Zimmer / Niedenzu Annual Reports in Inorganic and General Syntheses-1975

1. Auflage 2013
ISBN: 978-1-4832-6013-6
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 354 Seiten, Web PDF

Annual Reports in Inorganic and General Syntheses-1975 presents an annual review of synthetically useful information that would prove beneficial to nearly all organic chemists, both specialist and nonspecialist in synthesis. It should help relieve some of the information storage burden of the specialist and should aid the nonspecialist who is seeking help with a specific problem to become rapidly aware of recent synthetic advances. This is the fourth volume of 'ARIGS' and is organized along the lines used for the last volume. The authors were encouraged to use synthetic aspects as their primary guideline for the arrangement and preservation of the information; however, an occasional deviation to include structural or mechanistic features seemed to be justified in order to reflect the particular features of a given element's chemistry. Complex hydrides were dealt with under the particular elements. As a consequence there is no chapter on simple and complex metal hydrides of main groups I, II, and III in the present volume. As in previous issues of ARIGS, this volume presents an article of a timely subject of special interest. This year's special feature is the 'Synthesis of Radiopharmaceuticals by the Reduction of 99m TcO4-.'

Autoren/Hrsg.

Zimmer, Hans

Niedenzu, Kurt

Inhaltsverzeichnis

1;Front Cover;1
2;Annual Reports in Inorganic and General Syntheses–1975;4
3;Copyright Page;5
4;Table of Contents;6
5;PREFACE;10
6;CHAPTER 1. NOBLE GASES;12
6.1;KRYPTON;12
6.2;XENOSI;12
6.3;RADON;15
6.4;REFERENCES;16
7;CHAPTER 2. BORON;19
7.1;GENERAL;19
7.2;METAL BORON COMPOUNDS;19
7.3;ORGANO BORANES;20
7.4;RING SYSTEMS;21
7.5;FOUR COORDINATE BORON;22
7.6;REFERENCES;22
8;CHAPTER 3. ALUMINUM, GALLIUM, INDIUM AND THALLIUM;26
8.1;INTRODUCTION;26
8.2;SYNTHETIC METHODS;26
8.3;ORGANOMETALLIC;28
8.4;METAL–NITROGEN RING SYSTEMS;31
8.5;HALOGEN BRIDGED COMPOUNDS;31
8.6;HALIDE AND PSEUDOHALIDE COMPLEXES;32
8.7;COMPLEXES WITH .-ACID LIGANDS;33
8.8;METAL–CARBONYL COMPLEXES;34
8.9;REFERENCES;36
9;CHAPTER 4. SILICON CHEMISTRY;40
9.1;GENERAL;40
9.2;SILICON-HYDROGEN;40
9.3;SILICON–GROUP IV;41
9.4;SILICON–GROUP V;45
9.5;SILICON–GROUP VI;47
9.6;SILICON–GROUP VII;48
9.7;SILICON–METAL BONDS;49
9.8;OPTICALLY ACTIVE COMPOUNDS;49
9.9;REFERENCES;50
10;CHAPTER 5. Germanium, Tin, and Lead;57
10.1;GENERAL;57
10.2;MX4 COMPOUNDS (X's not necessarily the same);57
10.3;METAL–METAL BONDED COMPOUNDS;59
10.4;COORDINATION COMPOUNDS OF Ge, Sn and Pb;59
10.5;MISCELLANEOUS COMPOUNDS AND REACTIONS;60
10.6;REFERENCES;60
11;CHAPTER 6. NITROGEN;65
11.1;I. COMPOUNDS WITH NO N–N BONDS;65
11.2;II. COMPOUNDS WITH ONE OR MORE N–N BONDS;68
11.3;REFERENCES;69
12;CHAPTER 7. PHOSPHORUS;71
12.1;INTRODUCTION;71
12.2;ELEMENTAL PHOSPHORUS;71
12.3;PHOSPHIDES;71
12.4;PHOSPHORANES;72
12.5;PHOSPHANES;74
12.6;PHOSPHANEOXIDES, -SULFIDES AND -SELENIDES;75
12.7;PHOSPHORUS–BORON COMPOUNDS;76
12.8;PHOSHORUS COMPOUNDS WITH ELEMENTS OF THE IVth MAIN GROUP;77
12.9;PHOSPHORUS-NITROGEN COMPOUNDS;78
