Buch, Englisch, 654 Seiten, Format (B × H): 216 mm x 279 mm, Gewicht: 1088 g
Buch, Englisch, 654 Seiten, Format (B × H): 216 mm x 279 mm, Gewicht: 1088 g
ISBN: 978-0-87371-268-2
Verlag: CRC Press
By and for engineers and scientists, this comprehensive book covers all aspects of metals chemistry, separation chemistry, and metals separation processes. State-of-the-art papers give news and recent developments and future research needs, of special value and interest to persons from industry, academia, government agencies, commercial and research institutes, information centers and libraries. This valuable work is the complete proceedings of the Metals Speciation, Separation and Recovery International Symposium sponsored by the Industrial Waste Elimination Research Center at the Illinois Institute of Technology, Chicago, Illinois, and the Water Research Institute of the Italian National Research Council, Rome, Italy, held in Rome, May 14-19, 1989. The book will be about 800 pages replete with drawings, tables, and charts helpful to understanding and use of the information presented. Written by some 50 specialists from leading institutions and companies from Europe, Asia, North and Latin America, choice information and data in this valuable new volume are organized into seven major parts: One: Chemistry of Toxic Metals; Two: Precipitation Phenomena; Three: Metal Speciations and Complexation in Natural Systems; Four: Sorption Onto Surfaces; Five: Ion Separation; Six: Soils Contamination and Decontamination; Seven: Waste Reduction and Recovery Case Studies. Index.
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KEYNOTE PAPERS. Cycles, Fluxes and Speciation of Trace Metals in the Environment. Metals Control Technology; Past, Present, and Future. PART I: CHEMISTRY OF TOXIC METALS. METALS SPECIATION IN SLUDGES FROM WASTEWATERS TREATMENT BY BULK AND SURFACE (XPS) ANALYSIS. Abstract. Introduction. X-Ray Photoelectron Spectroscopy. Samples Treatment and Experimental Techniques. Results and Discussion. Conclusions. Acknowledgments. References. Discussion. CHEMICAL EQUILIBRIUM ANALYSIS OF LEAD AND BERYLLIUM SPECIATION IN HAZARDOUS WASTE INCINERATORS. Introduction. Metal Transformations in Incineration Systems. Metals Emissions from Incinerators. Modeling Approach. Model Simulations and Analysis. Conclusions. References. Discussion. NUCLEATION AND CRYSTAL GROWTH STUDIES ON PRECIPITATION OF CADMIUM HYDROXIDE FROM AQUEOUS SOLUTIONS. Abstract. Introduction. Background. Experimental. Results and Discussion. Conclusions. Acknowledgments. References. Discussion. EFFECT OF SPECIATION ON THE RATES OF OXIDATION OF METALS. Introduction. Background. Effect of pH on the Rates of Oxidation. Effect of the Major Ionic Components of Natural Waters on the Rates of Oxidation. Acknowledgments. References. Discussion. PART II: PRECIPITATION PHENOMENA. EXPERIMENTS ON THE SIMULTANEOUS OXIDIZING EXTRACTION PROCESS OF Fe(II). Summary. Introduction. Experimental Methods. Experimental Results and Discussion. Symbols. References. Discussion. HYDROLYSIS, PRECIPITATION AND AGING OF COPPER (II) IN THE PRESENCE OF NITRATE. Introduction. Background. Experimental. Results and Discussion. Summary and Conclusions. Acknowledgments. References. Discussion. ROLE OF COPPER COMPLEXATION ON TREATMENT EFFICIENCY AND DESIGN OF TWO INDUSTRIAL WASTESTREAMS. Abstract. Introduction. Some Theoretical Considerations. Results and Discussion. Conclusions. References. Discussion. PART III: METAL SPECIATION AND COMPLEXATION IN NATURAL SYSTEMS. SPECIATION OF ALUMINUM IN GEOTHERMAL BRINES: COMPARISON OF DIFFERENT METHODOLOGIES. Summary. Introduction. Experimental. Results and Discussion. Conclusions. References. Discussion. SPECIATION OF TIN IN SEDIMENTS OF ARCACHON BAY (FRANCE). Introduction. Material and Methods. Results and Discussion. Conclusions. References. Discussion. METAL COMPLEXATION BY WATER-SOLUBLE ORGANIC SUBSTANCES IN FOREST SOILS. Abstract. Introduction. Metal-Complexing Capacity of Leaf-Litter Leachates. Metal-Solubilization from Forest Soils by the Litter Leachates. Discussion. Acknowledgments. References. Discussion. THEORETICAL AND EXPERIMENTAL DRAWBACKS IN HEAVY METAL SPECIATION IN NATURAL WATERS. Introduction. The Biological Problem. The Chemical Problem. Conclusions. Acknowledgments. References. Discussion. PART IV: SORPTION ONTO SURFACES. PROTON AND METAL ION BINDING ON HUMIC SUBSTANCES. Abstract. Introduction. The Mono-Component Proton Adsorption Isotherm. Calculation of Qi,H(pH5) Curves from Experimental Proton Adsorption Data for Humic and Fulvic Acids. Metal-Ion Adsorption. Conclusions. Acknowledgments. References. Discussion. POLYELECTROLYTIC METAL IONS SEQUESTRANTS. Introduction. Results and Discussion. Concluding Remarks. Experimental. Acknowledgments. References. Discussion. CHEMICAL SPECIATION OF HEAVY METALS IN SOILS FOLLOWING LAND APPLICATION OF CONDITIONED BIOLOGICAL SLUDGES AND RAW PIG MANURE. Introduction. Preliminary Investigation. Heavy Metals in Agricultural Soil. Materials and Methods. Results and Discussion. Conclusions. References. Discussion. PART V: ION SEPARATION. A PROCESS TO IMPROVE THE REGENERATED EFFLUENT CONCENTRATION OF ION EXCHANGE. Introduction. Background. Limit Regenerated Effluent Concentration Theory. Step-by-Step Regeneration Process. Experimental Results. Conclusions. Acknowledgments. References. Discussion. HEAVY METAL REMOVAL USING NATURAL ZEOLITE. Introduction. Theoretical Aspects of the Ion Exchange Process. Experimental Procedure. Results. Discussion. Concluding Remarks. References. Discussion. METAL ION SEPARATIONS FROM HAZARDOUS W