Li Handbook of Green Chemistry - Green Solvents

Volume 5 - Reactions in Water
1. Auflage 2014
ISBN: 978-3-527-68856-2
Verlag: Wiley-VCH
Format: PDF
Kopierschutz: Adobe DRM (»Systemvoraussetzungen)

E-Book, Englisch, 427 Seiten, E-Book

Reihe: Handbook of Green Chemistry

The shift towards being as environmentally-friendly as possible has resulted in the need for this important volume on the topic of reactions in water. Edited by one of the leaders in the field, Professor C.-J. Li, this is an essential resource for anyone wishing to gain an understanding of the world of green chemistry, as well as for chemists, environmental agencies and chemical engineers.

Autoren/Hrsg.

Li, Chao-Jun

Weitere Mitwirkende

Anastas, Paul T.

Inhaltsverzeichnis

THE PRINCIPLES OF AND REASONS FOR USING WATER AS A SOLVENT FOR GREEN CHEMISTRY

Introduction

Binding Two Species Together Driven by the Hydrophobic Effect in Water

Aromatic Chlorination

Acylation of Cyclodextrins by a Bound Ester

Mimics of Metalloenzymes Using the Hydrophobic Effect in Water

Mimics of the Enzyme Ribonuclease

Mimics of Enzymes that Use Pyridoxamine Phosphate and Pyridoxal Phosphate as Coenzymes

Artificial Enzymes Carrying Mimics of Thiamine Pyrophosphate

Enolizations and Aldol Condensations

Hydrophobic Acceleration of Diels-Alder Reactions

Selectivities in Water Induced by the Hydrophobic Effect - Carbonyl Reductions

Selectivities in Water Induced by the Hydrophobic Effect - Oxidations

Using Hydrophobic Effects in Water to Determine the Geometries of Transition States for Some Important Reactions

Conclusion

GREEN ACID CATALYSIS IN WATER

Introduction

Lewis Acids in Water

Chiral Lewis Acid-Catalyzed Asymmetric Reactions in Water

Bronsted Acid Catalysis in Pure Water

Conclusion and Perspective

GREEN BASES IN WATER

Introduction

Types of Bases and Their Use from a Green Point of View

Liquid-Liquid Processes

Solid-Liquid Processes

GREEN OXIDATION IN WATER

Introduction

Water-Soluble Ligands

Oxidations Catalyzed by Metalloporphyrins and Metallophthalocyanines

Epoxidation and Dihydroxylation of Olefins in Aqueous Media

Alcohol Oxidations in Aqueous Media

Aldehyde and Ketone Oxidations in Water

Sulfoxidations in Water

Conclusion

GREEN REDUCTION IN WATER

Introduction

Water-Soluble Ligands

Hydrogenation in Water

Transfer Hydrogenation in Water

Role of Water

Conclusion

COUPLING REACTIONS IN WATER

Introduction

Reaction of Carbonyl Compounds and Derivatives

Reaction of Alkenes and Alkynes

Reaction of Organic Halides and Derivatives

Conclusion

"ON WATER" FOR GREEN CHEMISTRY

Introduction

Pericyclic Reactions

Addition of Heteronucleophiles to Unsaturated Carbonyl Compounds

Enantioselective Direct Aldol Reactions

Coupling Reactions

Oxidation

Bromination Reactions

Miscellaneous Reactions

Theoretical Studies

Conclusion

PERICYCLIC REACTIONS IN WATER. TOWARD GREEN CHEMISTRY

Introduction

Pericyclic Reaction in Aqueous Media

Conclusion

NON-CONVENTIONAL ENERGY SOURCES FOR GREEN SYNTHESIS IN WATER (MICROWAVE, ULTRASOUND, AND PHOTO)

Introduction

MW-Assisted Organic Transformations in Aqueous Media

Sonochemical Organic Transformations in Aqueous Media

Photochemical Transformations in Aqueous Media

Conclusion

FUNCTIONALIZATION OF CARBOHYDRATES IN WATER

Introduction

C-C Bond Formation Reactions

C-N Bond Formation Reactions

Functionalization of Hydroxy Groups

Clyco-Organic Substrates and Reactions in Aqueous Sugar Solutions

Conclusion

WATER UNDER EXTREME CONDITIONS FOR GREEN CHEMISTRY

Introduction

Background

Recent Progress in HTW Synthesis

WATER AS A GREEN SOLVENT FOR PHARMACEUTICAL APPLICATIONS

Introduction - Is Water a Green Solvent?

Water-Based Enzymatic Processes

Processes in Which the Product is Isolated by pH Adjustment to the Isoelectric Point

Carbon-Carbon Bond-Forming Cross-Coupling Reactions in Water

Pharmaceutical Processes Using Mixed Aqueous Solvents

Conclusion

WATER AS A GREEN SOLVENT FOR BULK CHEMICALS

Introduction

Hydroformylation - An Overview

Water as Solvent for Hydroformylation

Water as Solvent in the Production of 2,7-Octadien-1-ol (Kurayray Process)

Conclusion

Über Autor(innen)

Series Editor:

Paul T. Anastas joined Yale University as Professor and iserves as the Director of the Center for Green Chemistry and Green Engineering at Yale. From 2004-2006, Paul Anastas has been the Director of the Green Chemistry Institute in Washington, D.C. Until June of 2004 he served as Assistant Director for Environment at e White House Office of Science and Technology Policy where his responsibilities included a wide range of environmental science issues including furthering international public-private cooperation in areas of Science for Sustainability such as Green Chemistry. In 1991, he established the industry-government-university partnership Green Chemistry Program, which was expanded to include basic research, and the Presidential Green Chemistry Challenge Awards. He has published and edited several books in the field of Green Chemistry and developed the 12 principles of Green Chemistry.

 

Volume Editor:

Professor Chao-Jun Li received his Ph.D at McGill University (Montreal, Canada) and did a NSERC Postdoctoral Fellow at Stanford University (USA). He was on the faculty at Tulane University (New Orleans, USA) until 2003. Since 2003, he has been at McGill University where he currently holds a Canada Research Chair (in Green Chemistry) and an E. B. Eddy Chair Professorship. He has published over 300 scientific publications and received numerous awards including the US Presidential Green Chemistry Challenge Award and the Canadian Green Chemistry and Engineering Award. He is a Fellow of the Royal Society of Canada (Academy of Science) and is an Associate Editor for "Green Chemistry" of the Royal Society of Chemistry (UK).