Inorganic and Organometallic Polymers with Special Properties

Softcover Nachdruck of the original 1. Auflage 1992
ISBN: 978-94-010-5154-5
Verlag: Springer Netherlands

Buch, Englisch, Band 206, 435 Seiten, Format (B × H): 155 mm x 235 mm, Gewicht: 692 g

Reihe: NATO Science Series E:

Only in the past decade, has the scientific and industrial community come to realize the potential utility offered by inorganic and organometallic polymers (lOPs) for a wide variety of applications. This potential is especially important for applications requiring multifunctional polymers, e.g. for smart materials, nanotechnology, biomimetic systems (neural networks), photonics, etc; lOPs with special properties. The breadth of perfor­ mance requirements for the individual areas of application is enormous as are the problems pertaining to generating low cost, high performance, processable lOPs. This book represents the third in a series of books we have edited on inorganic and organometallic polymer chemistry (1. Transfonnation of Organometallics into Common and Exotic Materials, NATO ASI Series Vol 141. 2. Inorganic and Organometallic Oligo­ mers and Polymers, Kluwer publications). In this series, we have attempted to identify important trends that help to define for the reader; the potential scope of lOP science as well as the problems that must be surmounted to realize this potential. The focus of the work presented in the following chapters is primarily on the relationships between lOPs and solid state materials with special properties, e.g. conducting, magnetic, photonic and structural materials.

Zielgruppe

Research

Autoren/Hrsg.

Laine, R. M.

Fachgebiete

• Naturwissenschaften Chemie Anorganische Chemie
• Naturwissenschaften Physik Physik Allgemein Theoretische Physik, Mathematische Physik, Computerphysik
• Naturwissenschaften Physik Elektromagnetismus Quantenoptik, Nichtlineare Optik, Laserphysik
• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Werkstoffprüfung

Inhaltsverzeichnis

Framework Science.- Polymers for Multifunctional Applications: Some General Considerations.- An Objective for Polymers with Unusual Properties: Polymers with Delocalized Electronic States.- Ceramics from Organometallic Polymers: Industrial Perspectives.- The Current State of the Art in the Synthesis of Inorganic and Organometallic Polymers.- Polymer Synthesis.- Polymerization of Liquid Crystalline Monomers.- Electrosynthesis, A New Route to Disilanes, Polysilanes and Polycarbosilanes.- Catalytic Dehydro-and Dehydrosilyl-coupling: New Routes to Inorganic and Hybrid Organic/Inorganic Polymers.- Synthesis of Penta-alkoxy-and Penta-aryloxy Silicates Directly from SiO2.- Magnetic Materials.- Molecular Composites of the MPS3 Layered Inorganic Polymers: Chemistry, Magnetic, and Dielectric Properties.- Chemistry, Structures and Magnetic Properties of Mn(II)Cu(II) Molecular Compounds: Heterobinuclear Species, Ferrimagnetic Chains and Molecular-Based Ferromagnets.- Magnetic Molecular Materials.- Conducting And Electronic Materials.- Molecular Solids with Organic Conducting Chains and Inorganic Magnetic Chains: The (Per)2(mnt)2 Family. (M = Ni, Cu, Pd, Pt, Au, Fe and Co).- Selective Synthesis and Some Electroconductive Properties of Organosilicon Polymers Containing Aromatic Units.- Crystal and Electronic Structure of Cobaltacene Intercalates of the Host Lattices SnS2-xSex (x=O, 0.3, 0.5, 1.3, 1.85, 2).- Approaches to Stacked, Semi-conducting Organometallics.- Supramolecular Organization of Phthalocyanines. Design and Synthesis of Low Dimensional Conductors.- Preceramic Materials.- Synthesis and Pyrolysis Chemistry of Polymeric Precursors to SiC and Si3N4.- A Catalytic Preparation of a New Preceramic Polymer: Transformation into SiC.- Transition Metal Oxo Polymers Synthesized via Sol-Gel Chemistry.- Organically Modified Silicates as Inorganic-Organic Polymers.- Nonlinear Optical Materials.- Resonant Nonlinear Optical Excitations in Glassy Polymers.- Rigid-Rod Transition Metal Acetylide Complexes, Oligomers, and Polymers for Nonlinear Optics.- Characterization.- Spectroscopic Characterization of the Pyrolysis Process of Pre-Ceramics Polymers.- Characterisation of Metallophthalocyanine Polymers for Application as Semiconductor Gas Sensor Material.- Aspects of Polyphosphazene Photochemistry.- Characterizing the Microstructures of New Polymers.- Report To Nato.- Inorganic and Organometallic Polymer with Special Properties. Progress, Potential and Problems.