Hozumi / Jiang / Lee Stimuli-Responsive Dewetting/Wetting Smart Surfaces and Interfaces

1. Auflage 2018
ISBN: 978-3-319-92654-4
Verlag: Springer Nature Switzerland
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, Band 11, 467 Seiten

Reihe: Biologically-Inspired Systems

Superhydrophobic surfaces, artificially mimicking lotus leaves, have captured the attention of scientists and engineers over the past few decades. Recent trends have shifted from superhydrophobicity to superominipohobicity, or superamphiphobicity. In addition, dynamic rather than static surface wetting/dewetting properties, which can be triggered by various stimuli, including temperature, pH, magnetic/electric fields, solvents, light exposure etc, have been highly sought after for commercial applications. This book will focus on recent topics related to various stimuli-responsive wetting/dewetting surfaces, and give an overview of the knowledge and concepts of how to design and establish these smart artificial surfaces, which can be used for technical developments in a wide variety research fields.

Atsushi Hozumi is a group leader of Advanced Surface and Interface Chemistry Group, Structural Materials Research Institute, The National Institute of Advanced Industrial Science and Technology (AIST), Nagoya, Japan. He received a PhD in Material Processing Engineering at Nagoya University, Japan, in 1997. He then joined National Industrial Research Institute of Nagoya (NIRIN), Ministry of Trade and Industry, Japan in 1999 (reorganized as AIST in 2001). He also spent 2007 as a visiting scholar at University of Bristol, England (Prof. Stephen Mann's group) and as a visiting professor of University of Massachusetts Amherst, USA (Prof. Thomas J. McCarthy's group). His research interests are wettability/dewettability, biomimetic materials, micro/nanofabrication and self-assembled monolayers, and their practical applications. He currently serves on the editorial boards of the Materials Letters, Elsevier.  Lei Jiang received his B.S. degree in solid state physics (1987), and M.S. degree in physical chemistry (1990) from Jilin University in China. From 1992 to 1994, he studied in the University of Tokyo in Japan as a China-Japan joint course Ph.D. student and received his Ph.D. degree from Jilin University of China with Prof. Tiejin Li. Then, he worked as a postdoctoral fellow in Prof. Akira Fujishima's group in the University of Tokyo. In 1996, he worked as researcher in Kanagawa Academy of Sciences and Technology, Prof. Hashimoto's project. In 1999, he joined Institute of Chemistry, Chinese Academy of Sciences (CAS). In 2015, he moved to the Technical Institute of Physics and Chemistry, CAS. Since 2008, he also served as the dean of School of Chemistry and Environment in Beihang University. He was elected as members of the Chinese Academy of Sciences and The World Academy of Sciences in 2009 and 2012. In 2016, he also elected as a foreign member of the US National Academy of Engineering. He has been recognized for his accomplishments with Humboldt Research Award (Germany, 2017), Nikkei Asia Prize (Japan, 2016), MRS Mid-Career Researcher Award (USA, 2014), National Natural Science Award (China, 2005), and many other honors and awards. He has published over 500 papers including 3 papers in Nature, 1 paper in Science, 1 paper in Nature Nanotechnology, 1paper in Nature Reviews Materials, 1 paper in Nature Materials, 6 papers in Natural Communication, 5 papers in Science Advance, 3 papers in Chem. Rev., 7 papers in Chem. Soc. Rev., 6 papers in Acc. Chem. Res., 46 papers in Angew. Chem. Int. Ed., 31 papers in J. Am. Chem. Soc., and 128 papers in Adv. Mater., the works have been cited more than 56000 times with an H index of 117.Professor Haeshin Lee studied at KAIST where he received his B.S. degree in Biological Sciences between in 1996. He received his Ph.D. degree at Biomedical Engineering Department, Northwestern University in 2007. He started his professional carrier from 2009 at Department of Chemistry, KAIST. He is a currently director of Center for Nature-inspired Technology (CNiT) at KAIST. Haeshin Lee invented the first material-independent surface chemistry named 'polydopamine' in 2007, and this study has been one of the most cited paper in surface chemistry. He is the founding member of Korea Academy of Science Young Scholars and is an Associate Editor in Biomaterials Science (RSC).After graduating from Kyushu University in 1980, Masatsugu Shimomura engaged in the field of biomimetic chemistry as an assistant professor of Prof. Toyoki Kunitake's laboratory. He developed the research of polymeric Langmuir-Blodgett films at Tokyo University of Agriculture and Technology as an associate professor from 1985, and moved to Hokkaido University at 1993 for starting a new laboratory of the bottom-up nanotechnology based on self-organization and biomimetics. Self-organized honeycomb-patterned polymer films are newly developed by collaboration with many industrial companies and the RIKEN institute where he held concurrently post of the principle investigator from 1999 to 2007. After moving to Tohoku University at 2007 he organized a national research project on Engineering Neo-Biomimetics, and started an educational program on biomimetics at Chitose Institute of Science and Technology from 2014. He worked with Prof. Helmut Ringsdorf of Mainz University in 1982 and Prof. Erich Sackmann of TU-Munich in 1987, respectively. He is a Professor emeritus of Hokkaido University and Tohoku University.

