King Organometallic Syntheses

1. Auflage 2013
ISBN: 978-1-4832-9002-7
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, Band Volume 4, 640 Seiten, Web PDF

Reihe: Organometallic Syntheses

Over 160 detailed and tested procedures for the preparation of specific organometallic compounds are given in Volume 4. Part I contains procedures for the synthesis of 76 types of transition metal organometallic compounds, and Part II procedures for the synthesis of 85 nontransition metal organometallic compounds. In both parts, the editors have sought to include procedures that give the safe, reliable synthesis of organometallic compounds that can lay some claim to significance in current chemical research. This significance may be based on various factors such as: (a) the synthesis describes the formation of an unusual or less common structural type; (b) the compound prepared is a useful intermediate in other syntheses; (c) the compound is a model reagent for investigating the mechanisms of various fundamental or industrial processes, such as the Fischer-Tropsch reaction; (d) the compound is a useful reagent in organic synthesis; and (e) the techniques employed in the synthesis of the compound are unusual and worthy of further application, such as metal-atom and electrochemical procedures.Each specific or generalized procedure is organized into the following sections: an Introduction which discusses the available procedures and the reasons guiding the choice of the one selected; a Procedure section which strives to describe the modus operandi, the safety concerns and pitfalls in the preparation; a Properties section that offers further physical and chemical data on the product and, where appropriate, indications of how the compounds can be employed in research; and a Reference section which gives both leading literature citations and supplemental comments on the procedure.Research laboratories in organometallic chemistry, organic chemistry, inorganic chemistry and molecular catalysis have in this book a rich source of information on the preparation of organometallic compounds.

Autoren/Hrsg.

King, R. Bruce

Inhaltsverzeichnis

1;Front Cover;1
2;Organometallic Syntheses;4
3;Copyright Page;5
4;Table of Contents;12
5;Editorial Advisory Board For Volumes 3 And 4 of Organometallic Syntheses;6
6;Introduction;8
7;Preface;10
8;PART I: TRANSITION METAL ORGANOMETALLIC COMPOUNDS;22
8.1;CHAPTER 1. BIS (CYCLOPENTADIENYL) AND MONO- AND BIS (PENTAMETHYLCYCLOPENTADIENYL) METHYL DERIVATIVES OF THE LANTHANIDES: THEIR METHYLLITHIUM ADDUCTS;24
8.1.1;INTRODUCTION;24
8.1.2;PROCEDURE;25
8.1.3;PROPERTIES;28
8.1.4;REFERENCES;28
8.2;CHAPTER 2. (.4-BUTADIENE) BIS (.-PENTAMETHYLCYCLOPENTADIENYL) THORIUM;29
8.2.1;INTRODUCTION;29
8.2.2;PROCEDURE;30
8.2.3;PROPERTIES;30
8.2.4;REFERENCES;31
8.3;CHAPTER 3. [(PHENYLZIRCONOCENYL) METHYLENE] TRIPHENYLPHOSPHORANE;32
8.3.1;INTRODUCTION;32
8.3.2;PROCEDURE;33
8.3.3;PROPERTIES;33
8.3.4;SPECTROSCOPIC DATA;34
8.3.5;REFERENCES;34
8.4;CHAPTER 4. BIS (.5-CYCLOPENTADIENYL) (DICARBONYL) TITANIUM (II);35
8.4.1;INTRODUCTION;35
8.4.2;PROCEDURE;36
8.4.3;PROPERTIES;36
8.4.4;REFERENCES;36
8.5;CHAPTER 5. BIS (.5-CYCLOPENTADIENYL) VANADIUM (VANADOCENE);38
8.5.1;PROCEDURE;39
8.5.2;PROPERTIES;40
8.5.3;REFERENCES AND NOTES;40
8.6;CHAPTER 6. (.5-CYCLOPENTADIENYL) NIOBIUM TETRACHLORIDE AND -TANTALUM TETRACHLORIDE;43
8.6.1;INTRODUCTION;43
8.6.2;PROCEDURE;43
8.6.3;PROPERTIES;44
8.6.4;REFERENCES;44
8.7;CHAPTER 7. (.5-PENTAMETHYLCYCLOPENTADIENYL) NIOBIUM TETRACHLORIDE AND -TANTALUM TETRACHLORIDE;45
8.7.1;INTRODUCTION;45
8.7.2;PROCEDURE;45
8.7.3;PROPERTIES;46
8.7.4;REFERENCES;46
8.8;CHAPTER 8. BIS (.5-CYCLOPENTADIENYL) NIOBIUM DICHLORIDE AND -TANTALUM DICHLORIDE;47
8.8.1;INTRODUCTION;47
8.8.2;PROCEDURE;47
8.8.3;PROPERTIES;47
8.8.4;PROCEDURE;48
8.8.5;PROPERTIES;48
8.8.6;REFERENCES;48
8.9;CHAPTER 9. BIS (.5-PENTAMETHYLCYCLOPENTADIENYL) NIOBIUM DICHLORIDE AND -TANTALUM DICHLORIDE;49
8.9.1;INTRODUCTION;49
8.9.2;PROCEDURE;49
8.9.3;PROPERTIES;50
8.9.4;REFERENCES;50
8.10;CHAPTER 10. OLEFIN COMPLEXES OF NIOBIUM HYDRIDE (III) AND TANTALUM HYDRIDE (III);51
8.10.1;INTRODUCTION;51
8.10.2;PROCEDURE;51
8.10.3;PROPERTIES;53
8.10.4;REFERENCES;53
8.11;CHAPTER 11. BIS (.5-CYCLOPENTADIENYL) (ALLYL) COMPLEXES OF NIOBIUM AND TANTALUM;54
