King Organometallic Syntheses

1. Auflage 2013
ISBN: 978-1-4832-8993-9
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, Band Volume 3, 686 Seiten, Web PDF

Reihe: Organometallic Syntheses

Organometallic Syntheses, Volume 3 focuses on the synthesis of compounds containing carbon-metal bonds, including ligands, compounds, chlorides, and derivatives. The selection first elaborates on bis(cyclopentadienyl) organolanthanide and organoyttrium chloride, methyl, and hydride complexes and base stabilized alkali metal halide adducts of bis (pentamethylcyclopentadienyl) lanthanide chlorides. The text then examines cyclopentadienyl metal carbonyl and nitrosyl derivatives, ferrocenylamine, cobalticinium and rhodicinium salts, and alkyl transition metal derivatives. The publication takes a look at transition metal complexes containing organophosphorus ligands, transition metal derivatives containing chalcogen ligands, and coinage metal derivatives. The text also reviews transition metal organometallic compounds, including compounds of group IA, IIA, IIB, and IVA. The selection is a vital reference for researchers interested in the synthesis of compounds containing carbon-metal bonds.

Autoren/Hrsg.

King, R. Bruce

Inhaltsverzeichnis

1;Front Cover;1
2;Organometallic Syntheses;4
3;Copyright Page;5
4;Table of Contents;10
5;INTRODUCTION;6
6;PREFACE;8
7;PART I: TRANSITION METAL ORGANOMETALLIC COMPOUNDS;22
7.1;SECTION A: LANTHANIDE AND EARLY TRANSITION METAL COMPOUNDS;22
7.1.1;CHAPTER 1. BIS (CYCLOPENTADIENYL) ORGANOLANTHANIDE AND ORGANOYTTRIUM CHLORIDE, METHYL AND HYDRIDE COMPLEXES;24
7.1.1.1;GENERAL CONSIDERATIONS;24
7.1.1.2;BIS (CYCLOPENTADIENYL) YTTRIUM CHLORIDE;25
7.1.1.3;BIS (CYCLOPENTADIENYL) METHYL YTTRIUM;26
7.1.1.4;THF-SOLVATED BIS (CYCLOPENTADIENYL) YTTRIUM HYDRIDE;27
7.1.1.5;TETRAKIS (TETRAHYDROFURAN) LITHIUM HEXACYCLOPENTADIENYL TRIYTTRIUM TETRAHYDRIDE;29
7.1.1.6;REFERENCES;30
7.1.2;CHAPTER 2. BASE STABILIZED ALKALI METAL HALIDE ADDUCTS OF BIS (PENTAMETHYLCYCLOPENTADIENYL) LANTHANIDE CHLORIDES;32
7.1.2.1;INTRODUCTION;33
7.1.2.2;PROCEDURE;33
7.1.2.3;PROPERTIES;35
7.1.2.4;REFERENCES;35
7.1.3;CHAPTER 3. BIS(.5-CYCLOPENTADIENYL)BIS(TRIMETHYLPHOSPHINE)TITANIUM(II);36
7.1.3.1;EQUATION;36
7.1.3.2;INTRODUCTION;36
7.1.3.3;BIS(7y'-CYCL0PENTADIENYL)BIS(TRIMETHYLPH0SPNINE)TITANIUM(II);37
7.1.3.4;PROPERTIES;37
7.1.3.5;REFERENCES;38
7.1.4;CHAPTER 4. METHYLENE(BIS-.5-CYCLOPENTADIENYL)TITANIUM(IV)-ZINC CHLORIDE IODIDE COMPLEX;39
7.1.4.1;INTRODUCTION;39
7.1.4.2;PROCEDURE;39
7.1.4.3;PROPERTIES;40
7.1.4.4;REFERENCES;41
7.1.5;CHAPTER 5. .5-ALLYL(BIS-.5-CYCLOPENTADIENYL)TITANIUM(III);42
7.1.5.1;INTRODUCTION;42
7.1.5.2;PROCEDURE;42