Autoren/Hrsg.

Hozumi, Atsushi

Jiang, Lei

Lee, Haeshin

Shimomura, Masatsugu

Inhaltsverzeichnis

1;Preface;6
2;Contents;8
3;Contributors;10
4;Chapter 1: Introduction of Stimuli-Responsive Wetting/Dewetting Smart Surfaces and Interfaces;13
4.1;1.1 Introduction;13
4.2;1.2 Fundamental Theories of Surface Wetting/Dewetting;15
4.2.1;1.2.1 Flat/Smooth Surface;15
4.2.2;1.2.2 Rough Surface;18
4.3;1.3 Preparation Methods of Stimuli-Responsive Smart Surfaces and Interfaces;20
4.4;1.4 Typical Stimuli-Responsive Smart Surfaces and Interfaces;24
4.4.1;1.4.1 Mechanical (Stress/Stretch) Response;24
4.4.2;1.4.2 pH Response;25
4.4.3;1.4.3 Temperature Response;28
4.4.4;1.4.4 Light Response;29
4.4.5;1.4.5 Electric Response;31
4.4.6;1.4.6 Magnetic Response;32
4.4.7;1.4.7 Gas Response;34
4.4.8;1.4.8 Solvent Response;35
4.5;1.5 Summary;39
4.6;References;39
5;Part I: Stimuli-Responsive Dewetting/Wetting Smart Surfaces and Interfaces;46
5.1;Chapter 2: Photo-Responsive Superwetting Surface;47
5.1.1;2.1 Introduction;47
5.1.2;2.2 Switchable Wettability on Photo-Responsive Surfaces;48
5.1.3;2.3 Applications of the Photo-Responsive Surface Wettability;51
5.1.3.1;2.3.1 Photo-Responsive Surface for Droplet Actuation;51
5.1.3.2;2.3.2 Photo-Responsive Surface for Adhesion Control;53
5.1.3.3;2.3.3 Photo-Responsive Surface for Liquid Printing;56
5.1.3.4;2.3.4 Photo-Responsive Surface for Oil-Water Separation;60
5.1.4;2.4 Conclusions and Outlook;60
5.1.5;References;62
5.2;Chapter 3: pH Responsive Reversibly Tunable Wetting Surfaces;67
5.2.1;3.1 Introduction;68
5.2.2;3.2 pH Responsive Tunable Wetting Surfaces;70
5.2.3;3.3 Summary;86
5.2.4;References;86
5.3;Chapter 4: Thermal-Responsive Superwetting Surface;91
5.3.1;4.1 Introduction;91
5.3.2;4.2 Switchable Wettability on Thermal-Responsive Surfaces;92
5.3.2.1;4.2.1 Polymer-Based Thermal-Responsive Surfaces;92
5.3.2.1.1;4.2.1.1 LCST Polymer Surfaces;92
5.3.2.1.2;4.2.1.2 Shape Memory Polymer Surfaces;95
5.3.2.1.3;4.2.1.3 Other Polymer Surfaces;95
5.3.2.2;4.2.2 Inorganic-Oxide-Based Thermal-Responsive Surfaces;96
5.3.3;4.3 Superwetting Surfaces at Diverse Temperatures;96
5.3.3.1;4.3.1 High Temperature;96
5.3.3.2;4.3.2 Low Temperature;98
5.3.4;4.4 Cooperation of Temperature and Other Stimulus-Responsive Superwetting Surfaces;100
5.3.4.1;4.4.1 Dual- Responsive Surfaces;101
5.3.4.2;4.4.2 Multi-Responsive Surfaces;103
5.3.5;4.5 Applications of Thermal-Responsive Superwetting Surfaces;104
5.3.5.1;4.5.1 Thermal-Driven Movement of a Liquid Droplet;104
5.3.5.2;4.5.2 Thermal-Driven Switchable Surfaces Adhesion;105
5.3.5.3;4.5.3 Thermal-Driven Oil-Water Separation;109
5.3.6;4.6 Conclusions and Outlook;110
5.3.7;References;110
5.4;Chapter 5: Electric-Responsive Superwetting Surface;117
5.4.1;5.1 Introduction;117
5.4.2;5.2 Switchable Wettability on Electric-Responsive Surface;118