8.11.1;INTRODUCTION;54
8.11.2;PROCEDURE;54
8.11.3;PROPERTIES;55
8.11.4;REFERENCES;55
8.12;CHAPTER 12. BIS (.5-CYCLOPENTADIENYL) (ALLYL) COMPLEXES OF NIOBIUM AND TANTALUM;54
8.12.1;INTRODUCTION;56
8.12.2;PROCEDURE;56
8.12.3;PROPERTIES;58
8.12.4;REFERENCES;59
8.13;CHAPTER 13. MONO- AND BIS (DIENE) COMPLEXES OF TANTALUM;60
8.13.1;INTRODUCTION;60
8.13.2;PROCEDURE;60
8.13.3;PROPERTIES;63
8.13.4;REFERENCES;63
8.14;CHAPTER 14. TRIMETHYLSILYLCYCLOPENTADIENYLNIOBIUM DERIVATIVES;64
8.14.1;INTRODUCTION;64
8.14.2;PROCEDURE;64
8.14.3;PROPERTIES;65
8.15;Part II. CHLORO (TRIMETHYLPHOSPHINE) BIS (.5-TRIMETHYLSILYLCYCLOPENTADIENYL)- NIOBIUM (III);65
8.15.1;INTRODUCTION;65
8.15.2;PROCEDURE;65
8.15.3;PROPERTIES;66
8.16; Part III. METHYLPEROXOBIS (.5-TRIBETHYLSILYLCYCLOPENTADIENYL) NIOBIUM (V);66
8.16.1;INTRODUCTION;66
8.16.2;PROCEDURE;66
8.16.3;PROPERTIES;67
8.16.4;REFERENCES;67
8.17;CHAPTER 15. SODIUM HEXACARBONYLVANADATE (-I);69
8.17.1;INTRODUCTION;69
8.17.2;PROCEDURE;69
8.17.3;PROPERTIES;70
8.17.4;REFERENCES;71
8.18;CHAPTER 16. HEXACARBONYLVANADIUM (O);72
8.18.1;PROCEDURE;72
8.18.2;PROPERTIES;73
8.18.3;REFERENCES;74
8.19;CHAPTER 17. BIS (n5-CYCLOPENTADIENYL) CHROMIUM (CHROMOCENE);75
8.19.1;PROCEDURE;75
8.19.2;PROPERTIES;77
8.19.3;REFERENCES;77
8.20;CHAPTER 18. BIS (TRIPHENYLPHOSPHINE) IMINIUM TETRACARBONYLNTTROSYLCHROMATE;79
8.20.1;INTRODUCTION;79
8.20.2;PROCEDURE;79
8.20.3;PROPERTIES;80
8.20.4;REFERENCES;80
8.21;CHAPTER 19. Cp (CO) 2Mo[NH(R)CH(py)], A MOLYBDENA-AZIRIDINE COMPLEX CONTAINING A MoNC THREE-MEMBERED RING;96
8.21.1;INRODUCTION;96
8.21.2;PROCEDURE;96
8.21.3;STEREOCHEMISTRY;97
8.21.4;PROPERTIES;97
8.21.5;SCOPE OF THE REACTION;97
8.21.6;REACTIONS OF C5H5 (CO) 2Mo[ NH (R) CH (py)];97
8.21.7;REFERENCES;98
8.22;CHAPTER 20. TRANS-DICARBONYL (CYCLOPENTADIENYL) FORMYL (TRIPHENYLPHOSPHINE) MOLYBDENUM;99
8.22.1;INTRODUCTION;99
8.22.2;PROCEDURE;99
8.22.3;PROPERTIES;100
8.22.4;REFERENCES;100
8.23;CHAPTER 21. [.1-N,.1-P-4,5 DIMETHYL-2-(2'-PYRIDYL) PHOSPHININE] TETRACARBONYLCHROMIUM;101
8.23.1;INTRODUCTION;102
8.23.2;PROCEDURE;102
8.23.3;PROPERTIES;103
8.23.4;REFERENCES;104
8.24;CHAPTER 22. ISOCYANOMETHY LENETRIPHENYLPHOSPHORANE AND RELATED SPECIES;105
8.24.1;INTRODUCTION;105
8.24.2;1. ISOCYANOMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE;105
8.24.3;2. ISOCYANOMETHYLTRIPHENYLPHOSPHONIUM HEXAFLUOROPHOSPHATE;106
8.24.4;3. PENTACAHBONYL (TRIPHENYLPHOSPHONIOMETHYLISOCYANIDE) TUNGSTEN HEXAFLUOROPHOSPHATE;107
8.24.5;4. PENTACARBONYL [(FLUORENE–9–YLIDENE) METHYLISOCYANIDE] TUNGSTEN;108
8.24.6;5. PENTACARBONYL [1-PHENYL-3H-4-(TRIPHENYLPHOSPHORANEYLIDENE)-5- IMIDAZOLIDINTHIONE-2-YLIDENE] TUNGSTEN;109
8.25;CHAPTER 23. N–ISOCYANOIMINETRIPHENYLPHOSPHORANE AND RELATED SPECIES;110
8.25.1;INTRODUCTION;110
8.25.2;1. N-ISOCYANOIMINETRIPHENYLPHOSPHORANE;110
8.25.3;2. PENTACARBONYL (ISOCYANOIMINETRIPHENYLPHOSPHORANE) CHROMIUM AND-TUNGSTEN;111
8.25.4;3. PENTACARBONYL (ISOPROPYLIDENE ISOCYANOAMINE) CHROMIUM;112
8.25.5;4. PENTACARBONYL (CYCLOHEXYLIDENE ISOCYANOAMINE) TUNGSTEN;113
8.25.6;5. PENTACARBONYL (ISODIAZOMETHANE) CHROMIUM;113
8.26;CHAPTER 24. ALKYL DERIVATIVES OF OCTAHEDRAL MOLYBDENUM AND TUNGSTEN CLUSTER COMPLEXES;115
8.26.1;INTRODUCTION;115
8.26.2;PROCEDURE;116
8.26.3;PROPERTIES;117
8.26.4;REFERENCES;118
8.27;CHAPTER 25. BIS (TERT.-BUTYL-.5-CYCLOPENTADIENYL) MANGANESE;119
8.27.1;PROCEDURE;119
8.27.2;PROPERTIES;121
8.27.3;REFERENCES;121
8.28;CHAPTER 26. TRISODIUM TETRACARBONYLMETALLATES (-III) OF MANGANESE AND RHENIUM, Na3[M(8)4] ;123
8.28.1;INTRODUCTION;123
8.28.2;PROCEDURE;124
8.28.3;PROPERTIES;125
8.28.4;REFERENCES;126
8.29;CHAPTER 27. CIS-TETRACARBONYLFORMYL (TRIPHENYLPHOSPHINE) MANGANESE;127
8.29.1;INTRODUCTION;127
8.29.2;PROCEDURE;127
8.29.3;PROPERTIES;128
8.29.4;REFERENCES;128
8.30;CHAPTER 28. MER-TRICARBONYLFORMYLBIS (TRIPHENYLPHOSPHITE-P) MANGANESE;129
8.30.1;INTRODUCTION;129
8.30.2;PROCEDURE;129
8.30.3;PROPERTIES;130
8.30.4;REFERENCES;130
8.31;CHAPTER 29. METAL CARBONYL CATIONS WITH CYCLIC PI-HYDROCARBON LIGANDS;131
8.31.1;I. MANGANESE CYCLOHEXADIENYL COMPLEXES;131
8.31.2;II. MANGANESE CYCLOHEPTADIENYL COMPLEXES;135
8.31.3;III. RHENIUM CYCLOHEXADIENYL COMPLEXES;138
8.31.4;IV. DICARBONYL (ALKENE) (ARENE) MANGANESE COMPLEXES;140
8.31.5;ACKNOWLEDGMENT;142
8.31.6;REFERENCES;142