7.1.5.3;PROPERTIES;43
7.1.5.4;REFERENCES;44
7.1.6;CHAPTER 6. CYCLOPENTADIENYL COMPLEXES OF LOW-VALENT TITANIUM;45
7.1.6.1;DICARBONYLBIS (CYCLOPENTADIENYL) TITANIUM;45
7.1.6.2;TRIMETHYLPHOSPHINED1PHENYLACETYLENEBIS(CYCLOPENTADIENYL)TITANIUM;48
7.1.6.3;CYCLOPENTADIENYL(CYCLOHEPTATRIENYL)TITANIUM;50
7.1.7;CHAPTER 7. (.-CYCLOPENTADIENYL)ZIRCONIUM TRICHLORIDE;52
7.1.7.1;REFERENCES;54
7.1.8;CHAPTER 8. (s-CIS-) AND (s-TRAN5- n4-BUTADIENE)ZIRCONOCENE;55
7.1.8.1;REFEREMCES;57
7.2;SECTION B: METAL CARBONYL DERIVATIVES;55
7.2.1;CHAPTER 9. SOLUTIONS OF Na2CM(CO)5] (. = Cr, Mo, OR W ) , L i 2 C M ( C 0 ) 5 ] (M = Cr OR W ), AND K2[W(CO)5] IN TETRAHYDROFURAN;58
7.2.1.1;INTRODUCTION;58
7.2.1.2;PROCEDURE;59
7.2.1.3;ACKNOWLEDGMENT;62
7.2.1.4;REFERENCES;62
7.2.2;CHAPTER 10. TETRACARBONYLTRICHLOROSILYLIRON(II)HYDRIDE;63
7.2.2.1;INTRODUCTION;63
7.2.2.2;PROCEDURE;63
7.2.2.3;HAZARDS;65
7.2.2.4;PROPERTIES;65
7.2.2.5;REACTIONS;65
7.2.2.6;LITERATURE REFERENCES;65
7.3;SECTION C: CYCLOPENTADIENYL METAL CARBONYL AND NITROSYL DERIVATIVES;66
7.3.1;Chapter 1. Tris-µ-carbonyl-bis[ (.5- pentamethylcyclopentadienyl)manganese] (MrQIn);66
7.3.2;Chapter 2. Bis[( n5-cyclopentadienyl)(µ-nitrosyl)ruthenium](Ru=Ru) [1];68
7.3.3;Chapter 3. Bis[(µ-carbonyl)(.5-pentamethylcyclopentadienyl)rhodium](Rh—Rh);71
7.3.4;Chapter 4. (.5-Acylcyclopentadienyl)dicarbonylcobalt and -rhodium Compounds;73
7.3.5;Chapter 5. DI-µ-carbonyl-bis( .5-pentamethylcyclopentadienyl)-dinickel(l);78
7.3.6;Chapter 6. Cyclopentadienylnitrosyl Complexes of Tungsten;81
7.3.7;Chapter 7. (+)365-and (-)355-Carbonyl(. -cyclopentadienyl)nitrosyl[(S)-N-methyl-N-(1-phenylethyl)amino-diphenylphosphine]molybdenum;92
7.3.8;Chapter 8. (+)436-and (-)436-Carbonyl( .-cyclopentadienyl)iodo[(S)-N-methyl-N-(1-phenylethyl)amino-diphenylphosphine]iron;96
7.3.9;Chapter 9. (+)365- and (-)365-Dicarbonyl( . -cyclopentadienyl)[(S)-a -methyl-N-(2-pyridinylmethylene)-benzenemethaneamine-N, N' JmolybdenumHexafluorophosphate;100
7.4;SECTION D: COMPOUNDS HAVING TWO p-BONDED AROMATIC RINGS;104
7.4.1;Chapter 1. Ferrocenylamine;104
7.4.2;Chapter 2. Cobalticinium and Rhodicinium Salts;107
7.4.3;Chapter 3. (n6-Xanthene)(n5-cyclopentadienyl) iron(ll) Hexafluorophosphate;115
7.4.4;Chapter 4. (n6-2-Methylthianthrene)(n^-cyclopentadienyl)irond(II) Hexafluorophosphate;120
7.4.5;Chapter 5. .-Arene Complexes of Ruthenium(ll) and Osmium(ll);122
7.4.6;Chapter 6. Arene- and Cycloalkene-transition meta I-carborane Sandwich Complexes;127
7.5;SECTION E: OLEFIN, CYCLOBUTADIENE, AND ACETYLENE METAL COMPLEXES;132
7.5.1;Chapter 1. . -Cyclopentadienylbis(ethylene)cobalt(l);132
7.5.2;Chapter 2. 2,2'-Bipyridyl(1,5-cyclooctadiene)nickel;135
