Nishikawa / Iwata / Endo Correlated Functional Oxides

Nanocomposites and Heterostructures
1. Auflage 2016
ISBN: 978-3-319-43779-8
Verlag: Springer Nature Switzerland
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 241 Seiten

Reihe: Chemistry and Materials Science

This book introduces a variety of basic sciences and applications of the nanocomposites and heterostructures of functional oxides. The presence of a high density of interfaces and the differences in their natures are described by the authors. Both nanocomposites and heterostructures are detailed in depth by researchers from each of the research areas in order to compare their similarities and differences. A new interfacial material of heterostructure of strongly correlated electron systems is introduced.

Hiroaki Nishikawa / Degree: Ph.D. (Osaka Univ.), M.S. (Osaka Univ.) / Title: Associate Prof. at Kindai Univ. / Visiting Researcher: Univ. Twente 2007-2008 (The Netherlands) / Research Field: Oxide Electronics, Oxide Heterointerfaces and their Interface Properties, Bioceramic Thin Films / International Activity: International Conference Organizer of HTCMC 9 in conjunction with GFMAT 2016 (Toronto, Canada), IUMRS-ICAM 2015 (Jeju, Korea), JSAP-MRS Joint Symposia 2013 (Kyoto, Japan) etc. and Many Invited Talks such as Keynote Speaker of IUMRS-ICEM 2014 (Taipei, Taiwan). Nobuyuki Iwata / Degree: Ph.D. (Waseda Univ.), M. Eng. (Waseda Univ.) / Title: Associate Prof. at Nihon Univ. / Visiting Researcher: Univ. Twente 2008-2009 (The Netherlands) / Research Field: Multi-functional Oxide Films, Magnetoelectric Films, Synthesis Process for Carbon Related Materials / International Activity: International Conference Organizer of MRS-J 2015 (Yokohama, Japan), IUMRS-ICAM 2015 (Jeju, Korea), MRS-JSAP Joint Symposia 2012 (San Francisco, USA) etc. and Many Invited Talks such as Keynote Speaker of IUMRS-ICA 2014 (Fukuoka, Japan).  Tamio Endo / Degree: Ph.D. (Kyoto Univ.), MsD (Gifu Univ.) / Title: Emeritus Prof. of Mie Univ. (Jp), Gifu Univ. Special Researcher (Jp), Honorary Prof. of Southwest Jiaotong Univ. (Ch) / Visiting Researcher: Univ. Cal.- San Diego 1995 (USA) / Research Field: Oxide Thin Films, Heterostructures, Plasma Effects and Bonding of Polymer Films / Academic Project: Many of International Academic Projects and Jp-In Cooperative Science Program / International Activity: * Many of International Conference Organizers and Plenary Speakers * Many Foreign University Guest Talks * Representative of for International Activity.  Yayoi Takamura / Degree: Ph.D. (Stanford Univ.), M.S. (Stanford Univ.) / Title: Associate Prof. at Univ. California, Davis / Research Field: Growth of Complex Oxide Thin Films, Heterostructures, Nanostructures and the Characterization of the Novel Functional Properties Associated with their Interfaces / International Activity: International Conference Organizer of symposia at 2014 and 2016 MRS Spring Meeting (San Francisco, USA), JSAP-MRS Joint Symposia 2013 (Kyoto, Japan), 2013 APS March Meeting (Baltimore, USA) etc. and Many Invited Talks such as Plenary Speaker of ICNM-2013 (Istanbul, Turkey).  Gun-Hwan Lee / Degree: Ph.D. (Nantes Univ.), M.S. (KAIST) / Title: Principal Researcher at Korea Inst. Mater. Sci. / Research Field: High Quality Transparent Conductive Oxides, Indium Free TCO Coatings and Interface Controls in the Multi Oxide Layers for Increasing the Opto-electrical Properties / International Activity: International Conference Organizer of IUMRS-ICAM 2015 (Jeju, Korea), OMTAT 2013 (Kochi, India), JSAP-MRS Joint Symposia 2013 (Kyoto, Japan) etc. and Many of Plenary Speakers.  Paolo Mele is currently Associate Professor Lecturer at Research Center for Environmentally Friendly Materials Engineering, Muroran Institute of Technology (Muroran, Hokkaido, Japan). He obtained a master degree on Chemistry and PhD in Chemical Sciences at Genova University (Italy). In 2003 he moved to ISTEC-SRL in Tokyo to study melt-textured ceramic superconductors. Then he worked as post-doc at Kyoto University (JSPS fellowship) from 2004 to 2007, at Kyushu Institute of Technology (JST fellowship) from 2007 to 2011 and at Hiroshima University (as lecturer) from 2011 to 2014 before reaching his current position. His research interests include materials for energy and sustainable development (superconductors and thermoelectrics); fabrication and characterization of thin films of oxides, ceramics and metals; study of the effect of nanostructuration on the physical properties; thermal transport; vortex matter. He is author of more than 90 papers in scientific international journals, 4 book chapters, 2 patents and contributed to hundreds of communications at international conferences. He edited the book 'Oxide Thin Films, Multilayers and Nanocomposites' for Springer in 2015.

