Ebsworth / Taube / Maddock Volatile Silicon Compounds

International Series of Monographs on Inorganic Chemistry
1. Auflage 2013
ISBN: 978-1-4831-8055-7
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 188 Seiten, Web PDF

Volatile Silicon Compounds tackles the properties of volatile silicon compounds from both organic and inorganic perspectives. The title integrates the discussion on molecular structure and chemical properties. The opening chapter provides an introductory discourse on atomic properties. Next, the selection seals with SiH bond and the halides of silicon. The subsequent chapters discuss compounds containing silicon bound to various elemental groups. The text also covers other silicon compounds, such pseudohalogen derivatives and metal derivatives of silanes. The book will be of great use to students of chemistry related degrees.

Autoren/Hrsg.

Ebsworth, E. A. V.

Taube, H.

Maddock, A. G.

Inhaltsverzeichnis

1;Front Cover;1
2;Volatile Silicon Compounds;4
3;Copyright Page;5
4;Table of Contents;6
5;PREFACE;8
6;CHAPTER 1. INTRODUCTION: ATOMIC PROPERTIES;11
7;CHAPTER 2. THE SiH BOND;19
7.1;1. Formation;19
7.2;2. Physical properties;22
7.3;3. Chemical properties;33
8;CHAPTER 3. THE HALIDES OF SILICON;55
8.1;1. Formation of silicon-halogen bonds;55
8.2;2. Preparation of halosilanes;55
8.3;3. Physical properties;57
8.4;4. Chemical properties;65
8.5;5. Halides of germanium (IV) and tin (IV;75
9;CHAPTER 4. COMPOUNDS CONTAINING SILICON BOUND TO ELEMENTS OF GROUP IV;83
9.1;1. The silicon-carbon bond;83
9.2;2. The silicon-silicon bond;92
10;CHAPTER 5. COMPOUNDS CONTAINING SILICON BOUND TO ELEMENTS OF GROUP V;108
10.1;1. Silylamines;108
10.2;2. Silyl phosphines and arsines;124
11;CHAPTER 6. COMPOUNDS CONTAINING SILICON BOUND TO ELEMENTS OF GROUP VI;129
11.1;1. Compounds containing SiO bonds;129
11.2;2. Compounds containing silicon-sulphur bonds;140
11.3;3. Silyl selenides;146
12;CHAPTER 7. OTHER SILICON COMPOUNDS;151
12.1;1. Pseudohalogen derivatives;151
12.2;2. Compounds containing silicon bound to transition elements;159
12.3;3. Compounds containing silicon-boron bonds;159
12.4;4. Metal derivatives of silanes;160
13;CHAPTER 8. CONCLUSIONS;163
14;INDEX;172