Cadenhead / Danielli Progress in Surface and Membrane Science

Volume 14
1. Auflage 2013
ISBN: 978-1-4832-1979-0
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 504 Seiten, Web PDF

Progress in Surface and Membrane Science, Volume 14 covers the advances in the study of surface and membrane science. The book discusses statistical thermodynamics of monolayer adsorption from gas and liquid mixtures on homogeneous and heterogeneous solid surfaces; and the structure of the boundary layers of liquids and its influence on the mass transfer in fine pores. The text then describes the coupling of ionic and non-electrolyte fluxes in ion selective membranes; the electrocatalytic properties of matalloporphins at the interface; and the adsorption from binary gas and liquid phases. Phase transitions in two-dimensional amphiphilic systems, as well as the wettability of solids by liquid metals are also considered. Biochemists, physicists, and people in electrochemistry research will find the book invaluable.

Autoren/Hrsg.

Cadenhead, D. A.

Danielli, J. F.

Inhaltsverzeichnis

1;Front Cover;1
2;Progress in Surface and Membrane Science;4
3;Copyright Page;5
4;Table of Contents;6
5;CONTRIBUTORS;10
6;CONTENTS OF RECENT VOLUMES;12
7;CHAPTER 1. STATISTICAL THERMODYNAMICS OF MONOLAYER ADSORPTION FROM GAS AND LIQUID MIXTURES ON HOMOGENEOUS AND HETEROGENEOUS SOLID SURFACES;14
7.1;I. GENERAL CONSIDERATIONS;15
7.2;II. LOCALIZED ADSORPTION OF GASES ON SOLIDS;21
7.3;III. MOBILE ADSORPTION OF GASES ON SOLIDS;35
7.4;IV. PARTIALLY MOBILE ADSORPTION OF GASES ON SOLIDS;40
7.5;V. ADSORPTION FROM LIQUID MIXTURES ON SOLIDS;55
7.6;VI. APPROXIMATE MODELS FOR ADSORPTION OF MIXTURES WITH LATERAL INTERACTIONS;62
7.7;REFERENCES;71
8;CHAPTER 2. STRUCTURE OF THE BOUNDARY LAYERS OF LIQUIDS AND ITS INFLUENCE ON THE MASS TRANSFER IN FINE PORES;82
8.1;I. THEORETICAL CONSIDERATION;83
8.2;II. STRUCTURE AND PROPERTIES OF THE BOUNDARY LAYERS OF LIQUIDS;88
8.3;III. MASS TRANSFER IN FINE PORES;114
8.4;IV. CONCLUSION;130
8.5;References;132
9;CHAPTER 3. COUPLING OF IONIC AND NONELECTROLYTE FLUXES IN ION SELECTIVE MEMBRANES;144
9.1;I. INTRODUCTION;144
9.2;II. GENERAL CONSIDERATION OF THE COUPLING EFFECT OF IONIC AND NONELECTROLYTE FLUXES IN A MEMBRANE POTENTIAL FROM THE VIEW-POINT OF THE THERMODYNAMICS OF IRREVERSIBLE PROCESSES;145
9.3;III. EFFECT OF IONIC AND SOLVENT FLUXES COUPLING IN THE POTENTIAL OF A MEMBRANE WITH FIXED CHARGES;155
9.4;IV. EFFECT OF COUPLING OF FLUXES IN A MEMBRANE POTENTIAL FOR A SYSTEM WITH SPECIFICALLY INTERACTING NEUTRAL AND IONIC COMPONENTS;166
9.5;V. CONCLUSIONS;182
9.6;REFERENCES;184
10;CHAPTER 4. ELECTROCATALYTIC PROPERTIES OF METALLOPORPHINS AT THE INTERFACE;188
10.1;I. INTRODUCTION;188
10.2;II. ELECTROPHYSICAL AND CATALYTIC PROPERTIES OF METALLOPORPHINS;190
10.3;III. KINETICS AND MECHANISM OF OXYGEN ELECTROREDUCTION ON METAL-LOPORPHINS;205
10.4;IV. THE USE OF ORGANIC COMPLEXES OF METALS FOR CREATING GASDIFFUSION ELECTRODES;225
10.5;V. ELECTROCHEMICAL REACTIONS OF HYDROGEN PEROXIDE AND OTHER ELECTROCATALYTIC REACTIONS;234
10.6;REFERENCES;241
11;CHAPTER 5. ADSORPTION FROM BINARY GAS AND LIQUID PHASES;250
11.1;1. INTRODUCTION;250
11.2;II. CONCEPTS OF EXCESS AND ABSOLUTE ADSORPTION;251
11.3;III. THERMODYNAMICS OF THE ADSORPTION OF SOLUTIONS;264
11.4;IV. ADSORPTION AT DIFFERENT INTERFACES;280
11.5;V. PREDICTION OF THE ADSORPTION OF MIXTURES FROM THE ADSORPTION PROPERTIES OF PURE COMPONENTS;287
11.6;VI. DETERMINATION OF THE SPECIFIC SURFACE AREA BY THE METHOD BASED ON ADSORPTION FROM SOLUTIONS;295
11.7;REFERENCES;298
12;CHAPTER 6. PHASE TRANSITIONS IN TWO-DIMENSIONAL AMPHlPHILIC SYSTEMS;304
12.1;I. INTRODUCTION;305
12.2;II. BILAYERS;308
12.3;III. MONOLAYERS;328
12.4;IV. THEORETICAL MODELS;339
12.5;V. CONCLUSION;353
12.6;References;355
13;CHAPTER 7. THE WETTABILITY OF SOLIDS BY LIQUID METALS;366
13.1;I. INTRODUCTION;367
13.2;II. GENERAL LAWS OF THE WETTING OF SOLIDS BY LIQUIDS.WETTABILITY BY LIQUID METALS;370
13.3;III. METHODS OF MEASURING THE WETTABILITY OF A SOLID BODY BY A LIQUID METAL;384
13.4;IV. THE WETTABILITY OF DIFFERENT CLASSES OF SOLIDS BY LIQUID METALS;393
13.5;V. CONCLUSION;483
13.6;References;483
14;INDEX;498