Autoren/Hrsg.

Nishikawa, Hiroaki

Iwata, Nobuyuki

Endo, Tamio

Takamura, Yayoi

Lee, Gun-Hwan

Mele, Paolo

Inhaltsverzeichnis

1;Preface;5
2;Contents;8
3;Editors and Contributors;9
4;1 Functional Iron Oxides and Their Heterostructures;12
4.1;Abstract;12
4.2;1.1 Introduction;13
4.3;1.2 FeO: Transparent P-Type Oxide Semiconductor;13
4.4;1.3 ?-Fe2O3: Novel Oxide Photocatalyst for Solar Energy Conversion;18
4.5;1.4 Fe3O4: Room Temperature Ferromagnetic Oxide;22
4.6;1.5 Photocontrol of Spin-Glass State in Spinel/Garnet Ferrites;27
4.6.1;1.5.1 Photomagnetism in Spin-Glass Spinel Type Ferrites;28
4.6.2;1.5.2 Synaptic Signal Mimicked by Spin-Current in Spin-Glass Garnet Ferrites;30
4.7;1.6 Concluding Remarks;36
4.8;References;36
5;2 Functional Properties of Polydomain Ferroelectric Oxide Thin Films;40
5.1;Abstract;40
5.2;2.1 Introduction;41
5.3;2.2 Polydomain Ferroelectric Thin Films;42
5.4;2.3 Model of a Polydomain PZT Thin Film;44
5.4.1;2.3.1 Free Energy of a Polydomain, Clamped (001)-Oriented Thin Film;48
5.4.2;2.3.2 Application to a Tetragonal Polydomain Thin Film;49
5.4.3;2.3.3 Dielectric Properties of the Tetragonal (001) Polydomain Film;53
5.4.4;2.3.4 Lattice Parameters of the Tetragonal (001) Polydomain Film;55
5.4.5;2.3.5 Piezoelectric Properties of the Tetragonal, Polydomain (001) Film;55
5.5;2.4 Numerical Analysis;56
5.5.1;2.4.1 Numerical Results;57
5.6;2.5 Conclusions and Outlook;63
5.7;Acknowledgments;64
5.8;References;64
6;3 Stress Accommodation and Structural Distortions at Correlated Oxide Interfaces;65
6.1;Abstract;65
6.2;3.1 Introduction;66
6.3;3.2 Crystal Structure and Distortions of a Perovskite Unit Cell;67
6.4;3.3 Characterization of Octahedral Distortions by Advanced X-Ray Diffraction;70
6.5;3.4 Structural Distortions in Ultrathin Films and Interfaces;73
6.6;3.5 Conclusions;83
6.7;References;83
7;4 The Influence of Different Additives on MgB2 Superconductor Obtained by Ex Situ Spark Plasma Sintering: Pinning Force Aspects;85
7.1;Abstract;85
7.2;4.1 Introduction;86
7.3;4.2 Experimental;89
7.4;4.3 Results;96
7.4.1;4.3.1 Additives that Are not Reacting with MgB2 (Fig. 4.2);97
7.4.2;4.3.2 Additives Reacting with MgB2 and Formation of Impurity Boride MyBz Phases (Fig. 4.4);102
7.4.3;4.3.3 Additives: Metal (Fig. 4.5) and Metal Oxides (Fig. 4.6) Reacting with MgB2 and Formation of MguMv Impurity Phases;105
7.4.4;4.3.4 Additives which Are Source of Carbon (Fig. 4.7) Substituting for Boron in the Crystal Lattice of MgB2;107
7.5;4.4 Discussion;114
7.6;4.5 Conclusion;122
7.7;Acknowledgments;123
7.8;References;123
8;5 Infrared Spectra in Oxide Nanocomposites/Minerals;127
8.1;Abstract;127
8.2;5.1 Introduction;127
8.3;5.2 Spectral Range;128
8.4;5.3 Energy Levels in Molecules;129
8.5;5.4 Vibrational Modes;130
8.6;5.5 Stretching and Bending Modes of Vibration;132
8.7;5.6 Different Forms of Vibrations of Molecules;133
8.8;5.7 Degeneracy of the Bond;134
8.9;5.8 Fundamentals and Overtones;134
8.10;5.9 Characteristics of Combination Bands;135
8.10.1;5.9.1 The Calculation of Overtones and Harmonics;135
8.11;5.10 Types of IR Spectroscopy;135
8.12;5.11 Applications of NIR Spectroscopy;136
8.12.1;5.11.1 Advantages of Near Infrared/Infrared Spectroscopy;136
8.12.2;5.11.2 Disadvantages of NIR;136
8.13;5.12 Sample Preparation Procedure;137
8.14;5.13 Reflectance IR Spectroscopy;137
8.15;5.14 Applications;138
8.15.1;5.14.1 Nanoferrites;138
8.15.2;5.14.2 Molecules and Minerals;141
