Metzner / Thuillier / Katritzky Sulfur Reagents in Organic Synthesis

1. Auflage 2013
ISBN: 978-1-4832-8928-1
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 200 Seiten, Web PDF

Reihe: Best Synthetic Methods

Designed for the practising organic chemist, this book details over a hundred experimental procedures using sulfer compounds in organic synthesis. Many of these methods are new to the literature, having been published since 1991, and illustrate the striking versatility of the use of sulfur reagents. Examples are simple to perform and extremely useful, and as such this book will be an invaluable aid to all involved in synthetic organic chemistry, whether in academic or industrial laboratories.

Autoren/Hrsg.

Metzner, Patrick

Thuillier, Andre

Katritzky, A. R.

Meth-Cohn, O.

Inhaltsverzeichnis

1;Front Cover
;1
2;Sulfur Reagents in Organic Synthesis;4
3;Copyright Page;5
4;Table of Contents;12
5;Contents;6
6;Foreword;8
7;Abbreviations;18
8;Chapter 1. Introduction;20
9;Chapter 2. Preparation of organosulfur reagents;22
9.1;2.1 THIOLS;22
9.2;2.2 SULFIDES;25
9.3;2.3 DISULFIDES AND POLYSULFIDES;29
9.4;2.4 THIO- AND DITHIOACETALS AND RELATED COMPOUNDS;31
9.5;2.5 KETENEDITHIOACETALS AND a-OXOKETENEDITHIOACETALS;38
9.6;2.6 SULFOXIDES;42
9.7;2.7 SULFONES;47
9.8;2.8 THIOCARBONYL COMPOUNDS;49
9.9;2.9 SULFONIUM SALTS AND SULFUR YLIDES;70
10;Chapter 3. Functional modifications with organosulfur compounds;72
10.1;3.1 INTRODUCTION OF UNSATURATION;72
10.2;3.2 RADICAL DEOXYGENATION OF ALCOHOLS: THE BARTON REACTION;79
10.3;3.3 OXIDATION OF ALCOHOLS;81
10.4;3.4 ASYMMETRIC REDUCTION;82
10.5;3.5 DECARBOXYLATION;83
10.6;3.6 THE PUMMERER REARRANGEMENT;83
10.7;3.7 MISCELLANEOUS REACTIONS;86
11;Chapter 4. Organosulfur compounds as intermediates in organic synthesis;94
11.1;4.1 A WORD ON DESULFURIZATION;94
11.2;4.2 C–C BOND-FORMING REACTIONS;94
11.3;4.3 C=C BOND-FORMING REACTIONS;145
11.4;4.4 THREE-MEMBERED RING-FORMING REACTIONS. CYCLOPROPANATION, FORMATION OF EPOXIDES;162
11.5;4.5 PERICYCLIC REACTIONS OF ORGANOSULFUR COMPOUNDS;172
12;References;198
13;Index;214