8.32;CHAPTER 30. TRICARBONYL [h3-OCTAHYDROTIRBORATO (1-)] MANGANESE, (CO)3MnB3H8;144
8.32.1;INTRODUCTION;144
8.32.2;PROCEDURE;144
8.32.3;PROPERTIES OF (CO)3MNB3H8;146
8.32.4;REFERENCES;147
8.33;CHAPTER 31. NIDO -2-TRICARBONYL-2-MANGANAHEXABORANE, NIDO -2-(CO)3-2-MnB5H10;148
8.33.1;INTRODUCTION;148
8.33.2;PROCEDURE;148
8.33.3;PROPERTIES OF 2-(CO)3-2-MnB5H10;149
8.33.4;REFERENCES;152
8.34;CHAPTER 32. NIDO-6-TRICARBONYL-6-MANGANATRIDECAHYDRODECABORATE, NIDO-6-(CO)3-6-MnB9H13-, AND ITS DERIVATIVES;153
8.34.1;INTRODUCTION;153
8.34.2;PROCEDURE;153
8.34.3;PROPERTIES;154
8.34.4;REFERENCES;156
8.35;CHAPTER 33. CIS-BIS (TRIFLUOROACETYL) TETRACARBONYLIRON AND CIS-BIS (TRIFLUOROMETHYL) TETRA-CARBONYLIRON;157
8.35.1;INTRODUCTION;157
8.35.2;1. CIS-BIS (TRIFLUOROACETYL) TETRACARBONYLIRON;158
8.35.3;2. CIS-BIS (TRIFLUOROMETHYL) TETRACARBONYLIRON;159
8.35.4;REFERENCES;160
8.36;CHAPTER 34. PERRA- AND RUTHENACYCLOPENTANES, AND .2- ETHENE COMPLEXES OF IRON AND RUTHENIUM;161
8.36.1;INTRODUCTION;161
8.36.2;2 A. Synthesis of tetracarbonyl (.2 -ethene) iron (2ax), tetracar- bonylferracyclopentane (3ax), and -bicyclo [4.3.0] nonane (4ax);164
8.36.3;B. Synthesis of tetracarbonyl (.2 -ethene) ruthenium (2bx), tetra- carbonylruthenacyclopentane (3bx), and -bicyclo [4.3.0] nonane (4bx);166
8.36.4;C. Synthesis of PPh3 substituted tricarbonyl (.2-ethene) iron (2ay), tricarbonylferracyclopentane (3ay), and -bicyclo [4.3.0] nonane;168
8.36.5;REFERENCES;171
8.37;CHAPTER 35. THIOCARBONYL IRON (O) COMPLEXES;172
8.37.1;INTRODUCTION;172
8.37.2;REFERENCES;173
8.38;CHAPTER 36. [(CARBONYLBIS ((DIISOPROPYLAMINO) PHOSPHIDO)] HEXACARBONYLDIIRON;175
8.38.1;INTRODUCTION;175
8.38.2;PROCEDURE;175
8.38.3;PROPERTIES;176
8.38.4;REFERENCES;177
8.39;CHAPTER 37. [(DIISOPROPYLAMINO) TRIPHOSPHINE] HEXACARBONYLDIIRON;178
8.39.1;INTRODUCTION;178
8.39.2;PROCEDURE;179
8.39.3;PROPERTIES;180
8.39.4;REFERENCES;181
8.40;CHAPTER 38. VINYLMETALLOCENES: VINYLFERROCENE,- RUTHENOCENE AND -OSMOCENE; 1,1'-DIVINYLFERROCENE AND - RUTHENOCENE;182
8.40.1;INTRODUCTION;182
8.40.2;PROCEDURE;183
8.40.3;PROPERTIES;184
8.40.4;REFERENCES AND NOTES;185
8.41;CHAPTER 39. METHYL ESTERS OF FERROCENE THIO- AND DITHIO CARBOXYLIC ACIDS;188
8.41.1;INTRODUCTION;189
8.41.2;PROCEDURE;189
8.41.3;PROPERTIES;190
8.41.4;REFERENCES;191
8.42;CHAPTER 40. FERROCENYL PENTACARBONYLMANGANESE;192
8.42.1;INTRODUCTION;192
8.42.2;PROCEDURE;192
8.42.3;PROPERTIES;193
8.42.4;REFERENCES;194
8.43;CHAPTER 41. THERMALLY STABLE 19-ELECTRON Fe (I) AND RELATED COMPLEXES;195
8.43.1;C. (.5-cyclopentadienyl) ( .6-benzene) iron (I);201
8.43.2;D. (.5-cyclopentadienyl) (.5-pentamethylmethylenecyclohexadienyl) iron (II);202
8.43.3;E. (.6-hexamethylbenzene)2 iron (I) hexafluorophosphate;203
8.43.4;F. (.5-hexamethylcyclohexadienyl) (.6-hexamethylbenzene) iron (I)10;204
8.43.5;G. (.10, µ2-C10 H8 {(.6 -C6Me6)Fe} 2+PF6;205
8.43.6;J. Bis [(.5-pentamethylcyclopentadienyl) iron (I) (biphenyl) hexafluorophos-phate;208
8.43.7;Acknowledgments;209
8.43.8;References;209
8.44;CHAPTER 42. .6-DIETHYL PHENYLMALONATE-.5- CYCLOPENTADIENYLIRON HEXAFLUOROPHOSPHATE;211
8.44.1;INTRODUCTION;211
8.44.2;PROCEDURE;211
8.44.3;DISCUSSION;212
8.44.4;REFERENCES;212
8.45;CHAPTER 43. (R,S)-1-5-.5-1-NITRO-6-EXO-(2-OXO-1-PROPYL)- CYCLOHEXADIENYL-.5-CYCLOPENTADIENYL-IRON;214
8.45.1;INTRODUCTION;214
8.45.2;PROCEDURE;215
8.45.3;DISCUSSION;215
8.45.4;REFERENCES;216
8.46;CHAPTER 44. .6-FLUORENONE-.5-CYCLOPENTADIENYLIRON HEXAFLUOROPHOSPHATE;217
8.46.1;INTRODUCTION;217
8.46.2;PROCEDURE;218
8.46.3;DISCUSSION;218
8.46.4;REFERENCES;220
8.47;CHAPTER 45. Alkanediyl Complexes of Iron and Other Transition Metals;221
8.47.1;1. 1,4-Butanediylbis (cyclopentadienyliron dicarbonyl);221
8.47.2;2. 1,4-Butanediylbis(manganese pentacarbonyl);223
8.47.3;3. 1,4-Butanediylbis (cyclopentadienyltungsten tricarbonyl);225
8.47.4;References;226
8.48;CHAPTER 46. .5-CYCLOPENTADIENYLDICARB0NYL (PHENYLTHIOCARBENIUM) IRON HEXAFLUOROPHOSPHATE;228
8.48.1;INTRODUCTION;228
8.48.2;PROCEDURE;229
8.48.3;PROPERTIES;230
8.48.4;REFERENCES;230
8.49;CHAPTER 47. LITHIUM CARBONYL (CARBOXYLATO) (CYCLOPENTADIENYL) (TRIPHENYLPHOSPHINE) FERRATE (l-)1;233
8.49.1;INTRODUCTION;233
8.49.2;PROCEDURE;233
8.49.3;PROPERTIES;234
8.49.4;REFERENCES;234
8.50;CHAPTER 48. POTASSIUM CARBONYL (CARBOXYLATO) (CYCLOPENTADIENYL) (TRIPHENYLPHOSPHINE) FERRATE (1-)1;235
