Davies / Perlmutter Organotransition Metal Chemistry: Applications to Organic Synthesis

Organotransition Metal Chemistry: Applications to Organic Synthesis
1. Auflage 2013
ISBN: 978-1-4832-8584-9
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 430 Seiten, Web PDF

Although organotransition metal chemistry has been developing rapidly over the past 20 years, it is only recently that applications of transition metal complexes to organic synthesis have started to be exploited. This unique book provides an introduction to organometallic chemistry for chemists who have little or no experience in the field, describes the work that has already been done using organotransition metal complexes for synthesis, and indicates to organic and organometallic chemists the type of synthetic problems that can be solved using organometallic compounds. It covers all major advances that have been made in this rapidly expanding area of chemistry, including not only reactions that already have well established applications for synthesis but also many recently discovered potentially useful reactions, providing a survey of recent literature.

Autoren/Hrsg.

Davies, S. G.

Perlmutter, Patrick

Inhaltsverzeichnis

1;Front Cover;1
2;Organotransition Metal Chemistry Applications to Organic Synthesis;6
3;Copyright Page;7
4;Table of Contents;12
5;Dedication;8
6;FOREWORD;10
7;PREFACE;11
8;ABBREVIATIONS;18
9;CHAPTER 1. GENERAL INTRODUCTION TO ORGANOMETALLIC CHEMISTRY;20
9.1;1.1 18-ELECTRON RULE;21
9.2;1.2. BONDING OF HYDROCARBON LIGANDS TO TRANSITION METALS;23
9.3;1.3 ELECTRONIC EFFECTS OF COORDINATION OF UNSATURATED HYDROCARBONS TO TRANSITION METALS;24
9.4;1.4 STEREOCHEMICAL AND STERIC EFFECTS;29
9.5;1.5 CATALYTIC CYCLES;32
9.6;1.6 REFERENCES;37
10;CHAPTER 2. COMPLEXATION AND DECOMPLEXATION REACTIONS;38
10.1;2.1 PREPARATION AND DECOMPLEXATION OF n1-COMPLEXES;39
10.2;2.2 PREPARATION AND DECOMPLEXATION OF n2 -OLEFIN AND ACETYLENE COMPLEXES;51
10.3;2.3. PREPARATION AND DECOMPLEXATION OF n2 -CARBENE COMPLEXES;59
10.4;2.4 PREPARATION AND DECOMPLEXATION OF n3 -ALLYL COMPLEXES;63
10.5;2.5 PREPARATION AND DECOMPILATION OF n4 -DIENE COMPLEXES;72
10.6;2.6 PREPARATION AND DECOMPLEXATION OF n5 -DIENYL COMPLEXES;81
10.7;2.7 PREPARATION AND DECOMPLEXATION OF n6-ARENE AND RELATED COMPLEXES-116;87
10.8;2.8 PREPARATION OF n7-TRIENYL COMPLEXES;92
10.9;2.9 REFERENCES;94
11;CHAPTER 3. ORGANOMETALLICS AS PROTECTING AND STABILISING GROUPS;102
11.1;3.1 THE USE OF ORGANOMETALLIC SPECIES AS PROTECTING GROUPS;102
11.2;3.2 STABILISATION OF REACTIVE COMPOUNDS AND TRAPPING OF REACTION INTERMEDIATES;118
11.3;3.3 REFERENCES;132
12;CHAPTER 4. ORGANOMETALLICS AS ELECTROPHHES;135
12.1;4.1 STOICHIOMETRIC NUCLEOPHILIC ADDITIONS TO ORGANOTRANSITION METAL CATIONS;136
12.2;4.2. STOICHIOMETRIC NUCLEOPHILIC ADDITION AND SUBSTITUTION REACTIONS INVOLVING NEUTRAL ORGANOTRANSITION METAL COMPLEXES;175
12.3;4.3 CATALYTIC NUCLEOPHILIC ADDITION AND SUBSTITUTION REACTIONS;191
12.4;4.4 REFERENCES;200
13;CHAPTER 5. ORGANOMETALLICS AS NUCLEOPHILES;206
13.1;5.1 NEUTRAL COMPLEXES AS NUCLEOPHILES;206
13.2;5.2 ANIONIC COMPLEXES AS NUCLEOPHILES;220
13.3;5.3 REFERENCES;234
14;CHAPTER 6. COUPLING AND CYCLISATION REACTIONS;237
14.1;6.1 COUPLING REACTIONS INVOLVING BIS-n1-COMPLEXES;237
14.2;6.2 THE HECK REACTION AND RELATED TRANSFORMATIONS;243
14.3;6.3 COUPLING REACTIONS INVOLVING n3 -ALLYL INTERMEDIATES;255
14.4;6.4 COUPLING REACTIONS INVOLVING OLEFINS AND ACETYLENES;269
14.5;6.5 REFERENCES;280
15;CHAPTER 7. ISOMERISATION REACTIONS;285
15.1;7.1 ISOMERISATION OF OLEFINS AND ACETYLENES;285
15.2;7.2 ISOMERISATION OF DIENES;292
15.3;7.3 ISOMERISATION OF ALLYLIC ALCOHOLS, ETHERS, AMINES, ETC;301
15.4;7.4 REARRANGEMENTS OF SMALL RING HYDROCARBONS;310
15.5;7.5 ISOMERISATION OF SMALL RING HETEROCYCLES;313
15.6;7.6 REFERENCES;320
16;CHAPTER 8. OXIDATION AND REDUCTION;323
16.1;8.1 OXIDATION;323
16.2;8.2 REDUCTIONS;339
16.3;8.3. References;363
17;CHAPTER 9. CARBONYLATION AND RELATED REACTIONS;367
17.1;9.1 CARBONYLATION REACTIONS WITH Zr COMPOUNDS;371
17.2;9.2 CARBONYLATION REACTIONS WITH Fe COMPOUNDS;372
17.3;9.3. CARBONYLATION REACTIONS WITH Co AND Rh COMPOUNDS-33;385
17.4;9.4 CARBONYLATION REACTIONS WITH Pd AND Ni COMPOUNDS;397
17.5;9.5 ASYMMETRIC CARBONYLATION REACTIONS;411
17.6;9.6 INSERTION OF CO2;412
17.7;9.7 DECARBONYLATION REACTIONS;413
17.8;9.8. REFERENCES;419
18;INDEX;424