.4;4. Miscellaneous Methods;178
13.5;References;180
14;Chapter 7.
PSEUDOUREAS;183
14.1;1. Introduction;183
14.2;2. Condensation Reactions;186
14.3;3. Miscellaneous Methods;200
14.4;References;200
15;Chapter 8.
SEMICARBAZIDES;203
15.1;1. Introduction;203
15.2;2. Condensation Reactions;205
15.3;3. Reactions of Carbamic Acid Derivatives to Give Semicarbazides;215
15.4;4. Reduction Methods;216
15.5;5. Miscellaneous Methods;218
15.6;References;219
16;Chapter 9.
CARBODIIMIDES;222
16.1;1. Introduction;222
16.2;2. Elimination Reactions;224
16.3;3. Oxidation Reactions;232
16.4;4. Miscellaneous Methods;236
16.5;References;237
17;Chapter 10. N-CARBAMATES (URETHANES);240
17.1;1. Introduction;240
17.2;2. Condensation Reactions;241
17.3;3. Miscellaneous Reactions of Isocyanates and Alcohols;250
17.4;4. Miscellaneous Methods of Preparing Urethanes (N-Carbamates);250
17.5;References;250
18;Chapter 11. O-CARBAMATES;252
18.1;1. Introduction;252
18.2;2. Condensation Reactions;253
18.3;3. Miscellaneous Methods;261
18.4;References;261
19;Chapter 12.
IMINES;263
19.1;1. Introduction;263
19.2;2. Condensation Reactions;272
19.3;3. Reduction Reactions;278
19.4;4. Oxidation Reactions;278
19.5;5. Miscellaneous Methods;279
19.6;References;282
20;Chapter 13.
AZIDES;285
20.1;1. Introduction;285
20.2;2. Condensation Reactions;286
20.3;3. Miscellaneous Methods;299
20.4;References;299
21;Chapter 14.
AZO COMPOUNDS;302
21.1;1. Introduction;303
21.2;2. Condensation Reactions;308
21.3;3. Reduction Reactions;330
21.4;4. Oxidation Reactions;337
21.5;5. Isomerization Reactions;348
21.6;6. Miscellaneous Procedures;351
21.7;References;355
22;Chapter 15.
AZOXY COMPOUNDS;360
22.1;1. Introduction;361
22.2;2. Elimination Reactions;364
22.3;3. Oxidation Reactions;371
22.4;4. Reduction Reactions;384
22.5;5. Isomerization Reactions;391
22.6;6. Miscellaneous Preparations;392
22.7;References;398
23;Chapter 16.
C-NITROSO COMPOUNDS;400
23.1;1. Introduction;401
23.2;2. Condensation Reactions;405
23.3;3. Oxidation Reactions;423
23.4;4. Reduction Reactions;435
23.5;5. Miscellaneous Preparations;435
23.6;References;438
24;Chapter 17. N-NITROSO COMPOUNDS;441
24.1;1. Introduction;442
24.2;2. N-Nitrosoamines;443
24.3;3. N-Nitrosoamides;451
24.4;4. N-Nitrosolactams;456
24.5;5. N-Nitrosoureas;458
24.6;6. N-Nitroso-N-alkylurethanes (Alkyl N-Nitroso-N-alkylcarbamates);458
24.7;7. N-Nitroso-2-oxazolidones;459
24.8;8. 1-Nitroso-3-nitroguanidines;460
24.9;9. N-Nitrososulfonamides;461
24.10;10. N-Nitrosohydrazine Derivatives;462
24.11;11. N-Nitrosoketimines;462
24.12;12. N-Nitrosohydroxylamines;464
24.13;References;465
25;Author Index;468
26;Name Reaction Index;498
27;Subject Index;499
28;ORGANIC CHEMISTRY: A SERIES OF MONOGRAPHS;510