8.50.1;INTRODUCTION;235
8.50.2;PROCEDURE;235
8.50.3;PROPERTIES;236
8.50.4;REFERENCES;236
8.51;CHAPTER 49. HYDROGEN CARBONYL (CARBOXYLATO) (CYCLOPENTADIENYL) (TRIPHENYLPHOSPHINE) FERRATE (1-)1;237
8.51.1;INTRODUCTION;237
8.51.2;PROCEDURE;237
8.51.3;PROPERTIES;238
8.51.4;REFERENCES;238
8.52;CHAPTER 50. DINUCLEAR CYCLOPENTADIENYLRUTHENIUM CARBONYL COMPLEXES;239
8.52.1;1. µ-METHYLENE-µ-CARBONYL-CARBONYL (ACETONITRILE)-bis-[(.-CYCLO-PENTADIENYL) RUTHENIUM];239
8.52.2;2. µ-METHYLENE-µ-CARBONYL-µ-bis (DIPHENYLPHOSPHINO) METHANE-bis-[(.-CYCLOPENTADIENYL) RUTHENIUM];240
8.52.3;3. µ-METHYL-µ-CARBONYL-µ-bis-(DIPHENYLPHOSPHINO) METHANE-bis-[(.- CYCLOPENTADIENYL) RUTHENIUM]-TETRAFLUOROBORATE;242
8.52.4;4. [µ-METHYLIDYNE-µ-CARBONYL-µ-bis-(DIPHENYLPHOSPHINO) METHANE-bis-[(.- CYCLOPENTADIENY) RUTHENIUM]-HEXAFLUOROPHOSPHATE;243
8.52.5;5. µ-ETHYLIDENE-µ-CARBONYL-µ-bis-[CARBONYL (.-PENTAMETHYLCYCLO-PENTADIENYL) RUTHENIUM];245
8.52.6;6. µ-VINYLIDENE-µ-CARBONYL-µ-bis-[CARBONYL (.-PENTAMETHYLCYCLO-PENTADIENYL) RUTHENIUM];247
8.52.7;7. µ-VINYL-µ-CARBONYL-µ-bis[CARBONYL (.-PENTAMETHYLCYCLOPENTA-DIENYL) RUTHENIUM]-TETRAFLUOROBORATE;248
8.53;CHAPTER 51. ENDO- AND EXO-.3-ALLYL (CARBONYL) (.5-CYCLOPENTADIENYL) RUTHENIUM;250
8.53.1;INTRODUCTION;250
8.53.2;PROCEDURE;250
8.53.3;PROPERTIES;251
8.53.4;REFERENCES;251
8.54;CHAPTER 52. COMPLEXES WITHIN THE (.5-C5Me5)Os(CO)(L)X FAMILY;252
8.54.1;SUMMARY;252
8.54.2;INTRODUCTION;252
8.55;CHAPTER 53. SYNTHESIS OF ACTIVATED CLUSTERS OF [M3(CO)12] (M=Ru or Os);257
8.55.1;INTRODUCTION;257
8.55.2;PROCEDURE;257
8.55.3;PROPERTIES;258
8.55.4;PROPERTIES;259
8.55.5;PROPERTIES;260
8.55.6;REFERENCES;260
8.56;CHAPTER 54. THE CHEMICAL ACTIVATION OF THE CLUSTER [Os6(CO) 18]: SYNTHESIS OF [Os6(CO) 18-n (NCMe)n] (n=1 or 2);261
8.56.1;INTRODUCTION;261
8.56.2;A. PREPARATION OF HEPTADECACARBONYL (ACETONITRILE) HEXAOSMIUM;261
8.56.3;B. PREPARATION OF HEXADECACARBONYLBIS (ACETONITRILE) HEXAOSMIUM;262
8.57;CHAPTER 55. HIGH YIELD SYNTHESES OF THE TRANSITION METAL CLUSTER SALTS [N(PPh3) 2]2 [M4 (µ-H)2(CO)12] (M=Ru or Os);264
8.57.1;GENERAL INTRODUCTION;264
8.57.2;PROCEDURE;265
8.57.3;PROPERTIES;266
8.57.4;INTRODUCTION;267
8.57.5;PROCEDURE;267
8.57.6;PROPERTIES;268
8.57.7;ACKNOWLEDGEMENTS;269
8.57.8;REFERENCES;269
8.58;CHAPTER 56. HETERONUCLEAR TRANSITION METAL CLUSTER COMPOUNDS CONTAINING ONE OR TWO GOLD ATOMS;270
8.58.1;INTRODUCTION;270
8.58.2;PROCEDURE;271
8.58.3;PROPERTIES;272
8.58.4;PROCEDURE;273
8.58.5;PROPERTIES;274
8.58.6;ACKNOWLEDGEMENTS;275
8.58.7;REFERENCES;275
8.59;CHAPTER 57. NONACARBONYL-µ-HYDRIDO [µ3-.3-1,3 DIMETHYL 3 ALLENYL) Triangulo-TRIRUTHENIUM (3 Ru-Ru) and NONACARBONYL-µ-HYDRIDO (µ3-.3-1,3 DIMETHYL ALLYL) Triangulo TRIRUTHENIUM (3 Ru-Ru);276
8.59.1;INTRODUCTION;276
8.59.2;PROCEDURE;276
8.59.3;PROPERTIES;277
8.59.4;REFERENCES;278
8.60;CHAPTER 58. NONACARBONYL-µ-HYDRIDO (µ3-.2-t-BUTYLETYNYL) Triangulo-TRIRUTHENIUM (3 Ru-Ru) SILVIO AIME, LUCIANO MILONE and DOMENICO OSELLA;279
8.60.1;INTRODUCTION;279
8.60.2;PROCEDURE;279
8.60.3;PROPERTIES;280
8.60.4;REFERENCES;280
8.61;CHAPTER 59. NONACARBONYL-µ-DIHYDRIDO (µ3-.2-2-PENTYNE) Triangulo-TRIRUTHENIUM (3 Ru-Ru) SILVIO AIME, ROBERTO GOBETTO and DOMENICO OSELLA;281
8.61.1;INTRODUCTION;281
8.61.2;PROCEDURE;281
8.61.3;PROPERTIES;282
8.61.4;REFERENCES;282
8.62;CHAPTER 60. OCTACARBONYL (µ3-.4-1-METHYL, 2-ETHYL, 3,4-DIPHENYL-BUTA-1,3-DIENE-l,4 DIYL) TRIRUTHENIUM (2 Ru-Ru);283
8.62.1;INTRODUCTION;283
8.62.2;PROCEDURE;283
8.62.3;PROPERTIES;284
8.62.4;REFERENCES;284
8.63;CHAPTER 61. IODOTETRACARBONYLCOBALT MIKLÓS TASIa, TIBOR RANGA and GYULA PÁLYIb;285
8.63.1;INTRODUCTION;285
8.63.2;PROCEDURES;286
8.63.3;REFERENCES AND NOTES;287
8.64;CHAPTER 62. ALKOXYCARBONYLCOBALT TETRACARBONYLS MIKLÓS TASIa and GYULA PÁLYIb;289
8.64.1;INTRODUCTION;289
8.64.2;PROCEDURES;291
8.64.3;REFERENCES;292
8.65;CHAPTER 63. (µ2-DIPHOSPHORUS) HEXACARBONYLDICOBALT (Co-Co) AND DERIVATIVES ANNA VIZI-OROSZ, GYULA PÁLYIa, and LÁSZLÓ MARKÓb;295
8.65.1;INTRODUCTION;295
8.65.2;PROCEDURES;297
8.65.3;REFERENCES;299
8.66;CHAPTER 64. .5-METHOXYCARBONYLCYCLOPENTADIENYL-.4-1, 5-CYCLOOCTADIENECOBALT;301
8.66.1;INTRODUCTION;301
8.66.2;PROCEDURE;301
8.66.3;NOTES;302
8.66.4;PROPERTIES;302
8.66.5;REFERENCES;303
8.67;CHAPTER 65. C5H5CO [(NO)2 NORBORNENE], THE PRODUCT OF A THREE COMPONENT SYNTHESIS;304