7.5.3;Chapter 3. .4-Tetraphenylcyclobutadiene-nickel(II) Bromide Dimer;139
7.5.4;Chapter 4. . 4-Tetraphenylcyclobutadiene(bis-triethylphosphine)nickel;142
7.5.5;Chapter 5. ACETYL ACETYLENE CARBONYL CYCLOPENTADIENYL TUNGSTEN, ACETYLENE CARBONYL CYCLOPENTADIENYL METHYL TUNGSTEN, 2,2-DICARBONYL-2-.5-CYCLOPENTADIENYL-5-METHYL-l,2-OXATUNGSTENOL;145
7.6;SECTION F: ALLYL AND PENTADIENYL TRANSITION METAL DERIVATIVES;151
7.6.1;Chapter 1 . x-Allyl Derivatives of Rhodium(l) and Rhodium(lll);151
7.6.2;Chapter 2. Bis(2,4-dimethylpentadienyl) Complexes of the Transition Metals;159
7.7;SECTION G: ALKYL TRANSITION METAL DERIVATIVES;165
7.7.1;Chapter 1 . Alkylcobalt Carbonyls;165
7.7.2;Chapter 2. ( . 6-Toluene)bis(pentafluorophenyl)nickel(ll);170
7.7.3;Chapter 3. ( .6-Toluene)bis(pentachlorophenyl)nickel(ll);173
7.7.4;Chapter 4. ( n6-Toluene)bis(trichlorosilyl)nickel(ll);176
7.7.5;Chapter 5. ( n6-Toluene)bis(trifluorosilyl)nickel(ll);179
7.7.6;Chapter 6. ( n6-Toluene)bis(pentafluorophenyl)cobalt(ll);181
7.7.7;Chapter 7. Perhalophenyl Derivatives of Palladium(ll) and Platinum(ll);184
7.7.8;Chapter 8. Organo(aquo)cobaloximes;209
7.8;SECTION H: METHYLENE AND METHYLIDYNE TRANSITION METAL COMPLEXES;217
7.8.1;Chapter 1 . Pentacarbonyl[ethoxy(diphenylmethyleneamino)methylene]chromium;217
7.8.2;Chapter 2. Pentacarbonyl[methoxy(phenyl)methyleneamino(diphenylamino)-methylene]chromium;220
7.8.3;Chapter 3 . Pentacarbonyl(diethylaminomethylidyne)chromium- Tetrafluoroborate and -Hexachloroantimonate;222
7.8.4;Chapter 4. Pentacarbonyl[chloro(diethylamino)methylene]chromium;227
7.8.5;Chapter 5. trans-Chloro(tetracarbonyl)(diethylaminomethylidyne)chromium;230
7.8.6;Chapter 6. trans-Bromo(tetracarbonyl)(phenylmethylidyne)tungsten;232
7.8.7;Chapter 7. trans-lodo(tetracarbonyl)(phenylmethylidyne)tungsten;236
7.8.8;Chapter 8.PREPARATION OF Octacarbonylmethylenedi -iron,;239
7.8.9;Chapter 9. µ-Methylene- µ-carbonyl-bis[carbonyl(.-cyclopentadienyl) ruthenium] nancy m. doherty and selby a.r. knox;243
7.8.10;Chapter 10. µ-Ethylidene- µ-carbonyl-bis[carbonyl (n-cyclopentadienyl)ruthenium] nancy m. doherty and selby a.r. knox;245
7.8.11;Chapter 11. µ-.-Propylidene- µ-carbonyl - bis[carbonyl( .-cyclopentadienyl) ruthenium];247
7.8.12;Chapter 12. µ-iso-Propylidene- µ-carbonyl-bis[carbonyl(.-cyclopentadienyl)ruthenium];249
7.8.13;Chapter 13. µ-Benzylidene- µ-carbonyl - bis[carbonyl( .-cyclopentadieny)ruthenium];252
7.8.14;Chapter 14. µ-Methylene-bis[carbonyl(n5-pentamethylcyclopentadienyl)rhodium](Rh—Rh);254
7.8.15;Chapter 15. µ-Cyclobutylidene-bis[carbonyl( .5-pentamethylcyclopentadienyl)rhodium](Rh—Rh);257
