Marcus / Maurice Passivation of Metals and Semiconductors, and Properties of Thin Oxide Layers

A Selection of Papers from the 9th International Symposium, Paris, France, 27 June - 1 July 2005
1. Auflage 2006
ISBN: 978-0-08-046152-6
Verlag: Elsevier Science & Techn.
Format: EPUB
Kopierschutz: 6 - ePub Watermark

E-Book, Englisch, 764 Seiten

Passivation of Metals and Semiconductors, and Properties of Thin Oxide Layers contains a selection of papers presented at PASSIVITY-9, the 9th International Symposium on the Passivation of Metals and Semiconductors and the Properties of Thin Oxide Layers, which was held in Paris, 27 June - 1 July, 2005. One hundred and twelve peer-reviewed manuscripts have been included.
The book covers all the fundamental and applied aspects of passivity and provides a relevant and updated view of the advances and new trends in the field. It is structured in ten sections:
• Growth, (Nano)structure and Composition of Passive Films
• Passivity of Semiconductors
• Electronic Properties of Passive Films
• Passivity Issues in Biological Systems
• Passivity in High-Temperature Water
• Mechanical Properties of Passive Films,
• Passivity Issues in Stress Corrosion Cracking and Tribocorrosion
• Passivity Breakdown and Localized Corrosion
• Modeling and Simulation
• Surface Modifications and Inhibitors (for Improved Corrosion Resistance and/or Adhesion)

Autoren/Hrsg.