12.10;COMPOUNDS WITH P–P– or P–As–BONDS;87
12.11;COMPOUNDS OF PHOSPHORUS WITH ELEMENTS OF THE 6th MAIN GROUP;89
12.12;COMPLEXES WITH PHOSPHORUS LIGANDS;95
12.13;REFERENCES;98
13;CHAPTER 8. ARSENIC, ANTIMONY AND BISMUTH;105
13.1;REVIEWS;105
13.2;ARSENIC;105
13.3;ANTIMONY;107
13.4;BISMUTH;107
13.5;REFERENCES;108
14;CHAPTER 9. CHALCOGENS;112
14.1;OXYGEN;112
14.2;SULFUR;113
14.3;SELENIUM;115
14.4;TELLURIUM;117
14.5;REFERENCES;119
15;CHAPTER 10. HALOGENS AND PSEUDOHALOGENS;122
15.1;HALOGENS;122
15.2;PSEUDOHALOGEN COMPOUNDS OF MAIN GROUP ELEMENTS;124
15.3;PSEUDOHALO COMPLEKES OF TRANSITION METALS;126
15.4;PSEUDOHALO COMPLEXES OF INNER TRANSITION METALS;131
15.5;REFERENCES;132
16;CHAPTER 11. SCANDIUM, YTTRIUM, AND LANTHANIDES;136
16.1;SCANDIUM;136
16.2;YTTRIUM AND LANTHANIDES;136
16.3;REFERENCES;143
17;CHAPTER 12. TITANIUM, ZIRCONIUM, AND HAFNIUM;149
17.1;GENERAL;149
17.2;HALIDES AND PSEUDOHALIDES;150
17.3;GROUP VI COMPOUNDS;151
17.4;GROUP V COMPOUNDS;156
17.5;GROUP III COMPOUNDS;158
17.6;REFERENCES;159
18;CHAPTER 13. VANADIUM, NIOBIUM, AND TANTALUM;163
18.1;GENERAL;163
18.2;VANADIUM;163
18.3;REFERENCES;170
19;CHAPTER 14. CHROMIUM, MOLYBDENUM AND TUNGSTEN;176
19.1;GENERAL;176
19.2;CHROMIUM;176
19.3;MOLYBDENUM;179
19.4;TUNGSTEN;184
19.5;REFERENCES;187
20;CHAPTER 15. MANGANESE, TECHNETIUM AND RHENIUM;194
20.1;GENERAL;194
20.2;MANGANESE;194
20.3;COMPLEX;196
20.4;COMMENTS;196
20.5;TECHNETIUM;200
20.6;RHENIUM;201
20.7;REFERENCES;204
21;CHAPTER 16. IRON;207
21.1;GENERAL;207
21.2;IRON(II) –NITROGEN DONORS;207
21.3;IRON(III) –NITROGEN DONORS;209
21.4;SULFUR DONORS;210
21.5;HALIDE AND PSEUDOHALIDE DONORS;211
21.6;MISCELLANEOUS;212
21.7;REFERENCES;212
22;CHAPTER 17. COBALT and NICKEL;217
22.1;REVIEWS;217
22.2;LOWER OXIDATION STATES – COBALT;217
22.3;LOWER OXIDATION STATES – NICKEL;220
22.4;COBALT (II) and NICKEL (ll) COMPLEXES;222
22.5;COBALT(III);224
22.6;REFERENCES;229
23;CHAPTER 18. The Platinum Metals;233
23.1;PART I: Ruthenium, Osmium, Rhodium and Iridium;233
23.2;INTRODUCTION;233
23.3;GROUP VII DONORS;233
23.4;GROUP VI COMPOUNDS;234
23.5;GROUP V COMPOUNDS;237
23.6;GROUP IV COMPOUNDS;244
23.7;REFERENCES;251
24;CHAPTER 19. The Platinum Metals;259
24.1;PART II: Platinum and Palladium;259
24.2;INTRODUCTION;259
24.3;GROUP VI COMPOUNDS;260
24.4;GROUP V COMPOUNDS;264
24.5;REFERENCES;279
25;CHAPTER 20. COPPER;288
25.1;GENERAL;288
25.2;COPPER(I) COMPOUNDS;289
25.3;COPPER(II) COMPOUNDS;290
25.4;DIMERS AND POLYMERS;296
25.5;REFERENCES;297
26;CHAPTER 21. SILVER AND GOLD;304
26.1;INTRODUCTION;304
26.2;COMPOUNDS CONTAINING (Ag, Au) –C BONDS;304
26.3;SIMPLE SALTS AND OTHER COMPLEXES;306
26.4;CLUSTERS AND MISCELLANEOUS COMPOUNDS;308
26.5;REFERENCES;308
27;CHAPTER 22. ZINC, CADMIUM AND MERCURY;311
27.1;GENERAL AND INORGANIC COMPOUNDS;311
27.2;COORDINATION AND COMPLEX COMPOUNDS;312
27.3;ORGANOMETALIC COMPOUNDS;314
27.4;METAL–METAL BONDS;317
27.5;REFERENCES;319
28;CHAPTER 23. SYNTHESIS OF RADIOPHARMACEUTICALS BY THE REDUCTION OF 99mtco4-: 99mTc-LABELLED HEART SCANNING AGENTS;322
28.1;INTRODUCTION;322
28.2;PRODUCTION OF 99mTCO4;323
28.3;REDUCTION OF 99mTCO4;324
28.4;ACKNOWLEDGMENT;330
28.5;REFERENCES;330
29;INDEX;338