5.4.2.1;5.2.1 Irreversible Electrowetting on Rough Surface;119
5.4.2.2;5.2.2 Reversible Electrowetting on Rough Surface;121
5.4.2.2.1;5.2.2.1 Reversible Electrowetting on the Nanostructures in Air;121
5.4.2.2.2;5.2.2.2 Reversible Electrowetting in the Liquid/Liquid/Solid;122
5.4.2.2.3;5.2.2.3 Reversible Electrowetting of Liquid Marble in Air;123
5.4.2.2.4;5.2.2.4 Reversible Electrowetting on the Liquid Infused Film;123
5.4.3;5.3 Applications of Electric-Responsive Superwetting Surface;124
5.4.3.1;5.3.1 Electric-Responsive Liquid Actuation;124
5.4.3.2;5.3.2 Electric-Responsive Adhesion Control;126
5.4.3.3;5.3.3 Electric-Responsive Surface for Optical Devices;126
5.4.3.4;5.3.4 Electric-Responsive Liquid Separation;129
5.4.3.5;5.3.5 Photoelectric-Responsive Particles Manipulation;129
5.4.3.6;5.3.6 Photoelectric-Responsive Patterning;132
5.4.3.6.1;5.3.6.1 Self-Assemble Patterning;132
5.4.3.6.2;5.3.6.2 Liquid Patterning for Printing;132
5.4.4;5.4 Conclusions and Outlook;135
5.4.5;References;136
5.5;Chapter 6: Liquids on Shape-Tunable Wrinkles;142
5.5.1;6.1 Introduction;143
5.5.2;6.2 Shape-Tunable Wrinkles;144
5.5.3;6.3 Tunability of the Wetting States and Applications;148
5.5.3.1;6.3.1 Tunable Capillary Phenomena Via Change in Groove Depth;148
5.5.3.2;6.3.2 Light-Induced Capillary Phenomena on Wrinkles;152
5.5.3.3;6.3.3 Patterned Liquids as Templates for Au Nano-Ribbons;155
5.5.3.4;6.3.4 Further Shaping of Liquids Via Transformation of Groove Directions;158
5.5.3.5;6.3.5 Guided Phase Separation of Polymers on Wrinkle Grooves;160
5.5.3.6;6.3.6 Unique Boundary Condition for Nematic Liquid Crystal Alignment;162
5.5.3.7;6.3.7 Unique Boundary Condition for Smectic-A Liquid Crystal Alignment;169
5.5.4;6.4 Summary;171
5.5.5;References;172
5.6;Chapter 7: Solvent Response;178
5.6.1;7.1 Introduction;179
5.6.2;7.2 Polymer Brushes;179
5.6.3;7.3 Organic Solvent Response Surfaces;181
5.6.4;7.4 Aqueous Solution Response Surface;183
5.6.5;7.5 Summary;188
5.6.6;References;188
5.7;Chapter 8: Magnetic-Responsive Superwetting Surface;192
5.7.1;8.1 Introduction;192
5.7.2;8.2 Switchable Wettability on Magnetic-Responsive Surfaces;193
5.7.3;8.3 Applications of the Magnetic-Responsive Superwetting Surface;195
5.7.3.1;8.3.1 Magnetic-Responsive Surface Adhesion;195
5.7.3.2;8.3.2 Magnetic Field Assisted Microstructure Fabrication;198
5.7.3.3;8.3.3 Magnetic-Responsive Liquid Transport;199
5.7.3.4;8.3.4 Magnetic-Responsive Liquid Separation;203
5.7.3.4.1;8.3.4.1 Magnetic-Responsive Separation Based on Micro/Nanoparticles;203
5.7.3.4.2;8.3.4.2 Magnetic-Responsive Separation Based on Sponge;204
5.7.4;8.4 Conclusions and Outlook;208
5.7.5;References;208
6;Part II: Practical Applications;213
6.1;Chapter 9: Stimuli-Responsive Smart Surfaces for  Oil/Water Separation Applications;214
