E-Book, Englisch, 126 Seiten, Web PDF
Earnshaw Introduction to Magnetochemistry
1. Auflage 2013
ISBN: 978-1-4832-7069-2
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark
E-Book, Englisch, 126 Seiten, Web PDF
ISBN: 978-1-4832-7069-2
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark
Introduction to Magnetochemistry provides an introduction to the more important aspects of magnetochemistry. The measurement of magnetic moment has been one of the most consistently useful to coordination chemists. For teaching purposes it provides a simple method of illustrating the ideas of electronic structure, and in research it can provide fundamental information about the bonding and stereochemistry of complexes. The book contains six chapters covering topics such as free atoms and ions, transition metal complexes, crystal field theory, second and third row transition metal complexes, antiferromagnetism, and spin-pairing of electrons. The final chapter describes important experimental methods and then to shows briefly the way in which the problems of interpretation may be tackled.
Autoren/Hrsg.
Weitere Infos & Material
1;Front Cover;1
2;Introduction to Magneto Chemistry
;4
3;Copyright Page
;5
4;Table of Contents;8
5;PREFACE;6
6;DEFINITIONS OF SYMBOLS;10
7;Chapter I. INTRODUCTION;12
7.1;DIAMAGNETIC CORRECTIONS;15
8;Chapter II. FREE ATOMS AND IONS;20
8.1;SINGLE ELECTRON SYSTEM;20
8.2;MULTI-ELECTRON SYSTEMS;24
9;Chapter III. TRANSITION METAL COMPLEXES;43
9.1;VALENCE BOND THEORY;44
9.2;CRYSTAL FIELD THEORY;49
10;Chapter IV. CRYSTAL FIELD THEORY;56
10.1;VAN VLECK'S FORMULA FOR SUSCEPTIBILITY;56
10.2;STRENGTH OF LIGAND FIELDS;59
10.3;WEAK FIELD CASE;60
10.4;STRONG FIELD CASE;63
10.5;TERM SPLITTING AND ELECTRON CONFIGURATION;67
10.6;SPIN-ORBIT COUPLING ON A AND E TERMS;69
10.7;SPIN-ORBIT COUPLING ON T TERMS;71
10.8;SECOND ORDER ZEEMAN EFFECT;77
11;Chapter V. FURTHER TOPICS;81
11.1;SECOND AND THIRD ROW TRANSITION METAL COMPLEXES;81
11.2;ANTIFERROMAGNETISM;83
11.3;SPIN FREE-SPIN PAIRED EQUILIBRIA;93
12;Chapter VI. EXPERIMENTAL;95
12.1;MEASUREMENTS;95
12.2;INTERPRETATION;111
13;APPENDIX;118
13.1;ENERGY;118
14;REFERENCES;122
15;INDEX;124
