Parry / Kodama Boron Chemistry - 4

Plenary and Session Lectures Presented at the Fourth International Meeting on Boron Chemistry, Salt Lake City and Snowbird, Utah, USA, 9-13 July 1979
1. Auflage 2017
ISBN: 978-1-4831-5664-4
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 170 Seiten, Web PDF

Boron Chemistry - 4 covers the proceedings of the Fourth International Meeting on Boron Chemistry. The book contains invited plenary lectures and session lectures given during the conference. The text discusses several topics concerning boron chemistry, such as conceptual advances in boron chemistry; cluster compounds and carboranes; and organometallic compounds containing boron ligands, boron clusters, or carboranes. This monograph also explains boranes as reagents in organic chemistry; organoboranes; chemistry of smaller boranes; and applications of the boranes. This book will be of great interest to researchers whose line of work involves a certain aspect of boron.

Autoren/Hrsg.

Parry, Robert W.

Kodama, Goji

Inhaltsverzeichnis

1;Front Cover;1
2;Boron Chemistry — 4;4
3;Copyright Page;5
4;Table of Contents;6
5;Organizing Committee;7
6;PREFACE;8
7;ACKNOWLEDGEMENTS;9
8;CHAPTER 1.
BORON COMPOUNDS: TOPICS, 1979;10
8.1;Abstract;10
8.2;INTRODUCTION;10
8.3;ORBITAL CONTROL AND SYMMETRY CROSSING;10
8.4;CLASSICAL INTERMEDIATES;11
8.5;VACANCY STRUCTURES AND EXPANSION;13
8.6;LOCALIZED BONDS;14
8.7;HYDROBORATION;16
8.8;ELECTRON DENSITIES FROM X-RAY DIFFRACTION;16
8.9;Acknowledgement;17
8.10;REFERENCES;18
9;CHAPTER 2.
BORANE CLUSTERS, METAL CLUSTERS,AND CATALYSIS;20
9.1;Abstract;20
9.2;INTRODUCTION;20
9.3;DISCUSSION;22
9.4;CONCLUSIONS;30
9.5;Acknowledgements;30
9.6;REFERENCES;30
10;CHAPTER 3.
PATTERNS IN CLUSTER CHEMISTRY: BORANES AS MODEL SYSTEMS;32
10.1;Abstract;32
10.2;REFERENCES;40
11;CHAPTER 4.
FROM SODIUM BOROHYDRIDE TO 1,2-DICARBA-cIoso-DODECABORANES;42
11.1;Abstract;42
11.2;INTRODUCTION;42
11.3;RESULTS AND DISCUSSION;42
11.4;REFERENCES;48
12;CHAPTER 5. B-METALLATED DICARBA-closo- DODEGABORANES(12);50
12.1;ABSTRACT;50
12.2;INTRODUCTION.;50
12.3;RESULTS AND DISCUSSION;50
12.4;REFERENCES;56
13;CHAPTER 6.
SOME ASPECTS OF ORGANOBORATE CHEMISTRY;58
13.1;References.;79
14;CHAPTER 7.
REGENT ADVANCES IN THE CHEMISTRY OF PENTABORANE(9);82
14.1;Abstract;82
14.2;INTRODUCTION;82
14.3;ISOMERIZATION OF B5H9 DERIVATIVES;83
14.4;REACTIONS OF THE B5H8 ANION;84
14.5;TRANSITION METAL COMPLEXES;85
14.6;BERYLLIUM-PENTABORANE CHEMISTRY;86
14.7;Acknowledgement;87
14.8;REFERENCES;87
15;CHAPTER 8.
SYNTHESES AND REACTIONS OF CYCLIC DIBORAETHENE COMPOUNDS;90
15.1;Abstract;90
15.2;INTRODUCTION;90
15.3;SYNTHESES OF CYCLIC DIBORAETHENES;91
15.4;REACTIONS OF THE DIBORAETHENE HETEROCYCLES;92
15.5;Acknowledqement;102
15.6;REFERENCES;102
16;CHAPTER 9.
SOME PHYSICAL AND CHEMICAL CONSEQUENCES OF THE IRON TRICARBONYL FRAGMENT IN BORANE CAGES;104
16.1;Abstract;104
16.2;INTRODUCTION;104
16.3;MONOFERRABORANES;106
16.4;DIFERRABORANES;113
16.5;CONCLUSIONS;115
16.6;REFERENCES;115
17;CHAPTER 10.
PREPARATIVE AND MECHANISTIC STUDIES ON SIMPLE AND HETEROCYCLIC BORON COMPOUNDS;118
17.1;Abstract;118
17.2;REACTIONS OF BORON HETEROCYCLES;118
17.3;SILYLBORANES;124
17.4;TRIBORYLAMINES;126
17.5;REFERENCES;127
18;CHAPTER 11. SYNTHESIS AND BIOLOGICAL ACTIVITY OF BORON ANALOGUES OF THE a-AMINO ACIDS AND RELATED COMPOUNDS;128
18.1;ABSTRACT;128
18.2;INTRODUCTION;128
18.3;APPROACHES TO THE SYNTHESIS OF BORON ANALOGUES OF THE a-AMINO ACIDS;129
18.4;SYNTHESIS OF AMINE-CYANOBORANES;131
18.5;SYNTHESIS OF AMINE-CARBOXYBORANES;132
18.6;STUDIES OF BIOLOGICAL ACTIVITY;133
18.7;BORON ANALOGUE OF GLYCINE AND N-METHYL DERIVATIVES;134
18.8;CONCLUSION;137
18.9;Acknowledgement;137
18.10;REFERENCES;137
19;CHAPTER 12.
"NON-CLASSICAL" CARBOCATIONS—ISOELECTRONIC AND ISOSTRUCTURAL CARBON COPIES OF POLYBORANES; CONSERVATION OF CHEMICAL SHIFT;140
19.1;Abstract;140
19.2;INTRODUCTION;140
19.3;DISCUSSION;143
19.4;CONCLUSIONS;154
19.5;Acknowledgment;155
19.6;APPENDIX I. The conservation of chemical shift;155
19.7;APPENDIX II.The ethyl cation C2H5+;157
19.8;REFERENCES;158
20;CHAPTER 13.
Professor Anton Burg;160
21;CHAPTER 14.
BORON HYDRIDES: PERSPECTIVE AND PROSPECT;162
21.1;Abstract;162
21.2;INORGANIC CHEMISTRY FIFTY YEARS AGO;162
21.3;THE GREAT PIONEER,STOCK;163
21.4;TECHNICAL DIFFICULTIES;164
21.5;THE "GOOD ENOUGH" ATTITUDE;164
21.6;THE SCHLESINGER-BURG COLLABORATION, AND LONG-RANGE CONSEQUENCES;165
21.7;SOME THOUGHTS ABOUT THE FUTURE;168
21.8;THE PROCESSES OF DISCOVERY;169
21.9;REFERENCES AND NOTES;170