J. Edwards,WorksofJonathanEdwards(BannerofTruthTrust,Edinburgh,1979) v vi Preface operations. Thenusingsimplegrouptheoryprocedures,thephysicalpropertiesof thecrystalcanbedetermined. Duringthe45yearsIhavebeeninvolvedinteachingandresearchinvarious areasofsolidstatephysics,Ihavemadeextensiveuseoftheconceptsofgroup theory. YetIhavebeensurprisedathowlittleemphasisthistopicreceivesinany formaleducationalcurriculum. Generally,astudentstudyingsolidstatephysicsor chemistrywillbeexposedtocrystalstructuresearlyinthesemesterandthenhave nofurtherexposuretocrystalsymmetryuntilsomespecialtopicsuchasnonlinear opticsisdiscussed. Thisbookfocusesonthesymmetryofcrystalsandthedescr- tionofthissymmetrythroughtheuseofgrouptheory. Althoughspeci?cexamples are provided of using this formalism to determine both the microscopic and macroscopicpropertiesofmaterials,theemphasisisonthecomprehensive,per- sivenatureofsymmetryinallareasofsolidstatescience. Theintentofthebookistobeareferencesourceforthosedoingresearchor teachinginsolidstatescienceandengineering,oratextforaspecialtycoursein grouptheoryappliedtothepropertiesofcrystals. Tucson,AZ RichardC. Powell June2010 Contents 1 SymmetryinSolids. 1 1. 1 Symmetry. 1 1. 2 CrystalStructures. 4 1. 3 SymmetryinReciprocalSpace. 15 1. 4 Problems. 24 References. 24 2 GroupTheory. 25 2. 1 BasicConceptsofGroupTheory. 27 2. 2 CharacterTables. 31 2. 3 GroupTheoryExamples. 40 2. 3. 1 C PointGroup. 40 3v 2. 3. 2 O PointGroup. 45 h 2. 4 GroupTheoryinQuantumMechanics. 47 2. 5 Problems. 52 References. 53 3 TensorPropertiesofCrystals. 55 3. 1 First-RankMatterTensors. 57 3. 2 Second-RankMatterTensors. 62 3. 3 Third-RankMatterTensors. 68 3. 4 Fourth-RankMatterTensors. 73 3. 5 Problems. 77 References. 77 4 SymmetryPropertiesofPointDefectsinSolids. 79 4. 1 EnergyLevelsofFreeIons. 79 4. 2 CrystalFieldSymmetry. 85 4. 3 EnergyLevelsofIonsinCrystals. 87 vii viii Contents 4. 4 Example:d?Electrons. 95 4. 5 Example:f-Electrons. 100 4. 6 Problems. 104 References. 104 5 SymmetryandtheOpticalPropertiesofCrystals.
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Symmetry in Solids.- Group Theory.- Tensor Properties of Crystals.- Symmetry Properties of Point Defects in Solids.- Symmetry and the Optical Properties of Crystals.- Nonlinear Optics.- Symmetry and Lattice Vibrations.- Symmetry and Electron Energy Levels.
I. Symmetry in Solids
II. Group Theory
III. Tensor Properties of Crystals
IV. Symmetry Properties of Point Defects in Solids
V. Symmetry and the Optical Properties of Solids
VI. Nonlinear Optics
VII. Symmetry and Lattice Vibrations
VIII. Symmetry and Electron Energy Levels