7.8.16;Chapter 16. (µ-Carbonyl)(µ-methylene)bis[(n5-pentamethylcyclopentadienyl)cobalt( Co=Co);260
7.8.17;Chapter 17. Dicarbonyldi-tert-butylallenylidenecyclopentadienyl manganese;262
7.8.18;Chapter 18. Carbonyl ( n5 -cyclopentadienyl) ( n2 -4-methylphenylketenyl)-trimethylphosphinetungsten;264
7.8.19;Chapter 19. Carbonyl ( n5-cyclopentadienyl) (4-methylphenylketenyl)-bistrimethylphosphinetungsten;269
7.8.20;Chapter 20. Dicarbonyl (. 5-cyclopentadienyl) (4-methylphenylketenyl) trimethylphosphinetungsten;273
7.9;SECTION I: TRANSITION METAL COMPLEXES CONTAINING ORGANOPHOSPHORUS LIGANDS;277
7.9.1;Chapter 1. Tricarbonylbis(tricyclohexylphosphine)molybdenum(0) and -Tungsten(0);277
7.9.2;Chapter 2. (. 5-3,4-Dimethylphospholyl)tricarbonylmanganese;279
7.9.3;Chapter 3. 3,3',4,4'-Tetramethyl-1,1'-diphosphaferrocene;282
7.10;SECTION J: TRANSITION METAL DERIVATIVES CONTAINING CHALCOGEN LIGANDS;285
7.10.1;Chapter 1. Dithiolato and Hydrosulfido Bridged Dimers of Cyclopentadienylmolybdenum;285
7.10.2;Chapter 2. µ-Sulfur-di(n5-cyclopentadienyl) hexacarbonyl-ditungsten and µ-Thioformaldehyde-di(n5-cyclopentadienyl)tetracarbonyl-ditungsten;290
7.10.3;Chapter 3. µ-Thioformaldehyde-di( n5-cyclopentadienyl)tetracarbonyl-dimanganese;293
7.10.4;Chapter 4. ( µ-Sulfimide)hexacarbonyl-diiron;296
7.10.5;Chapter 5. Pentamethylcyclopentadienyl Dicarbonyl Disulfur Rhenium;299
7.10.6;Chapter 6. Pentamethylcyclopentadienyl Dicarbonyl Diselenium Manganese;302
7.10.7;Chapter 7. Pentakis(acetonitrile)thionitrosyl-chromium Bis(hexafluorophosphate);304
7.10.8;Chapter 8. Pentakis(t-butyl isocyanide)thionitrosyl-chromium Hexafluorophosphate;306
7.10.9;Chapter 9. µ-Seleno-bis[dicarbonyl( . 5-cyclopentadienyl)chromium];308
7.10.10;Chapter 10. µ-Seleno-bis[carbonyl( n 5-pentamethylcyclopentadienyl)rhodium](Rh—Rh);310
7.10.11;Chapter 11. µ -Sulfurdioxide(S)-bis[carbony1( n 5-pentamethylcyclopentadienyl)Rhodium](Rh—Rh);312
7.10.12;Chapter 12. Di-µ-carbonyl· µ -thioformaldehyde-S,S-dioxide(C,S)-bis[( nS-pentamethy-cyclopentadienl)cobalt](Co—Co);314
7.10.13;Chapter 13. Carbonyl(diphenylmethylene)- µ-sulfurdioxide(S)-bis[( n5-pentamethylcyclopentadienyl)rhodium](Rh—Rh);316
7.10.14;Chapter 14. µ-Carbonyl-µ-methylene-µ-sulfurdioxide(S)-bis[(n5-pentamethylcyclopentadienyl)cobalt](Co—Co);318
7.10.15;Chapter 15. Carbon Disulfide Iron(O) Complexes;320
7.10.16;Chapter 16. µ-Tellurio-bis[tricarbony (n5-cyclopentadienyl)chromium];325
7.10.17;Chapter 17. ( µ3-Tellurio)triangulo-bis(tricarbonylferrio)dicarbonyl(n 5-pentamethyl-cyclopentadienyl)manganese (Fe-Fe, 2Fe-Mn);327
7.11;SECTION K: ORGANOMETALLIC DERIVATIVES CONTAINING TWO DIFFERENT TRANSITION METALS;330