8.67.1;INTRODUCTION;304
8.67.2;SYNTHESIS;304
8.67.3;PROPERTIES;305
8.67.4;SCOPE OF THE REACTION;305
8.67.5;REACTIONS OF C5H5Co [(NO)2olefin];305
8.67.6;REFERENCES;305
8.68;CHAPTER 66. PREPARATION AND REACTIONS OF (µ-CARBONYL) BIS-(.5-CYCLOPENTADIENYL) (µ-.2-HEXAFLUOROBUT-2-YNE) DIRHODIUM;306
8.68.1;INTRODUCTION;306
8.68.2;PROCEDURE;306
8.68.3;SPECTROSCOPIC PROPERTIES;307
8.68.4;PROCEDURE;307
8.68.5;PROPERTIES;308
8.68.6;PROCEDURE;308
8.68.7;PROPERTIES;309
8.68.8;REFERENCES;310
8.69;CHAPTER 67. METHYL-TRIS (TRIPHENYLPHOSPHINE) COBALT;311
8.69.1;INTRODUCTION;311
8.69.2;PROCEDURE;311
8.69.3;PROPERTIES OF THE PRODUCT;312
8.69.4;REFERENCES;312
8.70;CHAPTER 68. HIGH OXIDATION STATE RHODIUM AND IRIDIUM ORGANOMETALLICS: COMPLEXES OF Rh(IV), Rh(V) AND Ir(V);314
8.70.1;INTRODUCTION;314
8.70.2;REFERENCES;319
8.71;CHAPTER 69. 2-ARYL-2-KETOETHYLCOBALOXIMES AND TRIFLUOROMETHYLCOBALOXIMES;320
8.71.1;INTRODUCTION;320
8.71.2;TRIFLUOROMETHYLCOBALOXIMES;323
8.71.3;ACKNOWLEDGEMENT;326
8.71.4;REFERENCES AND NOTES;326
8.72;CHAPTER 70. ORGANOCOBALT CORRINS;327
8.72.1;ORGANOCOBALAMINS;328
8.72.2;ORGANOCOBINAMIDES;332
8.72.3;ORGANOCOBINAMIDES FROM ORGANOCOBALAMINS;334
8.72.4;TRIFLUOROMETHYLCOBALAMIN35;335
8.72.5;ACKNOWLEDGEMENT;337
8.72.6;REFERENCES AND NOTES;337
8.73;CHAPTER 71. RHODIUM (I) ARYLDIISOCYANIDE POLYMERS;339
8.73.1;EQUATION;339
8.73.2;INTRODUCTION;339
8.73.3;PROCEDURE;340
8.73.4;PROPERTIES;340
8.73.5;REFERENCES;341
8.74;Chapter 72. Preparation of Pentafluorophenyl Derivatives of Nickel, Cobalt, Iron, Palladium, and Platinum via the Corresponding Highly Reactive Metal Powder;342
8.74.1;Preparation of Metal Slurries;342
8.74.2;INTRODUCTION;343
8.74.3;EXPERIMENTAL PROCEDURES;344
8.74.4;LITERATURE REFERENCES;351
8.75;CHAPTER 73. BISLIGAND METALLACYCLOALKANES BY OXIDATIVE COUPLING OF ACTIVATED ALKENES WITH NICKEL (O), PALLADIUM (O) AND PLATINUM (O) COMPOUNDS;353
8.75.1;INTRODUCTION;353
8.75.2;A. BIS (DIMETHYLPHENYLPHOSPHINE)-5-PALLADA-3,3,7,7-TETRAMETHYL-ANTI-TRICYCLO [4.1.0.02,4] HEPTANE;354
8.75.3;B. BIS (DIMETHYLPHENYLPHOSPHINE)-3,3,6,6,9,9,13,13-OCTAMETHYL- 11-PALLADA-ANTI, SYN, ANTI, SYN-PENTACYCLO [10.1.0.02,4.05,7.08,10] TRIDECANE;356
8.75.4;C. BIS (TRIMETHYLPHOSPHINE)-5-PLATINA-3,3,7,7-TETRAMETHYL-ANTI-TRICYCLO [4.1.0.02,4] HEPTANE;357
8.75.5;D. 2,2'-BIPYRIDINE-3,4-BIS (METHYLENE) NICKELACYCLOPENTANE;358
8.75.6;E. 2,2'-BIPYRIDINE-4-NICKELA-DISPIRO [2.2.2.1.] NONANE;359
8.75.7;F. 1,2-BIS (DIMETHYLPHOSPHINO) ETHANE-4-NICKELA-DISPIRO [2.2.2.1.] NONANE;360
8.75.8;G. BIS (TRIMETHYLPHOSPHINE) (OCTA-1,7-DIENE-3,6-DIYL-1,8-DICARBOXYLIC ACID DIMETHYL ESTER) PLATINUM;361
8.75.9;REFERENCES;363
8.76;CHAPTER 74. YLIDE AND METHANIDE PENTAFLUOROPHENYL-GOLD (I) AND GOLD (III) COMPLEXES;365
8.76.1;GENERAL INTRODUCTION;365
8.76.2;1. Methyltriphenylphosphonium bromopentafluorophenylaurate (I);367
8.76.3;2. Pentafluorophenyl (triphenylphosphonium-methylid) gold (I);368
8.76.4;3. Chloro (triphenylphosphonium-methylid) gold (I);369
8.76.5;4. Bis (diphenylphosphino) methanidegold (I) dimer;370
8.76.6;5. [Bis (diphenylphosphino) methanide gold (I)] pentafluorophenylgold (I) dimer;371
8.76.7;6. Chlorobis (pentafluorophenyl) [bis (diphenylphosphino) methane] gold (III);372
8.76.8;7. Bis (pentafluorophenyl) [bis (diphenylphosphino) methane] gold (III);373
8.76.9;8. Bis (pentafluorophenyl) [bis (diphenylphosphino) methanido] gold (III);374
8.76.10;9. Bis {[µ-bis (diphenylphosphino) methanido] [bis (pentafluorophenyl)] gold (III)} gold (I) perchlorate;375
9;PART II: NONTRANSITION METAL ORGANOMETALLIC COMPOUNDS;377
9.1;CHAPTER 75. C,O-DILITHIO-ACETALDEHYDE OXIME MONCEF BELLASSOUED AND MARCEL GAUDEMAR;378
9.1.1;INTRODUCTION;378
9.1.2;PROCEDURE;378
9.1.3;PROPERTIES;378
9.1.4;REFERENCES;379
9.2;CHAPTER 76. 1-(TRIMETHYLSILYL) EPOXYETHYLLITHIUM;380
9.2.1;INTRODUCTION;380
9.2.2;PROCEDURE;381
9.2.3;REFERENCES;382
9.3;CHAPTER 77. 1-(DIETHOXYPHOSPHINYL) EPOXYETHYLLITHIUM;383
9.3.1;INTRODUCTION;383
9.3.2;PROCEDURE;383
9.3.3;PROPERTIES;384
9.3.4;REFERENCES;384
9.4;CHAPTER 78. 3,4-DILITHIO-2,5-DIMETHYL-2,4-HEXADIENE ADALBERT MAERCKER, RALF DUJARDIN, AND FRANZ BRAUERS;385
9.4.1;INTRODUCTION;385
9.4.2;STRUCTURE;387
9.4.3;PROPERTIES;388
9.4.4;REFERENCES;388
9.5;CHAPTER 79. CIS-1,2-DILITHIOCYCLOOCTENE ADALBERT MAERCKER, THOMAS GRAULE, AND ULRICH GIRRESER;389
