Fürstner / Li / Moloney Science of Synthesis Knowledge Updates 2010 Vol. 1

1. Auflage 2014
ISBN: 978-3-13-178631-9
Verlag: Thieme
Format: EPUB
Kopierschutz: Adobe DRM (»Systemvoraussetzungen)

E-Book, Englisch, 580 Seiten, ePub, Format (B × H): 170 mm x 240 mm

The Science of Synthesis Editorial Board,together with the volume editors and authors, is constantly reviewing the whole field of synthetic organic chemistry as presented in Science of Synthesis and evaluating significant developments in synthetic methodology. Four annual volumes updating content across all categories ensure that you always have access to state-of-the-art synthetic methodology.

Content of this volume:
Germanium cyanides, acylgermanes, a-halo- and a-alkoxyvinylgermanes, a-halo-, a-hydroxy-, a-alkoxy-, and a-aminoalkylgermanes, alkynylgermanes, aryl- and heteroarylgermanes, propargyl- and allenylgermanes, selenophenes,
tellurophenes, isoxazoles, 1,2-benzisoxazoles and related compounds, benzoxazoles and other annulated oxazoles, isothiazoles, benzisothiazoles, benzothiazoles, isoselenazoles, annulated isoselenazole compounds, selenazoles, annulated selenazole compounds, isotellurazoles, and annulated isotellurazole and tellurazole compounds, pyridopyrazines and iodoarenes.

Zielgruppe

Wissenschaftler

Autoren/Hrsg.

Fürstner, Alois

Hämmerle, Johanna

Härtinger, Stefan

I, Heraklidia

Li, Jie Jack

Moloney, Mark G.

Ramsden, Christopher A.

Schaumann, Ernst

Fachgebiete

• Naturwissenschaften Chemie Organische Chemie

Leseproben

Abstracts

5.1.1.8 Germanium Hydrides

This manuscript is an update to the earlier contribution describing methods for the synthesis of germanium hydrides, their properties, and synthetic reactions. It focuses on the literature published in the period 2001–2009.

Keywords: germanes · germanium compounds · hydrides · germyl hydride · germanium hydride · radical reduction · hydrogermylation · germylation · tris(2-furyl)germane · cross coupling · germyl cation

5.1.15.2 Germanium Cyanides

This manuscript is an update to the earlier contribution describing methods for the synthesis of germanium cyanides, their properties, and synthetic reactions. It focuses on the literature published in the period 2001–2009.

Keywords: germanes · germanium compounds · cyanides · cyanation · halides · silver · germole

5.1.16.6 Acylgermanes

This manuscript is an update to the earlier contribution describing methods for the synthesis of acylgermanes, their properties, and synthetic reactions. It focuses on the literature published in the period 2001–2009.

Keywords: germanes · germanium compounds · enol ethers · [2+2] cycloaddition · azetidines · BINAP · alkynes · carbonylation · furans · radicals · polymerization · amides

5.1.18.4 a-Halo- and a-Alkoxyvinylgermanes

This manuscript is an update to the earlier contribution describing methods for the synthesis of a-halo- and a-alkoxyvinylgermanes, their properties, and synthetic reactions. It focuses on the literature published in the period 2001–2009.

Keywords: germanes · germanium compounds · substitution · hydrometalation · carbometalation · halogenation · alkynes · germatranes · desulfonylation · cross coupling · palladium(0) · styrenes

5.1.19.7 a-Halo-, a-Hydroxy,- a-Alkoxy-, and a-Aminoalkylgermanes

This manuscript is an update to the earlier contribution describing methods for the synthesis of a-halo-, a-hydroxy-, a-alkoxy-, and a-aminoalkylgermanes, their properties, and synthetic reactions. It focuses on the literature published in the period 2001–2009.

Keywords: germanes · germanium compounds · [1,2] rearrangements · oxo-carbenium · oxonium · substitution · hydroboration · boronic ester · [3+2] cycloaddition · germenes · silylation · borylation

5.1.20.4 Alkynylgermanes

This manuscript is an update to the earlier contribution describing methods for the synthesis of alkynylgermanes, their properties, and synthetic reactions. It focuses on the literature published in the period 2001–2009.