6.1.1;9.1 Introduction;215
6.1.2;9.2 Various Stimuli-Responsive Smart Surfaces for Oil/Water Separation;217
6.1.2.1;9.2.1 Light Responsive Smart Surfaces;217
6.1.2.2;9.2.2 pH Responsive Smart Surfaces;221
6.1.2.3;9.2.3 Temperature Responsive Smart Surfaces;226
6.1.2.4;9.2.4 Gas Responsive Smart Surfaces;230
6.1.2.5;9.2.5 Electric and Magnetic Field Responsive Smart Surfaces;231
6.1.2.6;9.2.6 Dual Stimuli Responsive Smart Surfaces;234
6.1.2.6.1;9.2.6.1 Photo-Thermal Dual Responsive Smart Surfaces;235
6.1.2.6.2;9.2.6.2 pH and Temperature Responsive Smart Surfaces;235
6.1.2.6.3;9.2.6.3 Other Dual/Multiple Responsive Smart Surfaces;238
6.1.3;9.3 Summary;239
6.1.4;References;240
6.2;Chapter 10: Anti-(bio)Fouling;245
6.2.1;10.1 Introduction;245
6.2.2;10.2 Liquid-Infusion Anti-fouling System with Charged Polymer Brushes;248
6.2.2.1;10.2.1 Oil Foulants;248
6.2.2.2;10.2.2 Asphaltenes;251
6.2.2.3;10.2.3 Marine Fouling Organisms;254
6.2.2.3.1;10.2.3.1 Barnacle Cypris Larvae;255
6.2.2.3.2;10.2.3.2 Mussel Larvae;257
6.2.2.3.3;10.2.3.3 Marine Bacteria;258
6.2.3;10.3 Conclusion;259
6.2.4;References;260
6.3;Chapter 11: Toward Enviromentally Adaptive Anti-icing Coating;264
6.3.1;11.1 Introduction;264
6.3.1.1;11.1.1 Definition of Icing;267
6.3.1.2;11.1.2 Evaluation of Anti-icing Property;268
6.3.2;11.2 Anti-icing Coatings;270
6.3.2.1;11.2.1 Correlation Between Wettability and Icephobic Property of a Solid Surface;271
6.3.2.2;11.2.2 Superhydrophobic Surfaces;272
6.3.2.3;11.2.3 Lubricated Coatings;275
6.3.2.3.1;11.2.3.1 Anti-icing Property of SLIPS;276
6.3.2.3.2;11.2.3.2 Slippery Ferrofluid Surfaces;279
6.3.2.3.3;11.2.3.3 Hygroscopic Surfaces;280
6.3.2.3.4;11.2.3.4 Swollen Crosslinked Polymers;283
6.3.2.3.5;11.2.3.5 Integration of Superhydrophobic Surfaces with Other Approach;284
6.3.3;11.3 Summary;285
6.3.4;References;287
6.4;Chapter 12: Stimulus-Responsive Soft Surface/Interface Toward Applications in Adhesion, Sensor and Biomaterial;292
6.4.1;12.1 Introduction;293
6.4.2;12.2 Synthesis of Stimulus-Responsive Soft Surfaces/Interfaces;294
6.4.2.1;12.2.1 Synthesis Methods;294
6.4.2.1.1;12.2.1.1 Controlled/Living Radical Polymerization;295
6.4.2.1.2;12.2.1.2 “Grafting from” Approach;300
6.4.2.1.3;12.2.1.3 “Grafting to” Approach;304
6.4.2.1.4;12.2.1.4 “Grafting Through” Approach;306
6.4.2.1.5;12.2.1.5 Adsorption of Polymer Micelle/Microgel;308
6.4.2.2;12.2.2 Synthesis Methods of Stimulus-Responsive Surfaces/Interfaces;308
6.4.2.2.1;12.2.2.1 pH-Responsive Surfaces;308
6.4.2.2.2;12.2.2.2 Salt-Responsive Surfaces;315
6.4.2.2.3;12.2.2.3 Temperature-Responsive Surfaces;315
6.4.2.2.4;12.2.2.4 Photo-Responsive Surfaces;321
6.4.2.2.5;12.2.2.5 Electric Field-Responsive Surfaces;323
6.4.2.2.6;12.2.2.6 Multi Stimuli-Responsive Surfaces;324