9.5.1;INTRODUCTION;389
9.5.2;PROCEDURE;389
9.5.3;PROPERTIES;390
9.5.4;REFERENCES;390
9.6;CHAPTER 80. PHENYLSULFONYL (TRIMETHYLSILYL) METHYLLITHIUM;391
9.6.1;INTRODUCTION;391
9.6.2;PROCEDURE;391
9.6.3;PROPERTIES;392
9.6.4;REFERENCES;392
9.7;CHAPTER 81. (E)-1-(PHENYLSULFONYL)-2-(TRIMETHYLSILYL) VINYLLITHIUM AND (Z)-1-(PHENYLSULFONYL)-2-(TRIMETHYLSILYL) VINYLLITHIUM;393
9.7.1;INTRODUCTION;393
9.7.2;PROCEDURE A;393
9.7.3;PROPERTIES;394
9.7.4;REFERENCES;395
9.8;CHAPTER 82. 1-(PHENYLSULFONYL)-2-(TRIMETHYLSILYL) ETHYLLITHIUM AND 1-(PHENYLSULFONYL)-2-(TRIMETHYLSILYL) ETHYLIDENEDILITHIUM;396
9.8.1;INTRODUCTION;396
9.8.2;PROCEDURE A;396
9.8.3;PROCEDURE B;397
9.8.4;PROPERTIES;397
9.8.5;REFERENCES;398
9.9;CHAPTER 83. (Z)-1-(TRIMETHYLSILYL)-1,2-EPOXY-1-OCTYLLITHIUM;399
9.9.1;INTRODUCTION;399
9.9.2;PROCEDURE;399
9.9.3;PROPERTIES;400
9.9.4;REFERENCES;401
9.10;CHAPTER 84. DILITHIUM BIPHENYLIDE;402
9.10.1;INTRODUCTION;402
9.10.2;PROCEDURE;403
9.10.3;PROPERTIES;404
9.10.4;REFERENCES;404
9.11;CHAPTER 85. 1-(TRIPHENYLSILYL) EPOXYETHYLLITHIUM;405
9.11.1;INTRODUCTION;405
9.11.2;PROCEDURE;405
9.11.3;PROPERTIES;407
9.11.4;REFERENCES;407
9.12;CHAPTER 86. TRIS (TRIMETHYLSILYL) SILYLLITHIUM. 3THF;408
9.12.1;INTRODUCTION;408
9.12.2;PROCEDURE;409
9.12.3;PROPERTIES;409
9.12.4;REFERENCES;410
9.13;CHAPTER 87. BIS (BROMOMAGNESIO) METHANE;412
9.13.1;INTRODUCTION;412
9.13.2;PROCEDURE;413
9.13.3;PROPERTIES;413
9.13.4;REFERENCES;414
9.14;CHAPTER 88. l,3-BIS (BROMOMAGNESIO)-2,2-DIMETHYLPROPANE;415
9.14.1;INTRODUCTION;415
9.14.2;PROCEDURE;415
9.14.3;PROPERTIES OF THE PRODUCT;417
9.14.4;REFERENCES;417
9.15;CHAPTER 89. 1-MAGNESACYCLOBUTABENZENE;419
9.15.1;INTRODUCTION;419
9.15.2;PROCEDURE;419
9.15.3;PROPERTIES;420
9.15.4;REFERENCES;420
9.16;CHAPTER 90. DIETHYL-, DI-n-BUTYL- AND DI-n-OCTYLMAGNESIUM FROM MAGNESIUM, HYDROGEN AND 1-ALKENES ;422
9.16.1;INTRODUCTION;422
9.16.2;PROCEDURES;423
9.16.3;PROPERTIES;425
9.16.4;REFERENCES;426
9.17;CHAPTER 91. ORGANOMAGNESIUM INNER COMPLEXES: BIS (3-N,N-DIMETHYL-AMINOPROPYL)-, BIS (4-N,N-DIMETHYLAMINOBUTYL)- AND BIS (4-METHOXYBUTYL) MAGNESIUM;427
9.17.1;INTRODUCTION;428
9.17.2;PROCEDURES;428
9.17.3;PROPERTIES;430
9.17.4;REFERENCES;431
9.18;CHAPTER 92. MAGNESIUM ANTHRACENE · 3THF;433
9.18.1;INTRODUCTION;433
9.18.2;PROCEDURE;433
9.18.3;REFERENCES;435
9.19;CHAPTER 93. CYANOMETHYLZINC BROMIDE NICOLE GOASDOUE AND MARCEL GAUDEMAR;437
9.19.1;INTRODUCTION;437
9.19.2;PROCEDURE;437
9.19.3;PROPERTIES;437
9.19.4;REFERENCES;438
9.20;CHAPTER 94. ETHOXYLCARBONYLMETHYLZINC BROMIDE;439
9.20.1;INTRODUCTION;439
9.20.2;PROCEDURE;439
9.20.3;PROPERTIES;439
9.20.4;REFERENCES;440
9.21;CHAPTER 95. .-FUNCTIONALLY SUBSTITUTED ORGANOZINC COMPOUNDS;441
9.21.1;INTRODUCTION;441
9.21.2;PREPARATION;441
9.21.3;PROPERTIES;442
9.21.4;REFERENCES;443
9.22;CHAPTER 96. CYCLOPENTADIENYLZINC-TRANSITION METAL COMPOUNDS;444
9.22.1;INTRODUCTION;444
9.22.2;PREPARATIONS;444
9.22.3;REFERENCES;447
9.23;CHAPTER 97. DI (CYCLOPENTADIENYL) COMPOUNDS OF GROUP IIB METALS;449
9.23.1;INTRODUCTION;449
9.23.2;PREPARATION;449
9.23.3;PROPERTIES;451
9.23.4;REFERENCES;452
9.24;CHAPTER 98. NIDO-2,3,4,5-TETRACARBAHEXABORANE (6);453
9.24.1;INTRODUCTION;453
9.24.2;PROCEDURE;453
9.24.3;PROPERTIES;454
9.24.4;ACKNOWLEDGEMENTS;454
9.24.5;REFERENCES;455
9.25;CHAPTER 99. TRIETHYLBOROXIN;456
9.25.1;INTRODUCTION;456
9.25.2;PROCEDURE;457
9.25.3;PROPERTIES;458
9.25.4;REFERENCES;459
9.26;CHAPTER 100. 1,2:1,2-BIS (ETHYLBORANEDIYL) DIOXYFUMARATE;460
9.26.1;INTRODUCTION;460
9.26.2;PROCEDURE;461
9.26.3;PROPERTIES;461
9.26.4;REFERENCES;462
9.27;CHAPTER 101. 9-IODO-9-BORABICYCLO [3.3.1] NONANE;463
9.27.1;INTRODUCTION;463
9.27.2;PROCEDURE;464
9.27.3;PROPERTIES;464
9.27.4;REFERENCES;465
9.28;CHAPTER 102. BIS (DIETHYLBORYL) SULFATE;466
9.28.1;INTRODUCTION;466
9.28.2;PROCEDURE;467
9.28.3;PROPERTIES;467
9.28.4;REFERENCES;468
9.29;CHAPTER 103. METHYL 4,6-O-ETHYLBORANEDIYL-2,3-BIS-O-DIETHYLBORYL a-D-GLUCOPYRANOSIDE;469
9.29.1;INTRODUCTION;469
9.29.2;PROCEDURE;470
9.29.3;PROPERTIES;471
9.29.4;REFERENCES;472
9.30;CHAPTER 104. 9-METHANESULFONYLOXY-9-BORABICYCLO [3.3.1] NONANE (MSBBN);473
9.30.1;INTRODUCTION;473
9.30.2;PROCEDURE;474
9.30.3;PROPERTIES;474
9.30.4;REFERENCES;475
9.31;CHAPTER 105. 2,3: 5,6-BIS-O-ETHYLBORANEDIYL-a-D-MANNOFURANOSYL BROMIDE;476
9.31.1;INTRODUCTION;476
9.31.2;PROCEDURE;477
