New Synthetic Routes to Polyoxometalate Containing Ionic Liquids

An Investigation of their Properties
2015
ISBN: 978-3-658-08795-1
Verlag: Springer

Buch, Englisch, 122 Seiten, Format (B × H): 148 mm x 210 mm, Gewicht: 1956 g

Reihe: BestMasters

In his Master project Sven Herrmann for the first time carried out fundamental investigations into the development of polyoxometalate based ionic liquids (POM-ILs). The POM-ILs were obtained by charge balancing inorganic polyoxometalate (POM) anions with sterically demanding tetraalkylammonium or tetraalkylphosphonium cations. By functionalization of lacunary Keggin clusters with 3d-transition metals and charge balancing with tetraalkylammonium cations of differing chain length, a model system for the correlation of the molecular structure with macroscopic materials properties was obtained. In a systematic approach the syntheses via self-aggregation is presented. Analytic methods comprise UV-Vis, FTIR, NMR, EPR and Mößbauer spectroscopy. For determination of the materials properties TGA and DSC were carried out and rheological studies shed light onto the flow characteristics of the highly viscous materials.

Zielgruppe

Research

Autoren/Hrsg.

Herrmann, Sven

Fachgebiete

• Naturwissenschaften Chemie Analytische Chemie Massenspektrometrie, Spektroskopie, Spektrochemie
• Technische Wissenschaften Verfahrenstechnik | Chemieingenieurwesen | Biotechnologie Biotechnologie
• Naturwissenschaften Chemie Anorganische Chemie

Inhaltsverzeichnis

Polyoxometlates and Ionic Liquids in General.- POM-Ils as New Class of Compounds.- Synthesis and Characterization of POM-ILs.- Reactivity Towards Azide and Carbonmonoxide.

Über Autor(innen)

Sven Herrmann obtained his Masters degree at the University of Erlangen-Nürnberg. He then joined the working group of Prof. Carsten Streb in the inorganic department at the University of Ulm to work on his PhD thesis that targets the development of polyoxometalate based ionic liquids (POM-ILs).