Niedenzu / Zimmer Annual Reports in Inorganic and General Syntheses-1974

1. Auflage 2013
ISBN: 978-1-4832-1389-7
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 388 Seiten, Web PDF

Annual Reports in Inorganic and General Syntheses-1974 presents an organized annual summary of synthetic developments in inorganic chemistry and its related areas. The book discusses the chemistry of simple and complex metal hydrides of main groups I, II, and III, boron, aluminium, gallium, indium, thallium, silicon, germanium, tin, lead, phosphorus, arsenic, antimony, bismuth, chalcogens, halogens, and pseudohalogens. The text also describes the chemistry of scandium, yttrium, lanthanides, actinides, titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, technetium, rhenium, iron, cobalt, nickel, ruthenium, osmium, rhodium, and iridium. The chemistry of palladium, platinum, copper, silver, gold, zinc, cadmium, and mercury is also encompassed. The book concludes by demonstrating the photochemical syntheses of inorganic compounds. Chemists, chemistry students, and people working in chemical laboratories will find the book invaluable.

Autoren/Hrsg.

Niedenzu, Kurt

Zimmer, Hans

Inhaltsverzeichnis

1;Front Cover;1
2;Annual Reports in Inorganic and General Syntheses -1974;4
3;Copyright Page;5
4;Table of Contents;6
5;PREFACE;18
6;CHAPTER 1. SIMPLE AND COMPLEX METAL HYDRIDES OF MAIN GROUPS I, II AND III;20
6.1;Sodium Hydride;20
6.2;Beryllium Hydride;21
6.3;Aluminum Hydride;24
6.4;Hydridoaluminates;27
6.5;References;28
7;CHAPTER 2. BORON;30
7.1;General;30
7.2;Novel Procedures;30
7.3;Inorganic Boron Derivatives;30
7.4;Metal-Boron Compounds;31
7.5;Organoboranes;32
7.6;Ring Systems;33
7.7;Four Coordinate Boron;34
7.8;References;34
8;CHAPTER 3. ALUMINUM, GALLIUM, INDIUM AND THALLIUM;38
8.1;Introduction;38
8.2;Synthetic Methods;38
8.3;Perfluorophenyl Compounds;42
8.4;Organometallic;42
8.5;Metal-Nitrogen Ring Systems;47
8.6;Halogen Bridged Compounds;47
8.7;Halide and Pseudohalide Complexes;48
8.8;Complexes with II Acid Ligands;49
8.9;Metal Carbonyl Complexes;50
8.10;Metal-Metal Bonded Compounds;52
8.11;References;53
9;CHAPTER 4. SILICON CHEMISTRY;57
9.1;General;57
9.2;Silicon-Hydrogen;57
9.3;Silicon-Group IV;58
9.4;Silicon-Group VII;66
9.5;Silicon-Transition Metal Bond;66
9.6;Molecular Rearrangements;67
9.7;References;68
10;CHAPTER 5. GERMANIUM, TIN, AND LEAD;74
10.1;General;74
10.2;MX4 Compounds (X's not necessarily the same);74
10.3;Coordination Compounds of Ge, Sn, Pb;77
10.4;Miscellaneous Compounds and Reactions;77
10.5;References;78
11;CHAPTER 6. PHOSPHORUS;85
11.1;Introduction;85
11.2;Elemental Phosphorus;85
11.3;Phosphides;85
11.4;Phosphoranes;86
11.5;Phosphines;86
11.6;Phosphorus-Boron Compounds;87
11.7;Phosphorus-Silicon Compounds;87
11.8;Phosphorus-Nitrogen Compounds;88
11.9;Compounds with P-P Bonds;97
11.10;Phosphorus-Halogen Compounds;100
11.11;Complexes with Phosphorus Ligands;101
11.12;References;102
12;CHAPTER 7. ARSENIC, ANTIMONY AND BISMUTH;109
12.1;Reviews;109
12.2;Arsenic;109
12.3;Arsenic (III);109
12.4;Arsenic (V);112
12.5;Antimony;112
12.6;Bismuth;112
12.7;Arsenic, Antimony and Bismuth as Acceptors;113
12.8;References;114
13;CHAPTER 8. CHALCOGENS;117
13.1;Oxygen;117
13.2;Sulfur;118
13.3;Selenium;120
13.4;Tellurium;121
13.5;References;122
14;CHAPTER 9. HALOGENS AND PSEUDOHALOGENS;124
14.1;Halogens;124
14.2;Pseudoholgen Compounds of Main Group Elements;127
14.3;Pseudohalo Complexes of Transition Metals;129
14.4;References;134
15;CHAPTER 10. SCANDIUM, YTTRIUM, LANTHANIDES AND ACTINIDES;138
15.1;Scandium;138
15.2;Yttrium and Lanthanides;138
15.3;Actinides;141
15.4;References;144