9.31.3;PROPERTIES;478
9.31.4;REFERENCES;479
9.32;CHAPTER 106. 1,1,2,5-TETRAMETHYL-3,4-DIETHYL-1,2-DIHYDRO-1,3-STANNABOROLE;480
9.32.1;INTRODUCTION;480
9.32.2;PROCEDURE;481
9.32.3;PROPERTIES;482
9.32.4;REFERENCES;482
9.33;CHAPTER 107. 1,1: 2,2–BIS (1,5-CYCLOOCTANEDIYL) DIBOROXANE;483
9.33.1;INTRODUCTION;483
9.33.2;PROCEDURE;484
9.33.3;PROPERTIES;484
9.33.4;REFERENCES;485
9.34;CHAPTER 108. FLUORO (DIMESITYL) BORANE;486
9.34.1;INTRODUCTION;486
9.34.2;PROCEDURE;486
9.34.3;PROPERTIES;487
9.34.4;REFERENCES;487
9.35;CHAPTER 109. DIMESITYL (MESITYLETHYNYL) BORANE;488
9.35.1;INTRODUCTION;488
9.35.2;PROCEDURE;489
9.35.3;PROPERTIES;491
9.35.4;REFERENCES;491
9.36;CHAPTER 110. TRIMESITYLBORIRENE;492
9.36.1;INTRODUCTION;492
9.36.2;PROCEDURE;493
9.36.3;PROPERTIES;493
9.36.4;REFERENCES;494
9.37;CHAPTER 111. 1,2-BIS (DIBROMOALUMINO) ETHANE;495
9.37.1;INTRODUCTION;495
9.37.2;PROCEDURE;496
9.37.3;PROPERTIES;496
9.37.4;REFERENCES;497
9.38;CHAPTER 112. 1,1,2,2-TETRACHLORODIMETHYLDISILANE;498
9.38.1;INTRODUCTION;498
9.38.2;PROCEDURE;498
9.38.3;PROPERTIES;498
9.38.4;REFERENCES;499
9.39;CHAPTER 113. 1,1-DIMETHYL-1-SILACYCLOPENT-3-ENE;500
9.39.1;4.1 INTRODUCTION;500
9.39.2;4.2 PROCEDURE;501
9.39.3;4.3 PROPERTIES OF 1,1-DIMETHYL-1-SILACYCLOPENT-3-ENE;502
9.39.4;REFERENCES;502
9.40;CHAPTER 114. 3-SILABICYLO [3.2.1] OCTANE AND ITS 3-GERMA AND 3-STANNA ANALOGUES;506
9.40.1;INTRODUCTION;506
9.40.2;PROCEDURE;506
9.40.3;PROPERTIES;508
9.40.4;REFERENCES;509
9.41;CHAPTER 115. 1,1,2,2-TETRAMETHYL-1,2-DISILACYCLOPENTANE;510
9.41.1;INTRODUCTION;510
9.41.2;PROCEDURE;510
9.41.3;PROPERTIES;511
9.41.4;REFERENCES;511
9.42;CHAPTER 116. 1,1,2,2-TETRAMETHYL-l,2-DISILACYCLOHEXANE;512
9.42.1;INTRODUCTION;512
9.42.2;PROCEDURE;512
9.42.3;PROPERTIES;513
9.42.4;REFERENCES;513
9.43;CHAPTER 117. a-(TRIMETHYLSILYL) BENZYL ALCOHOL;514
9.43.1;INTRODUCTION;514
9.43.2;PROCEDURE;515
9.43.3;PROPERTIES;515
9.43.4;REFERENCES;516
9.44;CHAPTER 118. PHENYLSULFONYL (TRIMETHYLSILYL) METHANE;517
9.44.1;INTRODUCTION;517
9.44.2;PROCEDURE;517
9.44.3;PROPERTIES;518
9.44.4;REFERENCES;518
9.45;CHAPTER 119. 1,4-BIS [TRIMETHYLSILYL]-l,3-BUTADIYNE;519
9.45.1;INTRODUCTION;519
9.45.2;PROCEDURE;519
9.45.3;PROPERTIES;520
9.45.4;REFERENCES;521
9.46;CHAPTER 120. (Z)-1-(PHENYLSULFONYL)-2-(TRIMETHYLSILYL) ETHENE;522
9.46.1;INTRODUCTION;522
9.46.2;PROCEDURE;522
9.46.3;PROPERTIES;523
9.46.4;REFERENCES;523
9.47;CHAPTER 121. (E)-1-(PHENYLSULFONYL)-2-(TRIMETHYLSILYL) ETHENE;524
9.47.1;INTRODUCTION;524
9.47.2;PROCEDURE A;524
9.47.3;PROPERTIES;525
9.47.4;REFERENCES;526
9.48;CHAPTER 122. 1-(PHENYLSULFONYL)-2-(TRIMETHYLSILYL) ETHANE;527
9.48.1;INTRODUCTION;527
9.48.2;PROCEDURE;527
9.48.3;PROPERTIES;528
9.48.4;REFERENCES;528
9.49;CHAPTER 123. DODECAMETHYLCYCLOHEXASILANE;529
9.49.1;INTRODUCTION;529
9.49.2;PROCEDURE;529
9.49.3;PROPERTIES;530
9.49.4;REFERENCES;530
9.50;CHAPTER 124. 1,1-DIMETHYL-3-PHENYL-2-(TRIMETHYLSILYL)-1-SILACYCLOPROPENE;531
9.50.1;INTRODUCTION;531
9.50.2;PROCEDURE;531
9.50.3;PROPERTIES;532
9.50.4;REFERENCES;532
9.51;CHAPTER 125. (TRIMETHYLSILYL) DIPHENYLPHOSPHINE;534
9.51.1;INTRODUCTION;534
9.51.2;PROCEDURE;534
9.51.3;PROPERTIES;535
9.51.4;REFERENCES;536
9.52;CHAPTER 126. 1-METHYL-1-(TRIMETHYLSILYL) DIBENZOSILOLE;537
9.52.1;INTRODUCTION;537
9.52.2;PROCEDURE;537
9.52.3;PROPERTIES;538
9.52.4;REFERENCES;538
9.53;CHAPTER 127. THE SYNTHESIS OF R (+) or S (-) a-NAPHTHYLPHENYLMETHYLSILANE;539
9.53.1;INTRODUCTION;539
9.53.2;PROCEDURE;539
9.53.3;PROPERTIES;540
9.53.4;REFERENCES;541
9.54;CHAPTER 128. EPOXYETHYL (TRIPHENYL) SILANE;542
9.54.1;INTRODUCTION;542
9.54.2;PROCEDURE A;542
9.54.3;PROCEDURE B;543
9.54.4;PROPERTIES;543
9.54.5;REFERENCES;544
9.55;CHAPTER 129. (E)-1-OCTENYL (TRIPHENYL) SILANE;545
9.55.1;INTRODUCTION;545
9.55.2;PROCEDURE;546
9.55.3;PROPERTIES;547
9.55.4;REFERENCES;547
9.56;CHAPTER 130. 1,1-DIMESITYL-3-PHENYL-2-(TRIMETHYLSILYL)-1-SILACYCLOPROPENE;548
9.56.1;INTRODUCTION;548
9.56.2;PROCEDURE;548
9.56.3;PROPERTIES;549
9.56.4;REFERENCES;549
9.57;CHAPTER 131. 1,1-DIMETHYL-2,3,4,5-TETRAPHENYLSILOLE;550
9.57.1;INTRODUCTION;550
9.57.2;PROCEDURE;550
9.57.3;PROPERTIES;551
9.57.4;REFERENCES;551
9.58;CHAPTER 132. (E)-1,2-DIMESITYL-1,2-DI (t-BUTYL) DISILENE;552
9.58.1;INTRODUCTION;552
9.58.2;PROCEDURE;553
9.58.3;PROPERTIES;555
9.58.4;REFERENCES;556
9.59;CHAPTER 133. CHLOROTRIMETHYLGERMANE;557
