Rowlinson / Swinton / Perlmutter Liquids and Liquid Mixtures

Butterworths Monographs in Chemistry
3. Auflage 2013
ISBN: 978-1-4831-4067-4
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 336 Seiten, Web PDF

Liquids and Liquid Mixtures, Third Edition explores the equilibrium properties of liquids and liquid mixtures and relates them to the properties of the constituent molecules using the methods of statistical thermodynamics. Topics covered include the critical state, fluid mixtures at high pressures, and the statistical thermodynamics of fluids and mixtures. This book consists of eight chapters and begins with an overview of the liquid state and the thermodynamic properties of liquids and liquid mixtures, including vapor pressure and heat capacities. The discussion then turns to the thermodynamics of and inequalities at the critical point; measurement of thermodynamic functions in the critical region; experimental values of the critical exponents; and scaling of the free energy. The change of thermodynamic functions with composition is the subject of the next two chapters, followed by an analysis of fluid mixtures at high pressures. The final chapter is devoted to the statistical thermodynamics of fluids and mixtures, paying particular attention to the thermodynamic properties in terms of the forces between the molecules; the balance of intermolecular potentials between like and unlike molecules; and phase behavior. This monograph will be of interest to students and researchers in the fields of chemistry and chemical engineering.

Autoren/Hrsg.

Rowlinson, J S

Swinton, F L

Perlmutter, Patrick

Buckingham, A D

Danishefsky, S.

Inhaltsverzeichnis

1;Front Cover;1
2;Liquids and Liquid Mixtures;4
3;Copyright Page;5
4;Table of Contents;8
5;Preface to the Third Edition;6
6;Chapter 1. Introduction;10
6.1;1.1 The liquid state;10
6.2;References;19
7;Chapter 2. The thermodynamic properties;20
7.1;2.1 Summary of thermodynamic relations;20
7.2;2.2 Vapour pressure;28
7.3;2.3 Mechanical properties;33
7.4;2.4 Heat capacities;38
7.5;2.5 Adiabatic properties;41
7.6;2.6 Residual and configurational properties;56
7.7;2.7 van der Waals's equation;60
7.8;References;63
8;Chapter 3. The critical state;68
8.1;3.1 Thermodynamics of the critical point;68
8.2;3.2 Inequalities at the critical point;74
8.3;3.3 The measurement of critical constants;79
8.4;3.4 Experimental values of the critical exponents;84
8.5;3.5 Scaling the free energy;86
8.6;References;93
9;Chapter 4. The thermodynamics of liquid mixtures;95
9.1;4.1 Introduction;95
9.2;4.2 Partial molar quantities;96
9.3;4.3 The ideal mixture;101
9.4;4.4 Thermodynamics of non-ideal mixtures;107
9.5;4.5 Tests for consistency;110
9.6;4.6 Azeotropy;113
9.7;4.7 Fields and densities;119
9.8;4.8 Thermodynamics of partially miscible liquids;124
9.9;4.9 Exponents at the critical point of a binary mixture;128
9.10;4.10 Tricritical points;131
9.11;References;138
10;Chapter 5. Excess thermodynamic functions;141
10.1;5.1 Introduction;141
10.2;5.2 The experimental determination of excess functions;142
10.3;5.3 Mixtures of condensed gases;149
10.4;5.4 Liquefied natural-gas mixtures;154
10.5;5.5 Mixtures of the higher hydrocarbons;158
10.6;5.6 Mixtures containing halides;163
10.7;5.7 Mixtures containing fluorocarbons;167
10.8;5.8 Mixtures containing polar liquids;171
10.9;5.9 Aqueous mixtures;183
10.10;5.10 Mixtures of quantum liquids;188
10.11;References;189
11;Chapter 6. Fluid mixtures at high pressures;200
11.1;6.1 Introduction;200
11.2;6.2 Gas–liquid critical states of binary mixtures;204
11.3;6.3 High-pressure phase equilibria: type I mixtures;212
11.4;6.4 High-pressure phase equilibria: type II and type VI mixtures;216
11.5;6.5 High-pressure phase equilibria: type III mixtures;222
11.6;6.6 High-pressure phase equilibria: type IV and type V mixtures;230
11.7;References;235
12;Chapter 7. The statistical thermodynamics of fluids;239
12.1;7.1 Intermolecular forces;239
12.2;7.2 Molecular distribution functions;241
12.3;7.3 Molecular correlation functions;246
12.4;7.4 The measurement and calculation of correlation functions;252
12.5;7.5 The principle of corresponding states;270
12.6;7.6 Perturbation theories: spherical molecules;275
12.7;7.7 Perturbation theories: non-spherical molecules;279
12.8;References;283
13;Chapter 8. The statistical thermodynamics of mixtures;288
13.1;8.1 Introduction;288
13.2;8.2 Ideal and random mixtures;288
13.3;8.3 Mixtures of spheres;293
13.4;8.4 The van der Waals approximation;295
13.5;8.5 Perturbation theories of mixtures of spherical molecules;297
13.6;8.6 Excess functions of simple mixtures;300
13.7;8.7 Mixtures of alkanes;307
13.8;8.8 Perturbation theories of mixtures of non-spherical molecules;309
13.9;8.9 Phase equilibria at high pressures;312
13.10;8.10 Conclusions;321
13.11;References;322
14;General index;326
15;Index of systems;332