Advances in Heterocyclic Chemistry

Erscheinungsjahr 1999
ISBN: 978-0-12-020774-9
Verlag: ACADEMIC PR INC

Buch, Englisch, Band 74, 253 Seiten, Format (B × H): 162 mm x 237 mm, Gewicht: 544 g

Reihe: Advances in Heterocyclic Chemi

Established in 1960, Advances in Heterocyclic Chemistry is the definitive serial in the area--one of great importance to organic chemists, polymer chemists, and many biological scientists. Written by established authorities in the field, the comprehensive reviews combine descriptive chemistry and mechanistic insight to yield an understanding of how the chemistry drives the properties.Degenerate ring transformations of heterocycles are classified as reactions in which a heterocyclic system is converted into the same heterocyclic system. This monograph covers an authoritative, comprehensive overview of a host of degenerate ring transformations in five- and six-membered heterocycles. It shows how by the use of 15N-labeled, 13C-labeled, or selectively substituted compounds these degenerate rign transformations can be discovered and how most of the results can be explained by the Addition Nucleophile, Ring Opening, and Ring Closure [ANRORC] mechanism. Another main topic of the monograph is the occurrence of degenerate ring transformations.

Zielgruppe

Organic chemists, pharmacologists, medicinal chemists, photographic chemists, and agrochemists.

Autoren/Hrsg.

Plas, Henk C. van der

Katritzky, Alan R.

Weitere Mitwirkende

van der Plas, Henk C.

Fachgebiete

• Naturwissenschaften Chemie Organische Chemie Supramolekularchemie
• Naturwissenschaften Chemie Analytische Chemie Umweltchemie, Lebensmittelchemie
• Naturwissenschaften Chemie Organische Chemie Polymerchemie
• Naturwissenschaften Chemie Organische Chemie Biochemie

Inhaltsverzeichnis

Introduction. SN (ANRORC) Reactions in Azines, Containing an "Outside" Leaving Group. SN (ANRORC) Reactions in Azaheterocycles, Containing an "Inside" Leaving Group. Degenerate Ring Transformations by Side-Chain Participation.

Über Autor(innen)

van der Plas, Henk C.
Professor Dr. H.C. van der Plas received his Ph.D. from the University of Amsterdam. He has served the Agricultural University at Wageningen, The Netherlands, from 1966 as a Reader, from 1970 as Professor of Organic Chemistry, and from 1978-1982 and 1989-1995 as Rector Magnificus. His research interest is in chemistry, mainly in the field of nucleophilic substitution and ring transformations. The results of his scientific results are set down in nearly 400 research papers, 20 review articles, and in two monographs, and a book (together with O. Chupakhin and V. Charushin), Nucleophilic Substitution of Aromatic Hydrogen.