Buch, Englisch, 264 Seiten, Format (B × H): 161 mm x 240 mm, Gewicht: 570 g
Chemistry, Biochemistry, Pharmacology and Practical Applications
Buch, Englisch, 264 Seiten, Format (B × H): 161 mm x 240 mm, Gewicht: 570 g
ISBN: 978-1-4200-4613-7
Verlag: Routledge
Building a hierarchy of complexity, the book provides a discussion of some basic principles of 51V NMR spectroscopy followed by a description of the self-condensation reactions of vanadate itself. The authors delineate reactions with simple monodentate ligands and then proceed to more complicated systems such as diols, a-hydroxy acids, amino acids, peptides, to name just a few. They revisit aspects of this sequence later, but first highlight the influence the electronic properties of ligands have on coordination and reactivity. They then compare and contrast the influences of ligands, particularly those of hydrogen peroxide and hydroxylamine, on heteroligand reactivity.
The book includes coverage of vanadium-dependent haloperoxidases and model systems, vanadium in the environment, and technological applications. It also briefly covers the catalytic reactions of peroxovanadate and haloperoxidase model compounds. It contains a discussion of the vanadium haloperoxidases and the biological and biochemical activities of vanadium(V) including potential pharmacological applications. The last chapters step outside these boundaries by introducing some aspects of the future of vanadium in nanotechnology, the recyclable redox battery, and the lithium/silver vanadium oxide battery.
Primary sources documented after each chapter minimize the need to search the literature, 80 illustrations provide structural information, reaction schemes, spectra, speciation diagrams, and biochemical schemes, and 22 tables present detailed information with references to primary sources. Packed with current and authoritative information, the book covers chemistry and bioinorganic vanadium chemistry in a broad and systematic manner that engenders comprehensive understanding.
Zielgruppe
Professional
Autoren/Hrsg.
Fachgebiete
Weitere Infos & Material
Introduction. Vanadate Speciation. Monodentate Ligands of Vanadate. Aqueous Reactions of Vanadate with Multidentate Ligands. Coordination of Vanadate by Hydrogen Peroxide and Hydroxylamines. Reactions of Peroxovanadates. Aqueous Reactions and NMR Spectroscopy of Hydroxamidovanadates. Reaction of Oligovanadates. Influence of Ligand Properties on Product Structure and Reactivity. Vanadium in Biological Systems. Pharmacology of Vanadium. Model Systems and Technological Development. Preparation, Characterization, and Battery Applications of Silver Vanadium. Index.
