Ross / Finkelstein / Rudd Anodic Oxidation

Organic Chemistry: A Series of Monographs, Vol. 32
1. Auflage 2013
ISBN: 978-1-4832-1986-8
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 352 Seiten, Web PDF

Anodic Oxidation covers the application of the concept, principles, and methods of electrochemistry to organic reactions. This book is composed of two parts encompassing 12 chapters that consider the mechanism of anodic oxidation. Part I surveys the theory and methods of electrochemistry as applied to organic reactions. These parts also present the mathematical equations to describe the kinetics of electrode reactions using both polarographic and steady-state conditions. Part II examines the anodic oxidation of organic substrates by the functional group initially attacked. This part particularly emphasizes the kinds of intermediates generated and the mechanisms leading to final products. This book is intended primarily to organic chemists and physical electrochemists.

Autoren/Hrsg.

Ross, Sidney D.

Finkelstein, Manuel

Rudd, Eric J.

Blomquist, Alfred T.

Wasserman, Harry H.

Inhaltsverzeichnis

1;Front Cover
;1
2;Anodic Oxidation;4
3;Copyright Page
;5
4;Table of Contents
;6
5;Preface;10
6;Part I: Principles and Methods
;12
6.1;Chapter 1. An Introduction to the

Electrochemical Reaction;14
6.1.1;I. Electrolysis and Its Terminology;14
6.1.2;II. Faraday and the Laws of Electrolysis
;15
6.1.3;.II. How Is the Electric Current Carried through the Cell?
;16
6.1.4;IV. The Electrochemical Reaction—A Simple Picture;17
6.1.5;V. A Most Important Factor—The Electrode Potential;17
6.1.6;VI. The Origin and Significance of the Electrode Potential
;18
6.1.7;VII. The Sign of the Electrode Potential;21
6.1.8;VIII. Thermodynamics of Electrode Potential
;22
6.1.9;IX. Reversiblity and Irreversibility;23
6.1.10;X. The Electrical Double Layer;24
6.1.11;XI. Adsorption at the Electrode-Solution Interface;27
6.1.12;.II. A General Representation of an Electrochemical Reaction
;29
6.1.13;References;32
6.2;Chapter 2. The Current—Potential Relationship
;34
6.2.1;I. The Rate of an Electrode Reaction—A Logical Place to Begin
;35
6.2.2;II. The Polarographic Method
;36
6.2.3;.II
. Reactions under Activation-Controlled Conditions;43
6.2.4;References;55
6.3;Chapter 3. Other Electrochemical Methods
;57
6.3.1;I. Transient Behavior at the Electrode Surface;58
6.3.2;II
. Coulometric Studies and Preparative Methods;67
6.3.3;References;72
6.4;Chapter 4. The Electrochemical Reaction— Practical Aspects
;74
6.4.1;I. Cells and Circuits—The Two-Electrode Cell;74
6.4.2;II
. Cells and Circuits—The Three-Electrode Cell;76
6.4.3;.II. Cells for Electrolysis
;78
6.4.4;IV. The Working Electrode;78
6.4.5;V. Electrode Construction;79
6.4.6;VI. The Counter or Auxiliary Electrode;81
6.4.7;VII
. Reference Electrodes in Aqueous Solutions;81
6.4.8;VIII . Reference Electrodes in Nonaqueous Solutions
;83
6.4.9;IX. Solvents;84
6.4.10;X. Supporting Electrolytes;87
6.4.11;References;88
7;Part II: A Survey of Anodic Oxidations
;90
7.1;Chapter 5. Hydrocarbons
;92
7.1.1;I. Introduction;92
7.1.2;II. Substituted Benzenes;93
7.1.3;.II. Anthracenes
;110
7.1.4;IV. Aryl Olefins;123
7.1.5;V. Aliphatic and Alicyclic Hydrocarbons;128
7.1.6;References;141
7.2;Chapter 6. The Kolbe Acid Oxidation: Radical Reactions
;145
7.2.1;I. Introduction;145
7.2.2;II. Experimental Conditions
;146
7.2.3;III. Side Reactions;147
7.2.4;IV. Scope and Limitations;147
7.2.5;V. Mechanism;150
7.2.6;References;164
7.3;Chapter 7. The Kolbe Acid Oxidation: Carbonium Ion Reactions
;167
7.3.1;References;198
7.4;Chapter 8. Amines
;200
7.4.1;I. Aromatic Amines;200
7.4.2;II. Aliphatic Amines;222
7.4.3;References;230
7.5;Chapter 9. Amides
;234
7.5.1;References;249
7.6;Chapter 10. Hydrazines and Related Compounds
;250
7.6.1;I. Hydrazines;250
7.6.2;II. Semicarbazides;267
7.6.3;III. Hydrazones;269
7.6.4;References;271
7.7;Chapter 11. Alcohols and Phenols ;273
7.7.1;I. Alcohols;273
7.7.2;II
. Phenols;282
7.7.3;References;303
7.8;Chapter 12. Ethers;306
7.8.1;I. Aliphatic Ethers;306
7.8.2;II. Aromatic Ethers
;316
7.8.3;References;330
8;Author Index;332
9;Subject Index;345