7.11.1;Chapter 1. Di-µ-carbony1-[( . 5-pentamethylcyclopentadienyl)cobaltio] n5pentamethyl cyclopentadieny1)iridium(Co-lr);330
7.11.2;Chapter 2. Tris( µ-carbonyl)[{n4-tetramethylcyclobutadiene)cobaltio}(n5-cyclopentadienyl)tungsten](Co=W);332
7.11.3;decacarbonyl-µ-(methoxymethylidyne) (triphenylphosphine)goldtriruthenium;335
7.12;SECTION L: COINAGE METAL DERIVATIVES;338
7.12.1;Chapter 1. Heteronuclear Transition Metal Clusters Containing One or Two Copper or Silver Atoms;338
7.12.2;Chapter 2. Polyaryl Derivatives of Gold(l), Silver(l), and Gold(lll);345
7.12.3;Chapter 3. Pentafluorophenyllithium and Pentafluorophenylsilver;366
7.12.4;Chapter 4. 13c-Methylsilver(I)-tri-n-butylphosphine;369
8;PART II: NONTRANSITION METAL ORGANOMETALLIC COMPOUNDS;374
8.1;SECTION A: COMPOUNDS OF GROUP lA;375
8.1.1;Chapter 1 . N-Butyllithium-Ethyllithium Complex;375
8.1.2;Chapter 2 . 2-Chlorophenyllithium;377
8.1.3;Chapter 3 . (Dilithiomethylene)cyclohexane;379
8.1.4;Chapter 4. Dilithium Pentalenide;381
8.1.5;Chapter 5 . a-Heteroatom Organolithium Compounds by Reductive Lithiation of Substituted Phenylthioethers using Lithium1-(Dimethylamino)naphthalenlde (LDMAN);384
8.1.6;Chapter 6. Hexachloro-5,5'-dilithio-4,4'-bipyridine;392
8.1.7;Chapter 7. Monolithio and Dilithio Derivatives of Phenyl 1-Propynyl sulfone;394
8.1.8;Chapter 8. (Phenylsulfonylmethylene)dilithium;397
8.1.9;Chapter 9. Tetralithiomethane;401
8.1.10;Chapter .0. Alkali Metal Pentamethylcyclopentadienides;404
8.1.11;Chapter 11. Benzylcesium;407
8.1.12;Chapter 12. Dicesium cis- 2, 4A, 4B, 7-Tetrahydro-9, 9-Dimethyl-2, 7-Fluorenediide;412
8.2;SECTION B: COMPOUNDS OF GROUP IIA;414
8.2.1;Chapter 1. Bis(1-indenyl)magnesium;414
8.2.2;Chapter 2. Bis(phenylethynyl)magnesium;416
8.2.3;Chapter 3. n-Butyl(sec-butyl)magnesium;418
8.2.4;Chapter 4. Cinnamylmagnesium Phenoxide;421
8.2.5;Chapter 5. Dicyclopentadienylmagnesium;423
8.2.6;Chapter 6. (Substituted) Magnesacycloalkanes;426
8.3;SECTION C: COMPOUNDS OF GROUP IIB;430
8.3.1;Chapter 1. Benzylzinc bromide;430
8.3.2;Chapter 2. Allenylzinc Bromide;432
8.3.3;Chapter 3. Allylzinc Bromide;434
8.3.4;Chapter 4. The Direct Electrochemical Synthesis of Methyl-, Ethyl-, and Benzy-lzinc Iodide /2,2'-Bipyridine Adducts;436
8.3.5;Chapter 5. Direct Electrochemical Synthesis of Methylcadmium Iodide, Ethylcadmium Iodide and Pentafluorophenylcadmium Bromide/2,2'Bipyridine;440
8.3.6;Chapter 6. 2,2'-Biphenylenemercury, (C12H8Hg)3;447
8.3.7;Chapter 7. Bis(trifluorosilyl)mercury, Bis(trifluoromethyl)mercury and Bis(trifluoromethyl) tris (trimethylphosphine)nickel;449
8.3.8;Chapter 8. Tetrakis(halomercurio)methanes;459
8.3.9;Chapter 9. Tris(halonnercurio)methanes and Bis(halomercurio)methanes;462