16;CHAPTER 11. TITANIUM, ZIRCONIUM, AND HAFNIUM;149
16.1;General;149
16.2;Group VI Compounds;151
16.3;Group V Compounds;155
16.4;Group IV Compounds;156
16.5;Group III Compounds;157
16.6;Hydrides;157
16.7;References;157
17;CHAPTER 12. VANADIUM, NIOBIUM AND TANTALUM;161
17.1;General;161
17.2;Vanadium;161
17.3;Niobium and Tantalum;164
17.4;References;166
18;CHAPTER 13. CHROMIUM, MOLYBDENUM AND TUNGSTEN;173
18.1;General;173
18.2;Chromium;173
18.3;Molybdenum;175
18.4;Tungsten;180
18.5;References;182
19;CHAPTER 14. MANGANESE, TECHNETIUM AND RHENIUM;188
19.1;General;188
19.2;Manganese;188
19.3;Technetium;193
19.4;Other Complexes;194
19.5;Rhenium;195
19.6;References;198
20;CHAPTER 15. IRON;205
20.1;General;205
20.2;Compounds with Carbon Donors;206
20.3;Compounds with Nitrogen Donors;206
20.4;Compounds with Oxygen Donors;209
20.5;Compounds with Sulfur Donors;210
20.6;Compounds with Halogen Donors;211
20.7;Miscellaneous;211
20.8;References;212
21;CHAPTER 16. COBALT AND NICKEL;218
21.1;General;218
21.2;Low-Valent Cobalt Complexes;218
21.3;Low-Valent Nickel Complexes;222
21.4;Cobalt(II) and Nickel(II) Complexes;223
21.5;Cobalt(III) Complexes;225
21.6;Higher Oxidation States;231
21.7;References;231
22;CHAPTER 17. THE PLATINUM METALS. PART I: RUTHENIUM, OSMIUM, RHODIUM AND IRIDIUM.;237
22.1;Introduction;237
22.2;Group VII Donors;237
22.3;Group VI Donors;238
22.4;Group V Donors;240
22.5;Group IV Donors;244
22.6;References;249
23;CHAPTER 18. THE PLATINUM METALS. PART II: PALLADIUM AND PLATINUM;257
23.1;Introduction;257
23.2;Group VII Donors;257
23.3;Group VI Donors;258
23.4;Group V Donors;263
23.5;Group IV Donors;268
23.6;References;275
24;CHAPTER 19. COPPER;285
24.1;General;285
24.2;Copper(I) Compounds;286
24.3;Copper(II) Compounds;288
24.4;Dimeric and Polymeric Compounds;295
24.5;References;298
25;CHAPTER 20. SILVER AND GOLD;307
25.1;Introduction;307
25.2;Compounds Containing (Ag,Au) -C Bonds;307
25.3;Simple Salts and Other Complexes;310
25.4;Miscellaneous Compounds;311
25.5;References;312
26;CHAPTER 21. ZINC, CADMIUM AND MERCURY;315
26.1;General Inorganic Compounds;315
26.2;Complex and Coordination Compounds;316
26.3;Organometallic Compounds ;319
26.4;Compounds with Metal-Metal Bonds;324
26.5;References;325
27;CHAPTER 22. PHOTOCHEMICAL SYNTHESES OF INORGANIC COMPOUNDS;328
27.1;Introduction;328
27.2;The Literature;328
27.3;Experimental Techniques;331
27.4;Photochemical Reactions and Syntheses;333
27.5;Lithium;334
27.6;Group IIIA Elements;334
27.7;Group IVA Elements;336
27.8;Group VA Elements;337
27.9;Group VIA Elements;339
27.10;Group VIIA Elements;339
27.11;Group VIB Elements;340
27.12;Group VIIB Elements;342
27.13;Iron, Ruthenium and Osmium;343
27.14;Cobalt, Rhodium and Iridium;345
27.15;Nickel, Palladium and Platinum;347
27.16;Miscellaneous;347
27.17;Concluding Remarks;350
27.18;References;350
28;INDEX;364
28.1;Actinides;364
28.2;Aluminum;364
28.3;Antimony;364
28.4;Arsenic;365
28.5;Bismuth;365
28.6;Boron;365
28.7;Cadmium;366
28.8;Chalcogens;366
28.9;Chromium;367
28.10;Cobalt;367
28.11;Copper;368
28.12;Gallium;370
28.13;Germanium;370
28.14;Gold;371
28.15;Hafnium;371
28.16;Halogens;372
28.17;Hydrides;372
28.18;Indium;372
28.19;Iron;373
28.20;Lanthanides;374
28.21;Lead;375
28.22;Manganese;375
28.23;Mercury;376
28.24;Molybdenum;377
28.25;Nickel;377
28.26;Palladium;378
28.27;Platinum;378
28.28;Platinum metals;380
28.29;Phosphorus;381
28.30;Pseudohalogen compounds;382
28.31;Rhenium;383
28.32;Silicon;384
28.33;Silver;384
28.34;Tantalum;385
28.35;Technetium;385
28.36;Thallium;385
28.37;Tin;386
28.38;Titanium;386
28.39;Tungsten;387
28.40;Vanadium;387
28.41;Zinc;388
28.42;Zirconium;388