Theoretical Aspects of Transition Metal Catalysis

1. Auflage. Softcover version of original hardcover Auflage 2005
ISBN: 978-3-642-06251-3
Verlag: Springer

Buch, Englisch, Band 12, 266 Seiten, Paperback, Format (B × H): 155 mm x 235 mm, Gewicht: 423 g

Reihe: Topics in Organometallic Chemistry

Transition metal catalysis belongs to the most important chemical research areas because a ubiquitous number of chemical reactions are catalyzed by transition metal compounds. Many efforts are being made by industry and academia to find new and more efficient catalysts for chemical processes. Transition metals play a prominent role in catalytic research because they have been proven to show an enormous diversity in lowering the activation barrier for chemical reactions. For many years, the search for new catalysts was carried out by trial and error, which was costly and time consuming. The understanding of the mechanism of the catalytic process is often not very advanced because it is difficult to study the elementary steps of the catalysis with experimental techniques. The development of modern quantum chemical methods for calculating possible intermediates and transition states was a breakthrough in gaining an understanding of the reaction pathways of transition metal catalyzed reactions. This volume, organized into eight chapters written by leading scientists in the field, illustrates the progress made during the last decade. The reader will obtain a deep insight into the present state of quantum chemical research in transition metal catalysis.

Zielgruppe

Research

Autoren/Hrsg.

Frenking, Gernot

Fachgebiete

• Naturwissenschaften Chemie Organische Chemie Organometallchemie
• Naturwissenschaften Chemie Anorganische Chemie Nichtmetallische Chemie
• Medizin | Veterinärmedizin Medizin | Public Health | Pharmazie | Zahnmedizin Klinische und Innere Medizin Immunologie
• Naturwissenschaften Chemie Organische Chemie Biochemie
• Naturwissenschaften Chemie Physikalische Chemie Quantenchemie, Theoretische Chemie

Inhaltsverzeichnis

D.G. Musaev, K. Morokuma: Transition Metal Catalyzed s-Bond Activation and Formation Reactions.- S. Sakaki: Theoretical Studies of C-H s-Bond Activation and Related Reactions by Transition-Metal Complexes.- G. Drudis-Solé, G. Ujaque, F. Maseras and A. Lledós: Enantioselectivity in the Dihydroxylation of Alkenes by Osmium Complexes.- D.V. Deubel, C. Loschen and G. Frenking: Organometallacycles as Intermediates in Oxygen-Transfer Reactions. Reality or Fiction?.- A. Michalak, T. Ziegler: Late Transition Metals as Homo- and Co-Polymerization Catalysts.- S. Tobisch: Co-Oligomerization of 1,3-Butadiene and Ethylene Promoted by Zerovalent ‘Bare’Nickel Complexes.- V. Staemmler: The Cluster Approach for the Adsorption of Small Molecules on Oxide Surfaces