8.4;SECTION D: COMPOUNDS OF GROUP IIIA;464
8.4.1;Chapter 1. Bromodi (T-butyl)borane;464
8.4.2;Chapter 2. Dialkylamino (diethynyl) boranes;469
8.4.3;Chapter 3. 9-Mesityl-9, 10-dihydro-9-boraanthracene;473
8.4.4;Chapter 4. Potassium (2-Methyl-1-cyclohexenyloxy)triethylborate;476
8.4.5;Chapter 5. 1-Thexyl-2-cyclohexyl-4-methyl-3-borolene;479
8.4.6;Chapter 6. Tris(T-butyl) borane;482
8.4.7;Chapter 7. Tris(pentafluorophenyl) boron and its Adducts;484
8.4.8;Chapter 8. 1-Acenaphthenyl(diisobutyl)aluminum;486
8.4.9;Chapter 9. (E)-2-Phenyl-1-propenyldimethylaluminum;490
8.4.10;Chapter 10. Tetraethyldialuminoxane, Triisobutyl(hydrido)dialuminoxane and sym-Dichloro(dimethyl)dialuminoxane-Diethyl Ether Complex;495
8.4.11;chaptr 11.cyclopentadientylindum(I);500
8.4.12;Chapter 12. Dimethylthallium Chloride and Bis(trimethylsilylmethyl)thallium Chloride;502
8.4.13;Chapter 13. 2-Methoxy-2-phenylethylthallium Diacetate;505
8.4.14;Chapter 14. Pentamethylcyclopentadienylthallium(l);507
8.4.15;Chapter 15. Phenylthallium Dichloride;510
8.5;SECTION .: COMPOUNDS OF GROUP IVA;512
8.5.1;Chapter 1. 1,2,3,4,5-Pentamethylcyclopentadiene;512
8.5.2;Chapter 2. trans-1,2 Bis(trimethylsilyl)ethylene;515
8.5.3;Chapter 3. 1,3-Bis(trinnethylsilyl)propyne;517
8.5.4;Chapter 4. Chloropentamethyldisilane;519
8.5.5;Chapter 5. 1-Chloro-1-phenyltetramethyldisilane;521
8.5.6;Chapter 6. Dodecamethylcyclohexasilane;523
8.5.7;Chapter 7. Hexakis(2,6-diethylphenyl)cyclotrisilane and Tetrakis(2,6-diethylphenyl)disilene;525
8.5.8;Chapter 8. 1-Lithio-1-phenyl-2-n-butyl-2-(2'-lithiophenyl)ethene as an 507Intermediate for Metallaindene Compounds : 1,1-Dimethyl-2-phenyl-3-n-butylbenzosilole, 1,1,2-Triphenyl-3-n-butylbenzosilole, and 3,3'-Di-n-butyl-2,2'-diphenyl-1,1'spirobi(benzosilole);530
8.5.9;Chapter 9. Octamethyltrisilane;535
8.5.10;Chapter 10. Optically Active Allylsilanes;537
8.5.11;Chapter 11. Pentamethyldisilane;540
8.5.12;Chapter 12. 2-Phenylheptamethyltrisilane;542
8.5.13;Chapter 13. Phenyl 2-(Trimethylsilyl)ethynyl Sulfone;544
8.5.14;Chapter 14. Potassium OrganopentafluorosiIicates;547
8.5.15;Chapter 15. Tetrakis(trimethylsilyl)allene;550
8.5.16;Chapter 16. 1,1,2,2-Tetramethyldisilane;552
8.5.17;Chapter 17. 1,1,1-Trimethyl-2,2-diiodo-2-phenyldisilane;554
8.5.18;Chapter 18. 1,1,1-Trimethyl-2-phenyldisilane and 1,1,1-Trimethyl-2-iododisilane;556
8.5.19;Chapter 19. Trimethyl(2-pyridyl)silane;559
8.5.20;Chapter 20. 1,1,1-Trimethyl-2,2,2-tribromodisilane, 1,1,1-Trimethyl-2,2-dibromo-2-phenyIdisilane and1,1,1-Trimethyl-2-bromo-2,2-diphenyIdisilane;562
8.5.21;Chapter 21. 1,1,2,2-Tetrachloro-1,2-diphenyldisilane;565
