Ionic Liquid Catalyzed Reactions

Green Concepts and Sustainable Applications
1. Auflage 2025
ISBN: 978-3-527-35075-9
Verlag: Wiley-VCH GmbH

Buch, Englisch, 384 Seiten, Format (B × H): 175 mm x 248 mm, Gewicht: 870 g

Understand the applications of ionic liquid catalysis with this cutting-edge overview

Ionic liquids have distinctive properties that have made them the subject of vigorous research in recent decades. They have primarily been seen as potential green alternatives to volatile organic solvents, and therefore as a vital tool in the development of sustainable industry. In fact, however, ionic liquids can also serve as catalysts, catalyst immobilizers, and initiators, with the result that they have been applied in over 100 known types of chemical reactions.

Ionic Liquid Catalyzed Reactions: Green Concepts and Sustainable Applications offers a detailed overview of these reactions and the catalytic mechanism of ionic liquids. It surveys cutting-edge research into ionic liquid catalysis and the concepts, perspectives, and skills needed for scientists to incorporate it into a range of experimental fields. It is a must-own for anyone looking to understand the range and variety of uses for ionic liquid catalysis.

Ionic Liquid Catalyzed Reactions readers will also find: - Case studies throughout showing ionic liquid catalysis applications
- Information for scientists working in organic chemistry, electrochemistry, biotechnology, and many more
- Detailed coverage of reactions including CO2 conversion, biomass transformation, organic synthesis, and many others

Ionic Liquid Catalyzed Reactions is ideal for catalytic chemists, organic chemists, environmental chemists, electrochemists, and anyone else working with chemical catalysis in need of new experimental methods.

Autoren/Hrsg.

Liu, Zhimin

Zhao, Yanfei

Fachgebiete

• Naturwissenschaften Chemie Physikalische Chemie Chemische Reaktionen, Katalyse
• Technische Wissenschaften Technik Allgemein Nachhaltigkeit, Grüne Technologien
• Naturwissenschaften Chemie Chemie Allgemein
• Naturwissenschaften Chemie Organische Chemie

Inhaltsverzeichnis

Chapter 1 Ionic liquid catalysts
1.1 Acidic ionic liquids
1.2 Basic ionic liquids
1.3 Neutra ionic liquids with hydrogen-bond donor/acceptor
1.4 Chiral ionic liquids
 
Chapter 2 Ionic liquid-catalyzed transformation of carbon dioxide to chemicals under metal-free conditions
2.1 Synthesis of organic carbonates
2.2 Synthesis of N-containing heterocycles
2.3 Reductive transformation of CO2
2.4 Synthesis of other compounds
2.5 Remarks and perspectives
 
Chapter 3 Ionic liquid-mediated reductive transformation of carbon dioxide with hydrogen
3.1 Direct hydrogenation of CO2
3.2 N-formylated or N-methylated reaction of amines with CO2/H2
3.3 Hydroformylation of olefin with CO2/H2
3.4 Hydromethylamination of olefin with CO2/H2 and amines
3.5 Carbonylation of alcohol/ethers with CO2/H2
3.6 Remarks and perspectives

Chapter 4 Electrochemical reduction of carbon dioxide in ionic liquid-based electrolytes
4.1 Fundamentals of CO2 electroreduction
4.2 Ionic liquid-based electrolytes for CO2 electroreduction
4.3 Electroreduction of CO2 to various chemicals in IL-based electrolytes
4.4 Electro-transformation of CO2 into value-added chemicals
4.5 Remarks and perspectives
Chapter 5 Ionic liquid-catalyzed chemical transformation of lignocellulose
5.1 Ionic liquid-catalyzed transformation of cellulose and its derivatives
5.2 Ionic liquid-catalyzed transformation of hemicellulose and xylose to furfural
5.3 Ionic liquid-catalyzed transformation of lignin and its platforms
5.4 Remarks and perspectives
 
Chapter 6 Ionic liquid catalyzed oxidation reactions
6.1 Oxidation of alcohols/aldehydes
6.2 Oxidation of organic sulfides and oxidative desulfurization
6.3 Oxidative cyclization of olefins and allylic alcohols
6.4 Oxidation of amines
6.5 Baeyer-Villiger oxidation
6.6 Oxidation of other compounds
6.7 Remarks and perspectives
 
Chapter 7 Ionic liquid catalyzed water-involved reactions
7.1 Dehydrative esterification
7.2 Dehydrative etherification of alcohols
7.3 Dehydration alkenylation
7.4 Dehydrative amidation
7.5 Ionic liquid catalyzed hydration reaction
7.6 Hydrolysis of esters/ ethers
7.7 Remarks and perspectives
 
Chapter 8 Ionic liquid-catalyzed other organic reactions
8.1 Alkylation reaction
8.2 Michael addition reaction
8.3 Diels-Alder reactions
8.4 Markovnikov addition
8.5 Knoevenagel condensation
8.6 Aldol condensation reaction
8.7 Ring-closing C-O/C-O and C-O/O-H bond metathesis
8.8 Remarks and perspectives
 
Chapter 9 Ionic liquid catalyzed recycling of spent polymers
9.1 Degradation of polyesters 1
9.2 Degradation of polyamides
9.3 Upcycling of polyolefins
9.4 Co-upcycling of PVC and polyester
9.5 Remarks and perspectives
 
Acknowledgements

Über Autor(innen)

Zhimin Liu, PhD, is Professor at the Institute of Chemistry, Chinese Academy of Sciences (ICCAS), China. She has spent most of her career conducting research at ICCAS. She is the recipient of numerous scientific awards. She is an Editor-in-Chief of Current Opinion in Green and Sustainable Chemistry.

Yanfei Zhao, PhD, is Associate Professor at ICCAS, China. Her current research interest concentrates on the ionic liquid-promoted transformation of renewable carbon resources.