Buch, Englisch, Band 255, 344 Seiten, Format (B × H): 210 mm x 297 mm, Gewicht: 1089 g
Reihe: Veröffentlichungen des Instituts für Geotechnik (IGT) der ETH Zürich
Buch, Englisch, Band 255, 344 Seiten, Format (B × H): 210 mm x 297 mm, Gewicht: 1089 g
Reihe: Veröffentlichungen des Instituts für Geotechnik (IGT) der ETH Zürich
ISBN: 978-3-7281-4011-1
Verlag: vdf Hochschulverlag
Swelling of anhydrite is caused by chemical processes: The anhydrite dissolves when it comes into contact with water, and from the dissolved ions in the pore water gypsum precipitates. The volume of gypsum is greater than that of anhydrite by 61%. During Anhydrite to Gypsum Transformation (hereafter denoted as AGT) the rock mass expands and the pore volume can also increase, for example due to cracking of the rock induced by the pressure exerted by the growing crystals upon a rigid rock structure ("crystallization pressure").
This PhD thesis seeks to establish a better understanding and quantification of the coupled chemomechanical swelling processes due to AGT and creates a basis for developing chemo-mechanical models of the swelling of anhydritic claystones.
The findings from the experiments verified kinetic models and assumptions related to AGT. Moreover, the systematic experimental investigations regarding the swelling behavior of anhydrite give an indication of a stress-strain relationship which can be implemented and used as a fundamental basis for future modelling of swelling due to AGT. This is necessary for practicing engineers in order to design underground structures in anhydritic rock. Furthermore, it was shown that the swelling due to anhydrite and clay can be de-coupled by varying the testing temperatures, which changes the equilibrium concentrations.