Tiwari / Sharma / Belcher The Determination of Carboxylic Functional Groups

Monographs in Organic Functional Group Analysis
1. Auflage 2013
ISBN: 978-1-4831-5125-0
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 140 Seiten, Web PDF

Monographs in Organic Functional Group Analysis, Volume 3: Determination of Carboxylic Functional Groups focuses on the quantitative determination of acid chlorides, esters, carboxylic acids, anhydrides, lactones, and amides. The monograph first takes a look at the determination of carboxylic acids. Countercurrent and electrophoretic separation of organic acids; polarography of organic acids; acid-base equilibrium in non-aqueous media; and titrimetric determination of acids are discussed. The book also examines the determination of acid anhydrides, chlorides, and esters. The characteristics and composition of acid chlorides and anhydrides, as well as the saponification and spectroscopic methods used in the identification of esters, are presented. The book also evaluates the methods and use of Grignard's reagent in the determination of amides. The text also presents an analysis of binary and ternary mixtures. Mixtures of acids and acid chlorides, differentiation of acids, mixtures of acids and esters, and mixtures of acids and amides are discussed. The monograph is a vital reference for readers interested in the quantitative determination of acid chlorides, esters, carboxylic acids, and other related compounds.

Autoren/Hrsg.

Tiwari, R. D.

Sharma, J. P.

Belcher, R.

Anderson, D. M. W.

Inhaltsverzeichnis

1;Front Cover;1
2;The Determination of Carboxylic Functional Groups;4
3;Copyright Page;5
4;Table of Contents;6
5;Preface;8
6;CHAPTER 1. INTRODUCTION;10
7;CHAPTER 2. THE DETERMINATION OF CARBOXYLIC ACIDS;13
7.1;1. GENERAL;13
7.2;2. ACID-BASE EQUILIBRIUM IN WATER;14
7.3;3 . ACID-BASE EQUILIBRIUM IN NON-AQUEOUS MEDIA;18
7.4;4 . TITRIMETRIC DETERMINATION OF ACIDS;22
7.5;5. SPECTROPHOTOMETRIC METHODS;45
7.6;6. CHROMATOGRAPHIC METHODS;51
7.7;7. COUNTERCURRENT SEPARATION OF ORGANIC ACIDS;60
7.8;8. ELECTROPHORETIC SEPARATION OF ORGANIC ACIDS;64
7.9;9 . POLAROGRAPHY OF ORGANIC ACIDS;68
7.10;10. SOME OTHER CHEMICAL METHODS;71
7.11;REFERENCES;73
8;CHAPTER 3. THE DETERMINATION OF ACID ANHYDRIDES AND ACID CHLORIDES;76
8.1;A. ACID ANHYDRIDES;76
8.2;B. ACID CHLORIDES;89
8.3;REFERENCES;92
9;CHAPTER 4. THE DETERMINATION OF ESTERS;93
9.1;1. GENERAL;93
9.2;2. SAPONIFICATION METHODS;94
9.3;3 . SOME SPECIFIC METHODS;101
9.4;4. SPECTROSCOPIC METHODS;103
9.5;5. CHROMATOGRAPHY OF ESTERS;107
9.6;6 . SOME OTHER PHYSICAL METHODS;108
9.7;7. DETERMINATION OF LACTONES;109
9.8;REFERENCES;111
10;CHAPTER 5. DETERMINATION OF AMIDES;114
10.1;1. GENERAL;114
10.2;2. GENERAL METHODS;114
10.3;3 . USE OF GRIGNARD'S REAGENT;121
10.4;4. SPECIFIC METHODS FOR PRIMARY AMIDES;121
10.5;REFERENCES;126
11;CHAPTER 6. THE ANALYSIS OF BINARY AND TERNARY MIXTURES;128
11.1;1. GENERAL;128
11.2;2. DIFFERENTIATION OF ACIDS;129
11.3;3. MIXTURES OF ACIDS AND ANHYDRIDES;132
11.4;4. MIXTURES OF ACIDS AND ACID CHLORIDES;134
11.5;5. MIXTURES OF ACIDS AND ESTERS;135
11.6;6. MIXTURES OF ACIDS AND AMIDES;137
11.7;REFERENCES;138
12;INDEX;140