E-Book, Englisch, 142 Seiten, Web PDF
Hanson / Barton / Raphael The Tetracyclic Diterpenes
1. Auflage 2013
ISBN: 978-1-4832-7888-9
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark
E-Book, Englisch, 142 Seiten, Web PDF
ISBN: 978-1-4832-7888-9
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark
International Series of Monographs in Organic Chemistry, Volume 9: The Tetracyclic Diterpenes covers the physico-chemical properties, stereochemistry, reactions, and synthesis of various tetracyclic diterpene compounds. Each chapter of this eight-chapter book describes specific tetracyclic diterpene. The opening chapters focus on the members of the kaurene-phyllocladene class, which are best known and most widely distributed of the tetracyclic diterpenes. The subsequent chapters deal with other classes, including gibberellins, the stachene class, tetracyclic diterpenes alkanoids, and aconite alkaloids. The final chapters consider the synthesis and biosynthesis of tetracyclic diterpenes. This book will prove useful to organic chemists.
Autoren/Hrsg.
Weitere Infos & Material
1;Front Cover;1
2;The Tetracyclic Diterpenes;4
3;Copyright Page;5
4;Table of Contents;6
5;Preface;8
6;Chapter 1. Introduction;10
6.1;Nomenclature;15
6.2;REFERENCES;15
7;Chapter 2. The Kaurene-phyllocladene Class;17
7.1;2.1. Phyllocladene;17
7.2;2.2. Kaurene;21
7.3;2.3. The Kaurenolides and the Stereochemistry of (—)-Kaurene;23
7.4;2.4. The Chemistry of Ring B of the Kaurenolides;26
7.5;2.5. Some Aspects of the Chemistry of Ring D of (—)-Kaurene and the Kaurenolides;27
7.6;2.6. Kauranol;29
7.7;2.7. The Kaurene Acids;29
7.8;2.8. Steviol;32
7.9;2.9. (—)-Kaur-l6-en-l8-oic Acid;34
7.10;2.10. Cafestol and Kahweol;34
7.11;2.11. Atractyligenin;37
7.12;2.12. The seco-Ring B Group of Tetracyclic Diterpenes;38
7.13;2.13. Enmein;39
7.14;2.14. The Grayanotoxins;41
7.15;2.15. The cyclo Kaurane Diterpenes;44
7.16;REFERENCES;46
8;Chapter 3. The Gibberellins;50
8.1;3.1. Introduction;50
8.2;3.2. The Structure of Gibberic Acid;50
8.3;3.3. The Structure of Allogibberic Acid;52
8.4;3.4. The Structure of Gibberellic Acid;54
8.5;3.5. The Stereochemistry of Gibberellic Acid;55
8.6;3.6. The Reduction of Gibberellic Acid;57
8.7;3.7. The C-19-Gibberellins;58
8.8;3.8. The Chemistry of the Gibberellins;60
8.9;3.9. The C-20 Gibberellins;63
8.10;3.10. Gibberellins in Higher Plants;65
8.11;REFERENCES;65
9;Chapter 4. The Stachene Class;69
9.1;4.1. Hibaene;69
9.2;4.2. Stachenone;70
9.3;4.3. 17-Hydroxystachene and Monogynol;71
9.4;4.4. Beyerol;73
9.5;REFERENCES;74
10;Chapter 5. The Tetracyclic Diterpene Alkaloids;75
10.1;5.1. The Garrya Alkaloids;75
10.2;5.2. Garryine and Veatchine;76
10.3;5.3. Cuauchichicine and Garryfoline;77
10.4;5.4. Napelline and Songorine;79
10.5;5.5. Atisine Alkaloids;81
10.6;5.6. Atidine and Ajaconine;84
10.7;5.7. Ignavine and Hypoignavine;85
10.8;5.8. Kobusine and Pseudo-Kobusine;86
10.9;5.9. Hetisine;88
10.10;REFERENCES;89
11;Chapter 6. The Aconite Alkaloids;91
11.1;6.1. Lycoctonine;92
11.2;6.2. Delpheline;95
11.3;6.3. Delcosine and Delsoline;98
11.4;6.4. Browniine;98
11.5;6.5. Aconitine;98
11.6;6.6. Pseudoaconitine;100
11.7;6.7. Bikhaconine;101
11.8;6.8. Chasmanine;101
11.9;6.9. Condelphine, Isotalatizidine, Talatizidine;102
11.10;6.10. Delphinine;103
11.11;6.11. Heteratisine;105
11.12;REFERENCES;105
12;Chapter 7. The Synthesis of the Tetracyclic Diterpenes;108
12.1;7.1. The Synthesis of Phyllocladene-Kaurene;108
12.2;7.2. The Synthesis of the Alkaloids;115
12.3;7.3. The Synthesis of the Gibberellins;117
12.4;REFERENCES;121
13;Chapter 8. The Biosynthesis of the Tetracyclic Diterpenes;123
13.1;REFERENCES;129
14;Appendix: Physical Constants of the Naturally Occurring Tetracyclic Diterpenoids;132
15;Index;138
16;Other Titles in the Series in Organic Chemistry;142
