Derome / Perlmutter Modern NMR Techniques for Chemistry Research

1. Auflage 2013
ISBN: 978-1-4832-8642-6
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, Band Volume 6, 299 Seiten, Web PDF

Reihe: Tetrahedron Organic Chemistry

Presents an introduction to modern NMR methods at a level suited to organic and inorganic chemists engaged in the solution of structural and mechanistic problems. The book assumes familiarity only with the simple use of proton and carbon spectra as sources of structural information and describes the advantages of pulse and Fourier transform spectroscopy which form the basis of all modern NMR experiments. Discussion of key experiments is illustrated by numerous examples of the solutions to real problems. The emphasis throughout is on the practical side of NMR and the book will be of great use to chemists engaged in both academic and industrial research who wish to realise the full possibilities of the new wave NMR.

Autoren/Hrsg.

Derome, A. E.

Perlmutter, Patrick

Inhaltsverzeichnis

1;Front Cover;1
2;Modern NMR Techniques for Chemistry Research;4
3;Copyright Page;5
4;Table of Contents;10
5;Introduction;18
6;Chapter 1. What This Boole Is About;20
6.1;1.1 INTRODUCTION;20
6.2;1.2 WHAT YOU NEED TO KNOW;22
6.3;1.3 WHAT IS IN THE BOOK;22
6.4;1.4 WHAT CAN BE DONE WITH NMR;24
6.5;1.5 A SHORT TOUR ROUND AN NMR SPECTROMETER;25
6.6;REFERENCE;27
7;Chapter 2. Why Bother With Pulse NMR;28
7.1;2.1 INTRODUCTION;28
7.2;2.2 THE TUNING OF BELLS;30
7.3;2.3 PULSE NMR;30
7.4;2.4 PRACTICAL IMPLEMENTATION OF PULSE NMR;33
7.5;2.5 WORKING WITH FT NMR;39
7.6;REFERENCES;48
8;Chapter 3. Basic Experimental Methods;50
8.1;3.1 INTRODUCTION;50
8.2;3.2 SAMPLE PREPARATION;50
8.3;3.3 ACHIEVING RESOLUTION;57
8.4;3.4 ACHIEVING SENSITIVITY;69
8.5;REFERENCES;80
9;Chapter 4. Describing Pulse NMR;82
9.1;4.1 INTRODUCTION;82
9.2;4.2 THE COMPONENTS OF THE EXPERIMENT;82
9.3;4.3 REALISTIC EXPERIMENTS;88
9.4;4.4 RELAXATION;104
9.5;4.5 DESCRIBING PULSE NMR;114
9.6;REFERENCES;115
10;Chapter 5. The Nuclear Overhauser Effect;116
10.1;5.1 INTRODUCTION;116
10.2;5.2 THE ORIGIN OF THE NUCLEAR OVERHAUSER EFFECT;117
10.3;5.3 MEASURING NOE'S;131
10.4;5.4 USING NOE'S;140
10.5;REFERENCES;146
11;Chapter 6. Polarisation Transfer and Spectrum Editing;148
11.1;6.1 INTRODUCTION;148
11.2;6.2 SELECTIVE POPULATION TRANSFER;149
11.3;6.3 INEPT;152
11.4;6.4 DEPT;162
11.5;REFERENCES;170
12;Chapter 7. Further Experimental Methods;172
12.1;7.1 INTRODUCTION;172
12.2;7.2 PULSE WIDTH AND FIELD STRENGTH;172
12.3;7.3 COPING WITH IMPERFECT PULSES;178
12.4;7.4 BROADBAND DECOUPLING;181
12.5;7.5 RELAXATION AND REPETITION;183
12.6;7.6 QUANTITATIVE INTENSITY MEASUREMENTS;187
12.7;7.7 SELECTIVE EXCITATION AND SUPPRESSION;191
12.8;7.8 SOME SPECTROMETER TESTS TO TRY;197
12.9;REFERENCES;200
13;Chapter 8. Homonuclear Shift Correlation;202
13.1;8.1 INTRODUCTION;202
13.2;8.2 FREQUENCY LABELLING;203
13.3;8.3 JEENER'S EXPERIMENT;206
13.4;8.4 EXPERIMENTS RELATED TO COSY;246
13.5;8.5 OTHER HOMONUCLEAR SHIFT CORRELATION EXPERIMENTS;253
13.6;REFERENCES;262
14;Chapter 9. Heteronuclear Shift Correlation;264
14.1;9.1 INTRODUCTION;264
14.2;9.2 DETAILS OF HSC;265
14.3;9.3 EXPERIMENTS RELATED TO HSC;271
14.4;9.4 RELAYED COHERENCE TRANSFER;274
14.5;REFERENCES;276
15;Chapter 10. Spin Echoes and J-Spectroscopy;278
15.1;10.1 INTRODUCTION;278
15.2;10.2 HETERONUCLEAR/-MODULATED SPIN ECHOES;278
15.3;10.3 THE HETERONUCLEAR J-SPECTRUM;283
15.4;10.4 THE HOMONUCLEAR J-SPECTRUM;289
15.5;REFERENCES;293
16;Index;296