Keywords: germanes · germanium compounds · alkynes · [3+2] cycloadditions · hydrostannylation · hydroboration · cross coupling · palladium(0) · substitution · cross metathesis · elimination · Pauson–Khand reaction · cyclopentenones

5.1.22.6 Aryl- and Heteroarylgermanes

This manuscript is an update to the earlier contribution describing methods for the synthesis of aryl- and heteroarylgermanes, their properties, and synthetic reactions. It focuses on the literature published in the period 2001–2009.

Keywords: germanes · germanium compounds · cross coupling · Stille reaction · Hiyama–Denmark reaction · substitution · Barbier conditions · transmetalation · cycloaddition · solid-phase synthesis · traceless linkers

5.1.23.6 Vinylgermanes

This manuscript is an update to the earlier contribution describing methods for the synthesis of vinylgermanes, their properties, and synthetic reactions. It focuses on the literature published in the period 2001–2009.

Keywords: germanes · germanium compounds · vinylgermanes · alkenylgermanes · ß-effect · hyperconjugation · hydrogermylation · heterogermylation · metallogermylation · cross coupling · germatranes

5.1.24.4 Propargyl- and Allenylgermanes

This manuscript is an update to the earlier contribution describing methods for the synthesis of propargyl- and allenylgermanes, their properties, and synthetic reactions. It focuses on the literature published in the period 2001–2009.

Keywords: germanes · germanium compounds · propargylgermanes · allenylgermanes · transmetalation · Grignard reagents · [2+2] cycloaddition

5.1.25.3 Benzylgermanes

This manuscript is an update to the earlier contribution describing methods for the synthesis of benzylgermanes, their properties, and synthetic reactions. It focuses on the literature published in the period 2001–2009.

Keywords: germanes · germanium compounds · benzylgermanes · cross coupling · boscalid

5.1.26.6 Allylgermanes

This manuscript is an update to the earlier contribution describing methods for the synthesis of allylgermanes, their properties, and synthetic reactions. It focuses on the literature published in the period 2001–2009.

Keywords: germanes · germanium compounds · alkenylgermanes · allylation · germylene · p-allylpalladium(0) · metallogermanes · Baylis–Hillman · germyl radicals

5.1.27.4 Alkylgermanes

This manuscript is an update to the earlier contribution describing methods for the synthesis of alkylgermanes, their properties, and synthetic reactions. It focuses on the literature published in the period 2001–2009.

Keywords: germanes · germanium compounds · alkenylgermanes · ADMET · germylene · hydrogermylation

9.11.4 Selenophenes

This manuscript is intended to update the first report on the synthesis of selenophenes in and will briefly summarize essential, more recent findings concerning this heterocyclic system in the first decade of the new millennium. During this time, applications of selenophene-based materials in organic electronics and photonics received considerable interest, and selenophene-containing p-conjugated compounds have been proposed as organic magnetic materials.

Keywords: selenophenes · active methylene compounds · selanylenynes · cyclization · aromatization · metal–halogen exchange

9.12.3 Tellurophenes

This manuscript is intended to update the earlier report on the synthesis of tellurophenes in , and summarizes essential, more recent findings concerning this heterocyclic system in the first decade of the new millennium. The decade 2000–2010 saw an increasing interest in organic molecules as functional materials, shifting the focus away from biological or pharmaceutical application. This trend could especially be observed for thiophenes, leading, not surprisingly, also to an increasing pursuit of potential applications of tellurophenes.

Keywords: tellurophenes · tellanylenynes · cyclization · aryl cross coupling

11.9.5 Isoxazoles

This manuscript is an update to the earlier contribution describing methods for the synthesis of isoxazoles (1,2-oxazoles). It focuses on the literature published in the period 2001–2009.

Keywords: isoxazoles · isoxazol-5-ones · dipolar cycloadditions · oximes · nitrile oxides · cyclization · multicomponent coupling · regioselectivity

11.10.5 1,2-Benzisoxazoles and Related Compounds

This update deals with...