Bonding and Charge Distribution in Polyoxometalates: A Bond Valence Approach

1999
ISBN: 978-3-540-64934-2
Verlag: Springer Berlin Heidelberg

Buch, Englisch, Band 93, 340 Seiten, HC runder Rücken kaschiert, Format (B × H): 160 mm x 241 mm, Gewicht: 699 g

Reihe: Structure and Bonding

This book presents the fundamentals of bonding in polyoxometalates and related oxides based on classical bonding concepts and the bond valence model. The in-depth treatment includes a revision of the procedure for the determination of the parameters of bond length-bond valence functions, the application of the bond valence model to polyoxometalates and related oxides, and the explanation of the distribution of the bond valences, and hence of the bond lengths, over the metal-oxygen bond and of the ionic charge on the oxygen atoms. Numerous tables and figures underline and illuminate the results. The principal author is a leader in the field of polyoxometalate chemistry. This work provides for the first time a comprehensive analysis of the structure and bonding in polyoxometalates, based on classical chemical concepts and the bond valence approach, and as such is a valuable resource for chemists, physicists and material scientists working in the field.

Zielgruppe

Research

Autoren/Hrsg.

Mingos, D. M. P.

Weitere Mitwirkende

Fischer, S.

Kurad, D.

Mehmke, J.

Tytko, K.H.

Fachgebiete

• Naturwissenschaften Chemie Anorganische Chemie Festkörperchemie
• Naturwissenschaften Chemie Chemie Allgemein
• Naturwissenschaften Chemie Anorganische Chemie Nichtmetallische Chemie
• Naturwissenschaften Chemie Anorganische Chemie Komplexchemie
• Naturwissenschaften Chemie Physikalische Chemie

Inhaltsverzeichnis

Bond length-bond valence relationships with particular reference to polyoxometalate chemistry.- A bond model for polyoxometalate ions composed of MO6 octahedra (MOk polyhedra with k>4).- Bonding and charge distribution in isopolyoxometalate ions and relevant oxides—A bond valence approach.