Batsanov Shock and Materials

1. Auflage 2018
ISBN: 978-981-10-7886-6
Verlag: Springer Nature Singapore
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 250 Seiten

Reihe: Engineering Materials

This book highlights how the properties and structure of materials are affected by dynamic high pressures generated by explosions, projectile impacts, laser compression, electric discharge or ball milling. Starting with the basics of shock-wave physics and an outline of experimental techniques, it then surveys dynamic compressibility and equations of state of various substances, phase transitions and syntheses of novel compounds under shock. It covers various industrial applications including hardening of metals and grinding (fragmentation) of solids, saturation of solids with defects for use as catalysts, production of superhard materials (synthetic diamond, BN (boron nitride)) and nanomaterials, especially nanodiamond, and discusses state-of-the-art techniques such as combining dynamic and static compression to obtain monolithic materials.

Stepan Sergeevich Batsanov was born in Moscow (November 9, 1928), obtained his MSc in Chemistry (1951); PhD on crystal-optical determination of the structure of complexes (1954) from Moscow State Universit. He received his DSc on refractometric methods in structural chemistry (1962) at Novosibirsk University, where he later became Chair in physical chemistry (1965). His main scientific interests are crystal optics, chemical structure and bonding, and (from 1966) shock-pressure chemistry and physics. He was the founder and director (in 1970-2010) of the Centre for High Dynamic Pressures (CHDP) at the State Committee of Standards at Mendeleevo, near Moscow. He authored and co-authored over 500 scientific papers and 8 books, including Structural Refractometry (in Russian, 1959, 2nd ed. 1976, English editions by Consultants Bureau, New York, 1961 & Van Nostrand, 1966), Effects of Explosions on Materials (Springer Verlag, 1994) and Introduction to Structural Chemistry (Springer, 2012).

Autoren/Hrsg.

Batsanov, Stepan S.

Inhaltsverzeichnis

1;Preface;6
2;Contents;8
3;Introduction;10
4;1 Effect of Explosion on Materials;12
4.1;1.1 Basics of Shock-Wave Physics;12
4.2;1.2 Compressibility of Solids. Equations of State;19
4.3;1.3 Techniques of Shock Compression;32
4.3.1;1.3.1 Cylindrical Recovery Ampoules;34
4.3.2;1.3.2 Planar Recovery Ampoules;42
4.3.3;1.3.3 Experimental Diagnostics of Recovery Ampoules;45
4.4;1.4 Microstructure of Shocked Materials;51
4.4.1;1.4.1 Fragmentation of Solids;51
4.4.2;1.4.2 Defects in Shocked Materials;58
4.5;1.5 Shock Hardening of Solids;64
4.6;1.6 Shock Compaction;71
4.7;1.7 Phase Transitions Under Shock Waves;80
4.7.1;1.7.1 Pressures of Phase Transformations Under Shock Loading;80
4.7.2;1.7.2 Phase Transition Under Dynamic Pressures Versus Defects;89
4.7.3;1.7.3 Phase Transition in Graphite and h-BN;92
4.7.4;1.7.4 E-Phase of BN;96
4.7.5;1.7.5 Metals Under High Dynamic Pressures;100
4.7.6;1.7.6 Anomalous Phase Transitions;104
4.7.7;1.7.7 Analysis of Shocked Samples After Transformations;106
4.8;1.8 Shock Synthesis and Decomposition of Substances;107
4.8.1;1.8.1 Chemical Transformation in Shocked Compounds;107
4.8.2;1.8.2 Shock Synthesis of Compounds;115
4.9;1.9 Duration of Solid-Phase Chemical Reactions Induced by Shock Waves;128
4.9.1;1.9.1 Duration of Solid-Phase Reactions;128
4.9.2;1.9.2 Mechanism of Ultrafast Solid-Phase Reaction;138
4.9.3;1.9.3 Perspectives and Applications of Shock-Induced Chemical Reactions;143
4.10;References;144
5;2 Detonation Transformation in Materials;164
5.1;2.1 Basics of Detonation Physics;164
5.2;2.2 Solid-State Detonation;166
5.3;2.3 Detonation Transformation of Substances;178
5.3.1;2.3.1 Detonation Synthesis of Compounds;178
5.3.2;2.3.2 Phase Transition Graphite ? Diamond Under Detonation;179
5.3.3;2.3.3 Technology of Detonation Synthesis of Nanodiamond;182
5.3.4;2.3.4 Characterization of DND Samples;184
5.3.5;2.3.5 Interaction of DND Samples with Water;193
5.3.6;2.3.6 Detonation Synthesis of the Hydrogen-Free Nanodiamond and c-BN;196
5.4;References;201
6;3 Laser-Induced Shock Compession;207
6.1;3.1 Quasi-isentropic Compression;207
6.2;3.2 Physico-chemical Transformations Under Laser Compression;208
6.3;References;210
7;4 Impulse Mechanical Action;212
7.1;4.1 Terminology, Physics, History;212
7.2;4.2 Physics and Techniques of Ball Milling;214
7.3;4.3 Phase Transformations;217
7.4;4.4 Synthesis of Compounds;219
7.4.1;4.4.1 Inorganic Materials;220
7.4.2;4.4.2 Organic Materials;226
7.5;References;227
8;5 Electric Discharge in Materials;230
8.1;5.1 Electric Discharge Consolidation of Porous Materials;230
8.2;5.2 Electric Discharge in Liquids;235
8.3;References;246
9;Conclusion;248
10;Index;249