Rogachev / Mukasyan Combustion for Material Synthesis

Erscheinungsjahr 2015
ISBN: 978-1-4822-3952-2
Verlag: Taylor & Francis
Format: PDF
Kopierschutz: Adobe DRM (»Systemvoraussetzungen)

E-Book, Englisch, 424 Seiten

This book summarizes the state of the art in combustion synthesis, from the fundamental and technological points of view. The authors discuss a wide range of topics including theory, phenomenology, properties of the product synthesized, and methods for large-scale materials production. Focus is given to the mechanisms of structural transformation at the micro-, nano- and atomic levels, which take place in the unique conditions of the combustion wave. It is a first attempt to summarize and critically review in one monograph mechanisms for a variety of solid–solid and gas–solid systems.

Autoren/Hrsg.

Rogachev, Alexander S.

Mukasyan, Alexander S.

Fachgebiete

• Naturwissenschaften Physik Thermodynamik Festkörperphysik, Kondensierte Materie

Inhaltsverzeichnis

Self-propagating high-temperature synthesis (SHS): Past and Present
Discovery of SHS. Reaction modes: thermal explosion and combustion wave
Synthesis from elements in gasless combustion mode
Synthesis from elements with gasification of some agents
Synthesis from elements with gas phase reactants (infiltration combustion)
Synthesis with an oxidation-reduction stage: thermite and nano-thermite systems
Synthesis with inorganic compounds
Thermal decomposition of complex compounds
Synthesis in sol-gel systems ("solution combustion")
Mechanical activation of SHS systems
Reactive multilayer nano-films

Thermodynamics and kinetics of the SHS process
Introduction
Thermodynamics and driving force of SHS processes
Kinetics of heterogeneous reactions

Theoretical structural macrokinetics
Introduction: The concept of structural macrokinetics
Macrokinetics of thermal explosion
Macrokinetics of combustion process
Theoretical models of structure formation during SHS
Conclusion

Experimental structural macrokinetics of SHS processes
Experimental methods
Experimental results

Commercialization and industrial use of SHS products
Introduction
Powders and sintered cakes
Ceramic materials
Cermets and functionally gradient materials
Products of SHS metallurgy
The use of reactive multilayer nanofilms
Conclusion
Concluding remarks
References