6.4.3;12.3 Characterization of Stimulus-Responsive Surface/Interface;325
6.4.3.1;12.3.1 Spectroscopic Methods;325
6.4.3.1.1;12.3.1.1 Fourier Transform Infrared Spectroscopy (FT-IR);325
6.4.3.1.2;12.3.1.2 Nuclear Magnetic Resonance (NMR) Spectroscopy;326
6.4.3.1.3;12.3.1.3 Sum-Frequency Generation Spectroscopy (SFG);327
6.4.3.2;12.3.2 Radiation Methods;330
6.4.3.2.1;12.3.2.1 Small Angle X-Ray Scattering (SAXS);330
6.4.3.2.2;12.3.2.2 Small Angle Neutron Scattering (SANS);333
6.4.3.2.3;12.3.2.3 Ellipsometry;335
6.4.3.2.4;12.3.2.4 Neutron Reflectometry (NR);337
6.4.3.2.5;12.3.2.5 Light Scattering Methods;342
6.4.3.2.6;12.3.2.6 Laser Diffraction;345
6.4.3.3;12.3.3 Other Methods;347
6.4.3.3.1;12.3.3.1 Atomic Force Microscopy (AFM);347
6.4.3.3.1.1;Imaging;347
6.4.3.3.1.2;Interaction Force Measurements;350
6.4.3.3.2;12.3.3.2 Quartz Crystal Microbalance (QCM);352
6.4.3.3.3;12.3.3.3 Contact Angle;355
6.4.3.3.4;12.3.3.4 Surface Charge;359
6.4.4;12.4 Application of Stimulus-Responsive Surfaces/Interfaces;362
6.4.4.1;12.4.1 Pressure-Sensitive Adhesives (PSAs);362
6.4.4.2;12.4.2 Controlled Lubrication;366
6.4.4.3;12.4.3 Sensors and Actuators;369
6.4.4.3.1;12.4.3.1 pH Responsive Surfaces;370
6.4.4.3.2;12.4.3.2 Thermoresponsive Surfaces;374
6.4.4.3.3;12.4.3.3 Photoresponsive Surfaces;377
6.4.4.3.4;12.4.3.4 Copolymer Systems;379
6.4.4.3.5;12.4.3.5 Lipid Mesophases;379
6.4.4.4;12.4.4 Drug Delivery;379
6.4.4.5;12.4.5 Cell Culture;384
6.4.5;12.5 Concluding Remarks;387
6.4.6;References;388
6.5;Chapter 13: Liquid Manipulation;403
6.5.1;13.1 Droplet Transfer on High Adhesion Superhydrophobic Surfaces;404
6.5.2;13.2 Droplet Sensing on High Adhesion Superhydrophobic Surfaces;408
6.5.3;13.3 Overwritable Liquid Selective Open Channel;412
6.5.4;13.4 Liquid Transport by Modified Open Channel;416
6.5.5;References;419
6.6;Chapter 14: Material-Independent Surface Modification Inspired by Principle of Mussel Adhesion;420
6.6.1;14.1 Introduction;420
6.6.2;14.2 Overview of Mussel Adhesive Proteins;421
6.6.3;14.3 The First Material-Independent Surface Chemistry: Polydopamine Coating;423
6.6.4;14.4 Toxicity of Polydopamine Coating;425
6.6.5;14.5 Polydopamine-Mediated Secondary Surface Derivatization;427
6.6.6;14.6 Polydopamine-Mediated Superhydrophobic Surface Modification and Microfluidics Applications Thereof;429
6.6.7;14.7 Polynorepinephrine-Mediated Surface Functionalization;432
6.6.8;14.8 Catechol-Containing Adhesive Polymers;434
6.6.9;14.9 Conclusion;437
6.6.10;References;437
6.7;Chapter 15: Stimuli-Responsive Mussel-Inspired Polydopamine Material;440
6.7.1;15.1 Introduction;440
6.7.2;15.2 Temperature Responsiveness vs Polydopamine;441
6.7.3;15.3 Light-Responsive Mussel-Inspired Polydopamine;448
6.7.4;15.4 Humidity-Sensitive and Responsive Materials;451
6.7.5;15.5 Conclusion;456
6.7.6;References;456
7;Index;458