9.59.1;INTRODUCTION;557
9.59.2;PROCEDURE;557
9.59.3;PROPERTIES;558
9.59.4;REFERENCES;558
9.60;CHAPTER 134. BIS (CHLOROMETHYL) DIMETHYLGERMANE;559
9.60.1;INTRODUCTION;559
9.60.2;PROCEDURE;559
9.60.3;PROPERTIES;560
9.60.4;REFERENCES;561
9.61;CHAPTER 135. 1,2-DICHLORO-1,1,2,2-TETRAMETHYLDIGERMANE;562
9.61.1;INTRODUCTION;562
9.61.2;PROCEDURE;562
9.61.3;PROPERTIES;563
9.61.4;REFERENCES;563
9.62;CHAPTER 136. MESITYLGERMANIUM CHLORIDES: MesGeCl3, Mes2GeCl2 , Mes3GeCl;565
9.62.1;INTRODUCTION;565
9.62.2;PROPERTIES;566
9.62.3;REFERENCES;567
9.63;CHAPTER 137. MESITYLGERMANIUM HYDRIDES: MesGeH3, Mes2GeH2, Mes3GeH;568
9.63.1;INTRODUCTION;568
9.63.2;PROCEDURE;568
9.63.3;PROPERTIES;570
9.63.4;REFERENCES;571
9.64;CHAPTER 138. 2,3,7,8-TETRAMETHYL-5-GERMASPIRO [4.4] NONA-2,7-DIENE;572
9.64.1;INTRODUCTION;572
9.64.2;PROCEDURE;572
9.64.3;PROPERTIES;573
9.64.4;REFERENCES;574
9.65;CHAPTER 139. TRICHLORO (2,4,6-TRI-TERT-BUTYLPHENYL) GERMANE;575
9.65.1;INTRODUCTION;575
9.65.2;PROCEDURE;575
9.65.3;PROPERTIES;576
9.65.4;REFERENCES;577
9.66;CHAPTER 140. TRIORGANOMETALLOMETHANES OF TIN AND LEAD;578
9.66.1;INTRODUCTION;578
9.66.2;PROCEDURE;578
9.66.3;PROPERTIES;580
9.66.4;REFERENCES;581
9.67;CHAPTER 141. BIS (TRIALKYLSTANNYL) ETHYNE;582
9.67.1;INTRODUCTION;582
9.67.2;PROCEDURE;583
9.67.3;PROPERTIES;584
9.67.4;REFERENCES;585
9.68;CHAPTER 142. 1.1-DIMETHYL-3-DIETHYLBORYL-4-ETHYL-1-STANNACYCLOPENTADIENE;586
9.68.1;INTRODUCTION;586
9.68.2;PROCEDURE;586
9.68.3;PROPERTIES;587
9.68.4;RFEERENCES;588
9.69;CHAPTER 143. 1-TRlMETHYLSILYL-3,4-BIS (TRIMETHYLSTANNYL)-3-DECEN-1-YNE: PREPARATION AND REACTIONS;589
9.69.1;INTRODUCTION;589
9.69.2;PROCEDURE;590
9.69.3;PROPERTIES;591
9.69.4;REFERENCES;592
9.70;CHAPTER 144. TRI-n-BUTYL ((E) -1-OCTENYL) TIN;593
9.70.1;INTRODUCTION;593
9.70.2;PROCEDURE;593
9.70.3;PROPERTIES;594
9.70.4;REFERENCES;594
9.71;CHAPTER 145. TRI-n-BUTYL ((E) -1,2-EPOXY-1-OCTYL) TIN;595
9.71.1;INTRODUCTION;595
9.71.2;PROCEDURE;595
9.71.3;PROPERTIES;596
9.71.4;REFERENCES;596
9.72;CHAPTER 146. TRIPHENYLTIN HYDROXIDE AND BIS (TRIPHENYLTIN) OXIDE;597
9.72.1;INTRODUCTION;597
9.72.2;PROCEDURE;597
9.72.3;PROPERTIES;598
9.72.4;REFERENCES;598
9.73;CHAPTER 147. TRIMETHYL (1-PROPYNYL) LEAD;599
9.73.1;INTRODUCTION;599
9.73.2;PROCEDURE;599
9.73.3;PROPERTES;600
9.73.4;REFERENCES;601
9.74;CHAPTER 148. DICHLOROBIS (TRIPHENYLPLUMBYL) METHANE;602
9.74.1;INTRODUCTION;602
9.74.2;PROCEDURE;602
9.74.3;PROPERTIES;603
9.74.4;REFERENCES;604
9.75;CHAPTER 149. TRIMETHYLARSINE;605
9.75.1;INTRODUCTION;605
9.75.2;PROCEDURE;605
9.75.3;PROPERTIES;607
9.75.4;REFERENCES;607
9.76;CHAPTER 150. DIBROMO (PHENYL) STIBINE;608
9.76.1;INTRODUCTION;608
9.76.2;PROCEDURE;608
9.76.3;PROPERTIES;609
9.76.4;REFERENCES;609
9.77;CHAPTER 151. DIMETHYL (p-TOLYLTELLURO) STIBINE;610
9.77.1;INTRODUCTION;610
9.77.2;PROCEDURE;610
9.77.3;PROPERTIES;611
9.77.4;REFERENCES;611
9.78;CHAPTER 152. PHENYLBIS (TRIMETHYLSILYL) STIBINE;612
9.78.1;INTRODUCTION;612
9.78.2;PROCEDURE;612
9.78.3;PROPERTIES;613
9.78.4;REFERENCES;613
9.79;CHAPTER 153. HEXAPHENYLCYCLOHEXASTIBINE;614
9.79.1;INTRODUCTION;614
9.79.2;PROCEDURE;614
9.79.3;PROPERTIES;614
9.79.4;REFERENCES;615
9.80;CHAPTER 154. TETRAMESITYLDISTIBINE;616
9.80.1;INTRODUCTION;616
9.80.2;PROCEDURES;616
9.80.3;PROPERTIES;618
9.80.4;REFERENCES;618
9.81;CHAPTER 155. DIPROPYL (p-TOLYLTELLURO) BISMUTH;619
9.81.1;INTRODUCTION;619
9.81.2;PROCEDURE;619
9.81.3;PROPERTIES;621
9.81.4;REFERENCES;621
9.82;CHAPTER 156. (2,2'-BIPHENYLYLENE) TRIPHENYLBISMUTH (5,5,5-TRIPHENYL-5H-DIBENZO-BISMOLE);622
9.82.1;INTRODUCTION;622
9.82.2;PROCEDURE;622
9.82.3;PROPERTIES;623
9.82.4;REFERENCES;623
9.83;CHAPTER 157. BIS (2,2'-BIPHENYLYLENE) SELENIUM (5,5'-SPIROBI [DIBENZOSELENOPHENE]);624
9.83.1;INTRODUCTION;624
9.83.2;PROCEDURE;624
9.83.3;PROPERTIES;626
9.83.4;REFERENCES;626
9.84;CHAPTER 158. BIS (3-CHLORO-2-PYRIDYL) DITELLURIDE;627
9.84.1;INTRODUCTION;627
9.84.2;PROCEDURE;627
9.84.3;PROPERTIES;628
9.84.4;REFERENCES;628
9.85;CHAPTER 159. TELLURANTHRENE;629
9.85.1;INTRODUCTION;629
9.85.2;PROCEDURE;629
9.85.3;PROPERTIES;630
9.85.4;REFERENCES;630
9.86;CHAPTER 160. BIS (2,2'-BIPHENYLYLENE) TELLURIUM (5,5'-SPIROBI [DIBENZOTELLURO-PHENE]);631
9.86.1;INTRODUCTION;631
9.86.2;PROCEDURE;632
9.86.3;PROPERTIES;632
9.86.4;REFERENCES;633
10;INDEX OF METALS AND LIGANDS;634