8.15.2.1;5.14.2.1 Water;141
8.15.2.2;5.14.2.2 Hydroxyl Ion (OH?);142
8.15.2.3;5.14.2.3 Silicates;143
8.15.2.4;5.14.2.4 Carbonates;143
8.15.2.5;5.14.2.5 Oxides and Hydroxides;143
8.15.2.6;5.14.2.6 Sulfides and Sulfates;144
8.15.2.7;5.14.2.7 Halides, Phosphates, Arsenates, Vanadates, and Borates;144
8.15.3;5.14.3 Thin Film Metrology;145
8.15.3.1;5.14.3.1 Analysis of Silicon Dioxide Thin Film;146
8.15.4;5.14.4 Application of FTIR Spectroscopy in Environmental Studies;146
8.16;5.15 Summary;147
8.17;References;148
9;6 Self-assembled Nanocomposite Oxide Films;149
9.1;Abstract;149
9.2;6.1 Introduction;149
9.3;6.2 Growth Methodology of Self-assembled Nanocomposite Oxide Films;151
9.3.1;6.2.1 Film Preparation by PLD Techniques;152
9.3.2;6.2.2 Self-assembled Growth of Nanocomposite Oxide Structures;152
9.3.3;6.2.3 Physical Properties of Spinel (Fe,Zn)3O4–Perovskite BiFeO3 Nanocomposite Structures;155
9.4;6.3 Position-Controlled Nanocomposite Structures Using Nano-Seeding Assembly;157
9.4.1;6.3.1 Preparation of Nanodot Templates;158
9.4.2;6.3.2 Synthesis of Nanocomposite Structures by Combination of Self-assembly and Selective Growth Using Nanodot Templates;161
9.4.3;6.3.3 Growth Mechanism of Position-Controlled Nanocomposite (Fe,Zn)3O4–BiFeO3 Array;167
9.5;6.4 Summary;170
9.6;References;171
10;7 Functionality in Insulating Oxide Thin Films: Work Function Control and Polar Surface;174
10.1;Abstract;174
10.2;7.1 Introduction;174
10.3;7.2 Work Function Control at the Insulator Interface;175
10.3.1;7.2.1 Introduction;175
10.3.2;7.2.2 Kelvin Probe Technique;177
10.3.3;7.2.3 MgO/Nb:SrTiO3;179
10.3.4;7.2.4 LaAlO3/(Nb:)SrTiO3;184
10.4;7.3 Formation of Polar Surface by Thin Film Growth: Fabrication and Characterization of Polar MgO(111);188
10.4.1;7.3.1 Introduction;188
10.4.2;7.3.2 MgO(111) Surface;189
10.4.3;7.3.3 Growth of MgO(111) Thin Films by PLD;191
10.4.3.1;7.3.3.1 Layer-by-Layer Growth of MgO(111) Thin Films Using NiO(111) Buffer Layer;191
10.4.3.2;7.3.3.2 Flat MgO(111) Films Grown on ?-Al2O3(0001) Substrates;193
10.4.3.3;7.3.3.3 MgO Thin Films on SrTiO3 Substrates: MgO(111) Versus MgO(100);196
10.5;7.4 Concluding Remarks;199
10.6;Acknowledgments;199
10.7;References;199
11;8 Material Design of Metal Oxide Nanowires and Their Promises;204
11.1;Abstract;204
11.2;8.1 Introduction;204
11.3;8.2 Bottom-up Nanowire ReRAM Fabrication;205
11.4;8.3 Summary;211
11.5;References;212
12;9 Atomic Processes of Pulsed Laser Deposition During Growth of Alkaline Earth Oxide Thin Films;214
12.1;Abstract;214
12.2;9.1 Introduction;214
12.3;9.2 Mechanism of Laser Ablation on Alkaline Earth Metals;216
12.3.1;9.2.1 Experimental Techniques: PLD, QMS, and TOF;218
12.3.2;9.2.2 Results and Discussion;221
12.3.2.1;9.2.2.1 TOF Spectra and Amount of Desorbed Monovalent Ion on Laser Ablation of Alkaline Earth Metals;221
12.3.2.2;9.2.2.2 Influence of the Variation of Effective Pulse Duration by Using Double Pulsed Laser Ablation Technique;225
12.3.2.3;9.2.2.3 General Remarks and Considerations on the Mechanism of the Laser Ablation for the Metallic Bond Crystals;229
12.3.3;9.2.3 Summary of the Section;232
12.4;9.3 Study of the Migration Process of SrO During Laser Ablation;232
12.4.1;9.3.1 Experimental Techniques: On Time-Resolved RHEED;233
12.4.2;9.3.2 Results and Discussion;234
12.4.3;9.3.3 Summary of the Section;237
12.5;9.4 Conclusion;237
12.6;Acknowledgments;238
12.7;References;238
13;Index;240