8.5.22;Chapter 22. (2E)-1-Trimethylsilyl-3,7-dimethyl-2,6-octadiene (Geranyltrimethylsilane);567
8.5.23;Chapter 23. 1,1-Dialkyl-1-germacyclobutanes;570
8.5.24;Chapter 24. Diethylgermanium Dibromide;573
8.5.25;Chapter 25. 1,1-Dimethyl-1-germa-3-cyclopentene;575
8.5.26;Chapter 26. Diphenylgermanium Dibromide;578
8.5.27;Chapter 27. Hexakis(2,6-diethylphenyl)cyclotrigermane and Tetrakis(2,6-diethyIpheny) digermene;580
8.5.28;Chapter 28. 5,5,10,10-Tetraphenyloctafluorogermanthrene;586
8.5.29;Chapter 29. Bis(pentamethylcyclopentadienyl)tin (Decamethylstannocene) and Bis(pentamethylcyclopentadienyl)germanium ( Decamethylgermanocene);589
8.5.30;Chapter 30. 3,3-Bis(trimethylstannyl)propyl Acetate;592
8.5.31;Chapter 31. Dialkyl(diethynyl)tin;595
8.5.32;Chapter 32. Hexakis(2,6-diethyIphenyl)cyclotristannane;599
8.5.33;Chapter 33. 5-lsopropenyl-2-methyl-3-trimethylstannyl-cyclohexanone;603
8.5.34;Chapter 34. (Pentamethylcyclopentadienyl)tin Tetraf luoroborate and (Pentamethylcyclopentadienyl)germanium Tetrafluoroborate;606
8.5.35;Chapter 35. 1,1,2,4,6-Pentamethyl-1,4-dihydro-1,4-stannaborine;609
8.5.36;Chapter 36. Tetrakis(pentafluorophenyl)tin;614
8.5.37;Chapter 37. 1,1,2,6-Tetramethyl-3,4,5-tr¡ isopropyl-1,4-dihydro-1,4-stannaborine;616
8.5.38;Chapter 38. Tetravinyltin;620
8.5.39;Chapter 39. Biscyclopentadienyllead (Plumbocene);623
8.5.40;Chapter 40. Di-n-butyllead Dichloride;625
8.5.41;Chapter 41. Hexaphenyldilead;627
8.5.42;Chapter 42. Tetra-n-butyllead;629
8.5.43;Chapter 43. Tri-n-butyllead Chloride;631
8.5.44;Chapter 44. Triphenyllead lithium;633
8.6;SECTION F: COMPOUNDS OF GROUP VA;635
8.6.1;Chapter 1. Bis(2,2'-biphenylylene)arsonium Chloride (5,5'-Spirobi [ 5H-dibenzarsolium ]Chloride);635
8.6.2;Chapter 2. Lithium Tris(2,2'-biphenylylene)arsenate;638
8.6.3;Chapter 3. Pentamethylcyclopentaarsine (Arsenomethane);641
8.6.4;Chapter 4. Tetra-_t-butylcyclotetrastibine;644
8.6.5;Chapter 5. Tris(trimethylstannyl)stibine;646
8.6.6;Chapter 6. Tetramethyldistibine;648
8.6.7;Chapter 7. (2,2'-Biphenylylene) triphenylantimony (5,5,5-Triphenyl-5H-dibenzostibole);651
8.6.8;Chapter 8. DODECAFLUORO-1,6-DISTIBATRIPTYCENE (DODECAFLUORO-5,10-o-BENZENOSTIBANTHRENE);653
8.6.9;Chapter 9. Alkyldihalostibines;656
8.6.10;Chapter 10. Tetraethyldibismuthine;659
8.6.11;Chapter 11. Triethylbismuth;661
8.7;SECTION G: COMPOUNDS OF GROUP VIA;21
8.7.1;Chapter 1. 2-Nitrophenyl(phenvl) Selenide;663
8.7.2;Chapter 2. Octafluoroselananthrene;665
8.7.3;Chapter 3. Diphenyl Ditelluride;667
8.7.4;Chapter 4. 4-Methoxyphenyltellurium Trichloride;670
8.7.5;Chapter 5. Tellurium Tetrachloride and its Organotellurium Derivatives;672
9;INDEX OF METALS AND LIGANDS;679