Marcus, Philippe

Maurice, Vincent

Inhaltsverzeichnis

1;Cover;1
2;Contents;8
3;Preface;6
4;Section A Growth, (Nano)structure and Composition of Passive Films;18
4.1;Electrochemical Properties of Fe-Cr-Mo Alloys and Fe2O3-Cr2O3-MoO2 Artificial Passivation Films in 1 M HCl;20
4.2;Formation and growth processes of electrochemical passive layers (borate medium: pH 9.2) and electron stimulated oxidized films (5.10-6 Pa O2) formed on Fe-Cr alloys ;26
4.3;Development and Composition of the High Temperature Oxide Film Grown on Fe-15Cr during Annealing;32
4.4;Passivity of Nickel-Containing Stainless Steels in Concentrated Sulphuric Acid;40
4.5;An insight on the role of Nickel in the passive films generated on different stainless steels;46
4.6;Passivity of Nitrogen-Bearing Stainless Steel in Acidic Solution;52
4.7;Passive behaviour of stainless steels and nickel in LiBr solution at different temperatures;58
4.8;The effect of the Cerium ion implantation in the passive films properties of a duplex stainless steel;64
4.9;Use of Alloy 22 as Long-Term Radioactive Waste Containment Material;70
4.10;Effect of temperature and melt composition on the passivity of a Ni-10%Cr alloy in a molten electrolyte;76
4.11;Spontaneous Passivation of Amorphous Bulk Ni-Cr-Mo-Ta-Nb-P Alloys in Concentrated HCl;82
4.12;Passivity of Fe90V10 and Fe75Cr15V10 in Alkaline Media A. Drexler and H.-H. Strehblow;88
4.13;Effect of anodic passivation on the corrosion behaviour of Fe-Mn-Al steels in 3.5% NaCl;94
4.14;Surface Characterization of 1018 Carbon Steel in Borate Medium by in-situ Electrochemical Scanning Tunneling Microscopy;100
4.15;Iron passivation studied by in situ Raman spectroscopy on Fe/Au(111) epitaxial films;106
4.16;Atomic-Structure Characterization of Passive Film of Fe by Grazing Incidence X-ray Scattering at SPring-8;112
4.17;Electrochemical aspects of the behavior of perchlorate ions in the presence of iron group metals;118
4.18;The effect of Al supremum 3+ in the passivity of iron in alkaline media containing chlorides;124
4.19;Nanoscale modifications of a Ni(111) surface during nucleation and growth of the passive film;130
4.20;Simultaneous Anodic Dissolution and Passivation of Nickel in Moderate Acid Medium;136
4.21;Copper Passivity in Carbonate Base Solutions and its Application in Chemical Mechanical Planarization (CMP);142
4.22;Analysis of Cu corrosion product in aqueous lithium bromide concentrated solutions;148
4.23;Passivity of Tin and CuSn Alloys in Alkaline Media studied by X-ray Photoelectron Spectroscopy;154
4.24;Surface Analytical Characterization of Chromium Passivation on Tinplate;160
4.25;To Passivate or not to Passivate, that is the Question: The Case of Barium Tin(II) Chloride Fluorides;166
4.26;A Thin Passivating Tin(IV) Oxide Layer on Tin(II)-Containing Fluoride Particles, or not? The M1-x Snx F2 Solid Solutions;172
4.27;Electrochemical Data About Disruption of Passivating Films. The Pb/PbSO4/H2SO4 System;178
4.28;Morphology, composition and structure of anodic films on binary Al-Cu alloys;184
4.29;Repassivation of aluminium during the AC-graining process by aluminium hydroxide formation;190
4.30;Anodization of Ti : Formation of Self-Organized Titanium Oxide Nanotube-Layers;196
4.31;Self-Organized Nanoporous Valve Metal Oxide Layers;204
4.32;Studies on transition of titanium from active into passive state in phosphoric acid solutions;210
4.33;The Influence of Temperature on the Passive Film Properties of ASTM Grade-7 Titanium;216
4.34;Chromatic properties of anodised titanium obtained with two techniques;222
4.35;Amorphous-to-Crystalline Transition of Anodic Niobia;228
4.36;Ellipsometric Analysis of Growth Process of Oxidation Films on Magnesium and its Alloys in Neutral Aqueous Solutions;234
4.37;Corrosion Protection of Magnesium Alloys by Ce, Zr and Nb oxide layers;242
5;Section B Passivity of Semiconductors;248
5.1;Passivation of (100) and (111) Silicon in KOH Solution H.G.G. Philipsen and J.J. Kelly;250
5.2;On the nature of oscillations of Open Circuit Potential of silicon immersed in CuSO4/HF solution;256
5.3;Passivation and Local Corrosion of p-Silicon in Anhydrous Organic Solutions of Chlorides;262
5.4;Silicon Texturing Under Negative Potential Dissolution (NPD) Conditions;268
5.5;Fermi Level Pinning at n-GaAs(110) Electrodes;274
5.6;Composition and Growth of Thermal and Anodic Oxides on InAlP;280
5.7;High-k gate oxide formed by anodic oxidation for organic field effect transistors;288
6;Section C Electronic Properties of Passive Films;294
6.1;Photoelectrochemical analysis of the passive film formed on Fe-Cr-Ni alloys in pH 8.5 buffer solution H. J. Jang and H. S. Kwon;296
6.2;Photoelectrochemical Response and Corrosion Property of Passive Films on Fe-18Cr Alloy;302
6.3;Effects of EDTA on the Electronic Properties of Passive Film on Fe-20Cr in pH 8.5 Buffer Solution;308
6.4;Electrochemical and Mott-Schottky Behaviour of the Oxide Films on I625 Exposed to Gamma Radiation;316
6.5;Oxygen Reduction on Passive Steel and Cr Rich Alloys for Concrete Reinforcement;322
6.6;Diffusivity of point defects in the passive film on Fe;328
6.7;Electrochemical Impedance of Thin Rust Film Fabricated Artificially;334
6.8;A new approach to describe the passivity of nickel and titanium oxides;342
6.9;Relation of the Photocurrents to the Corrosion Rates of Pure Aluminum having Various Oxides;348
6.10;Growth and Characterization of Anodic Films on Al-Nb Alloys;354
6.11;Amorphous semiconducting passive film-electrolyte junctions revisited. The influence of a non homogeneous density of state on the differential admittance behaviour of anodic a-Nb2O5 ;360
7;Section D Passivity Issues in Biological Systems;366
7.1;Influence of Protein Adsorption on the Passivation of Dental Amalgams;368
7.2;BSA adsorption on Fe-17Cr in acid solution: electrochemical behaviour and surface composition;374
7.3;XPS characterisation of BSA adsorption on stainless steel;382
