Modern Cyclophane Chemistry

1. Auflage 2004
ISBN: 978-3-527-30713-5
Verlag: WILEY-VCH

Buch, Englisch, 566 Seiten, Format (B × H): 175 mm x 246 mm, Gewicht: 1229 g

Endlich ein Werk, das den gegenwärtigen Forschungsstand der Cyclophanchemie widerspiegelt! Jeder, der mit Cyclophanen arbeitet, wird von der umfangreichen Sammlung von Beiträgen führender Fachleute profitieren. Unter Federführung zweier hervorragender Herausgeber wurde der Stoff klar strukturiert und übersichtlich nach Themenbereichen geordnet (Synthese und Reaktivität, Strukturen und Analytik, Anwendungen).

Zielgruppe

Chemiker, Organiker, Biochemiker, Metallorganiker

Autoren/Hrsg.

Gleiter, Rolf

Hopf, Henning

Fachgebiete

• Naturwissenschaften Chemie Organische Chemie Organometallchemie
• Naturwissenschaften Chemie Chemie Allgemein Pharmazeutische Chemie, Medizinische Chemie
• Naturwissenschaften Chemie Chemie Allgemein Toxikologie, Gefahrstoffe, Sicherheit in der Chemie
• Naturwissenschaften Chemie Chemie Allgemein Chemometrik, Chemoinformatik
• Naturwissenschaften Chemie Organische Chemie Biochemie
• Naturwissenschaften Chemie Chemie Allgemein Chemische Labormethoden, Stöchiometrie

Inhaltsverzeichnis

a) Synthesis and Reactions

Cyclophynes

Heteraphanes

Highly Strained Cyclophanes

Superphanes

Carbon-Bridged Ferrocenophanes

Endohedral Metalcomplexes of Cyclophanes

Intramolecular Reactions in Cyclophanes

Reactive Intermediates from Cyclophanes

b) Structures

X-Ray Crystal Structures of Porphyrinophanes as Model Compounds for Photoinduced Electron Transfer

Ultraviolet Photoelectron Spectra of Cyclophanes

UV/Vis Spectra of Cyclophanes

Electronic Circular Dichroism of Cyclophanes

Fully Conjugated Beltenes (Beltlike and Tubular Aromatics)

Molecular Electrochemistry of Cyclophanes

NMR Spectra of Cyclophanes

c) Applications

Strained Heteroatom-Bridged Metallocenophanes

Cyclophanes as Templates in Stereoselective Synthesis

Vapor-Based Polymerization of Functionalized [2,2] Paracyclophanes: A Unique Approach towards Surface-Engineered Microenvironments

From Cyclophanes to Molecular Machines

Molecular Recognition Studies with Cyclophane Receptors in Aqueous Solutions

a) Synthesis and Reactions
Cyclophynes
Heteraphanes
Highly Strained Cyclophanes
Superphanes
Carbon-Bridged Ferrocenophanes
Endohedral Metalcomplexes of Cyclophanes
Intramolecular Reactions in Cyclophanes
Reactive Intermediates from Cyclophanes
b) Structures
X-Ray Crystal Structures of Porphyrinophanes as Model Compounds for Photoinduced Electron Transfer
Ultraviolet Photoelectron Spectra of Cyclophanes
UV/Vis Spectra of Cyclophanes
Electronic Circular Dichroism of Cyclophanes
Fully Conjugated Beltenes (Beltlike and Tubular Aromatics)
Molecular Electrochemistry of Cyclophanes
NMR Spectra of Cyclophanes
c) Applications
Strained Heteroatom-Bridged Metallocenophanes
Cyclophanes as Templates in Stereoselective Synthesis
Vapor-Based Polymerization of Functionalized [2,2] Paracyclophanes: A Unique Approach towards Surface-Engineered Microenvironments
From Cyclophanes to Molecular Machines
Molecular Recognition Studies with Cyclophane Receptors in Aqueous Solutions

Über Autor(innen)

Born in 1940, Henning Hopf is Director of the Institute for Organic Chemistry at the TU Braunschweig. After studying chemistry in Goettingen and at the University of Wisconsin in Madison, where he gained his doctorate 1967, he qualified as a professor in 1972 at the University of Karlsruhe. Three years later he was offered a chair at the University of Wuerzburg and from there followed an offer of a professorship at Braunschweig in 1979. His
main areas of research concern hydrocarbon chemistry (alkines, allenes, cumulenes, aromats, cyclophanes, polyolefines, etc.) and mechanistic investigations of high-temperature reactions.


Rolf Gleiter is professor of chemistry at the Universitat Heidelberg. He studied chemistry and finished his doctoral thesis under the supervision of F. Effenberger in Stuttgart in 1964. From 1965 - 1968 he did postdoctoral work in the US, one year with P. v. R. Schleyer at Princeton and two years with R. Hoffmann at Cornell. He completed his habilitation with E. Heilbronner in Basel in 1972. In 1973 he moved as full professor to TU Darmstadt. In 1979 he took his present position. R. Gleiter is interested in intra- and intermolecular bonding properties by synthesizing model systems and investigation of their interactions by physical measurements supported by quantum chemical calculations.