7.4;Study of corrosion behaviour of Ti-coated AISI 316L stainless steel in a simulated body fluid solution;388
7.5;Effect of Al on the passivity of Ti base implant alloys;394
7.6;Improved adhesion of titanium oxide film to titanium-base alloy by Ti/O compositional gradient using reactive sputter-deposition;400
7.7;Liquid crystal behavior in solutions, electrode passivation, and impedance loci in four quadrants;406
8;Section E Passivity in High-Temperature Water;412
8.1;Passive film growth and oxide layer restructuring on stainless steel in a high-temperature borate electrolyte;414
8.2;Kinetics of passivation of nickel-base alloys (Alloy 600 and Alloy 690) in high temperature water;420
8.3;Behaviour of oxide films in boric acid – lithium hydroxide solutions;428
8.4;The Effect of CO2 and H2S on the Passivation of Chromium and Stainless Steels in Aqueous Solutions at Elevated Temperature and under High Pressure;434
8.5;Effect of Lead on Passivation of Alloy 600 Surface;442
8.6;Interaction of Oxide Layers on Structural Materials with Light Water Reactor Coolants - its influence on the mechanism of oxide growth and restructuring;448
9;Section F Mechanical Properties of Passive Films;454
9.1;Differences in Mechanical Properties of the Passive Metal Surfaces Obtained in Solution and Air;456
9.2;Current Transients of Passive Iron during Micro-indentation in Solution;468
9.3;Mechanical Properties of Single-Crystal Tantalum (100) Surface Covered with Anodic Oxide Film;474
9.4;Study of the mechanical effects on passivity breakdown by local probe techniques;480
9.5;Mechanical properties of metastable r.f magnetron sputter-deposited A infimum 1-x Cu infimum x thin films;486
10;Section G Passivity Issues in Stress Corrosion Cracking and Tribocorrosion;492
10.1;Passivity Issues in Tribocorrosion;494
10.2;Wear in nuclear power plants, a tribocorrosion approach;506
10.3;Comparison between tribocorrosion mechanisms of Stellite 6 and Zircaloy 4 in LiOH-H infimum 3 BO3solutions;512
10.4;Detrimental effect of lead on the passivity of UNS N06690 alloy;518
10.5;The role of Borides in the Passivity and SCC of Alloy 600;524
10.6;Effect of Nickel and Tungsten on Repassivation Rate of Stainless Steels in Chloride Solution by Potential Step Chronoamperometry;530
10.7;Dislocations effect on kinetic of passivation of polycristalline nickel in H2 SO4 medium;536
10.8;Electrochemical potential oscillations during galvanostatic passivation of copper in NaNO2solution and their role in TGSCC mechanism;542
10.9;Effects of straining on oxide films and passivity of copper in nitrite solution at ambient temperature;548
10.10;Repassivation Kinetics of Al-Alloys for Aircraft Structures;554
11;Section H Passivity Breakdown and Localized Corrosion;560
11.1;Localized Corrosion Growth Kinetics in AA7178;562
11.2;An in situ AFM study of the first steps of localised corrosion on a stressed 304L stainless steel in chloride media;15
11.3;Initial stage of localized corrosion in artificial pit formed on zinc coated steels by photon rupture;578
11.4;Influence of the chemical dissolution of MnS inclusions on the composition of passive films and the local electrochemical behaviour of stainless steels;584
11.5;Electrochemical characterization of corrosion resistant alloys in chloride solutions;590
11.6;Effect of HCl on Pickling of 304 Stainless Steel in Iron Chloride-Based Electrolytes;596
11.7;Influence of thermal oxides on pitting corrosion of austenitic and duplex steels;602
11.8;Modifications in the electrochemical behaviour of SAF 2205 in alkaline media induced by Cl- ions;608
11.9;In-situ Raman spectroscopy study of iron and carbon steel corrosion in mineral water;614
11.10;Effect of Noble Element Alloying on Passivity and Passivity Breakdown of Ni;620
11.11;Analysis of Electrochemical Noise of Pure Aluminium in Sulphate and Molybdate Ion-Containing 0.1 M NaCl Solution;626
11.12;Localized corrosion of 2024 alloy: structure and composition of oxide films grown on model alloys representative of the different metallurgical phases;632
11.13;Passivity Breakdown of Aluminum Alloys by Trace Element Lead;638
11.14;Passivity Breakdown of Aluminium Alloys by Surface Enrichment of Group IIIA - VA Trace Elements;644
11.15;Electrochemical behaviour of Al and some of its alloys in chloride solutions;650
12;Section I Modelling and Simulation;656
12.1;Cooperative Spreading of Pit Sites as a New Explanation for Critical Threshold Potentials;658
12.2;Atomistic simulation of the passivation of iron-chromium alloys using calculated local diffusion activation barriers;668
12.3;DFT study of the interactions of Cl- with passivated Nickel surfaces: energetic and structural aspects;676
12.4;Simulation of corrosion processes with anodic and cathodic reactions separated in space;684
13;Section J Surface Modifications and Inhibitors (for Improved Corrosion Resistance and/or Adhesion);690
13.1;On the Interaction of Organic Molecules with Metal Oxide Surfaces;692
13.2;Formation of Al-Si Composite Oxide Films on Aluminum by Electrophoretic Sol-Gel Coating / Anodizing;702
13.3;In-situ Raman Spectroscopy and Spectroscopic Ellipsometry study of the iron/Polypyrrole interface;708
13.4;Spontaneous grafting of iron surfaces by reduction of aryldiazonium salts in acidic water. Applications to the inhibition of iron corrosion;714
13.5;Conversion coating of zinc heptanoate in aqueous media on electrogalvanized steel;720
13.6;Study of carbon steel corrosion inhibition in alkaline solution by means of EIS;726
13.7;Nitrided/nitrocarburized and oxidized steel: Corrosion data in dependenceon the N- and C-content of the e-phase under the oxide layer;732
13.8;Passivation treatments on Zn and Zn alloys substrates involving Mo and W compounds;738
13.9;Electrochemical Properties and Applications of Sputtered Iridium Oxide Thin Films;746
13.10;Study of DSA® deactivation;754
14;Index;760