Niedenzu / Zimmer Annual Reports in Inorganic and General Syntheses-1973

1. Auflage 2013
ISBN: 978-1-4832-1388-0
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 332 Seiten, Web PDF

Annual Reports in Inorganic and General Syntheses-1973 presents an organized annual summary of synthetic developments in inorganic chemistry and its related areas. The book covers the synthetic aspects and structural or mechanistic features of elements, including the main group hydrides, alkali and alkaline earth elements, boron, aluminium, gallium, indium, thallium, silicon, germanium, tin, and lead, nitrogen, phosphorus, arsenic, antimony, bismuth, chalcogens, halogens and pseudohalogens, and noble gases. The text also discusses the synthetic aspects and structural or mechanistic features of elements of yttrium, scandium, lanthanides, and actinides, titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, technetium, rhenium, iron, cobalt, and nickel. The chemistry of ruthenium, osmium, rhodium, iridium, palladium, platinum, copper, silver, gold, zinc, cadmium, and mercury is also encompassed. The book concludes by describing the synthesis and structures of metalloporphyrins. Chemists, chemistry students, and people working in chemical laboratories will find the book invaluable.

Autoren/Hrsg.

Niedenzu, Kurt

Zimmer, Hans

Inhaltsverzeichnis

1;Front Cover;1
2;Annual Reports in Inorganic and General Syntheses–1973;4
3;Copyright Page;5
4;Table of Contents;6
5;PREFACE;18
6;CHAPTER 1. MAIN GROUP HYDRIDES, ALKALI AND ALKALINE EARTH ELEMENTS;22
6.1;Simple Hydrides;22
6.2;Complex Hydrides;22
6.3;Alkali and Alkaline Earth Elements;23
6.4;References;29
7;CHAPTER 2. BORON;32
7.1;General;32
7.2;Novel Procedures;32
7.3;Inorganic Boron Derivatives;33
7.4;Metal-Boron Compounds;33
7.5;Organoboranes;34
7.6;Ring Systems;34
7.7;Four-Coordinate Boron;35
7.8;References;35
8;CHAPTER 3. ALAUMINUM, GALLIUM, INDIUM AND THALLIUM;39
8.1;Introduction;39
8.2;Synthetic Methods;39
8.3;Reactions of Organometallic Compounds;41
8.4;Donor-Acceptor Interactions with Metal Carbonyl and Metal Dinitrogen Complexes;47
8.5;Metal-Metal Bonded Compounds;48
8.6;Miscellaneous;50
8.7;References;51
9;CHAPTER 4. SILICON;55
9.1;General;55
9.2;Silicon-Hydrogen;55
9.3;Silicon-Halogen;55
9.4;Silicon-Nonmetal;56
9.5;Silicon-Metal;60
9.6;Silicon-Silicon;61
9.7;References;63
10;CHAPTER 5. GERMANIUM, TIN AND LEAD;65
10.1;General;65
10.2;MR4 Compounds;65
10.3;Metal-Metal Bonded Compounds;67
10.4;Coordination Compounds of Ge, Sn, Pb;68
10.5;Miscellaneous Compounds and Reactions;69
10.6;References;70
11;CHAPTER 6. NITROGEN;77
11.1;I. Compounds with no N-N Bonds;77
11.2;II. Compounds with one N-N Bond.;82
11.3;III. Compounds with Three or More Linked Nitrogens;85
11.4;References;86
12;CHAPTER 7. PHOSPHORUS;89
12.1;Introduction;89
12.2;Phosphides;89
12.3;Phosphorus-Boron Compounds;89
12.4;Phosphorus-Carbon Compounds;90
12.5;Phosphorus-Si, Ge, Sn compounds;90
12.6;Phosphorus-Nitrogen Compounds;90
12.7;Compounds of Phosphorus with Elements of Group VIA;95
12.8;Complexes with Phosphorus Ligands;98
12.9;Phosphorus-Halogen Compounds;99
12.10;References;101
13;CHAPTER 8. ARSENIC, ANTIMONY AND BISMUTH;108
13.1;Reviews;108
13.2;Arsenic;108
13.3;Tertiary Arsines;108
13.4;Antimony;111
13.5;Bismuth;112
13.6;References;113
14;CHAPTER 9. CHALCOGENS;117
14.1;Oxygen;117
14.2;Sulfur;117
14.3;Selenium;123
14.4;Tellurium;124
14.5;References;126
15;CHAPTER 10. HALOGENS AND PSEUDOHALOGENS;130
15.1;Halogens;130
15.2;Pseudohalogen Compounds of Main Group Elements;133
15.3;Pseudohalo Complexes of Transition Metals;134
15.4;Pseudohalo Complexes of Inner Transition Metals;139
15.5;References;139
16;CHAPTER 11. NOBLE GASES;143
16.1;Krypton;143
16.2;Xenon;143
16.3;Radon;144
16.4;References;144
17;CHAPTER 12. YTTRIUM, SCANDIUM, LANTHANIDES AND ACTINIDES;146
17.1;The Elements;146
17.2;New Method of Purification;146
17.3;Lanthanide Ions as Reducing Agents;147
17.4;Phase Relationships;148
17.5;High Pressure synthesis;149
17.6;Borides;149
17.7;Fluorides;149
17.8;Lanthanide Nitrates;149
17.9;Double Oxides;150
17.10;Carbides;150
17.11;Mixed Carbides;150
17.12;Isocyanate and Isothiocyanates;151
17.13;Carboxylates;152
17.14;Thiophosphates;152
17.15;Alkoxides;153
17.16;Fluorinated Acetonylpyrazolides;154
17.17;Carbonyls;155
17.18;References;157
18;CHAPTER 13. TITANIUM, ZIRCONIUM AND HAFNIUM;158
18.1;Bromides;158
18.2;Alkoxides;158
18.3;Oxotitanium Complexes;160
18.4;References;168
19;CHAPTER 14. VANADIUM, NIOBIUM, TANTALUM;169
19.1;Vanadium;169
19.2;Niobium and Tantalum;171
19.3;References;173
20;CHAPTER 15. CHROMIUM, MOLYBDENUM, AND TUNGSTEN;178
20.1;General;178
20.2;Chromium;178
20.3;Molybdenum;181
20.4;Tungsten;185
20.5;References;186
21;CHAPTER 16. MANGANESE, TECHNETIUM AND RHENIUM;193
21.1;General;193
21.2;Manganese;194
21.3;Technetium;202
21.4;Rhenium;203
21.5;References;211
22;CHAPTER 17. IRON;217
22.1;General;217
22.2;Compounds with Carbon Donors;217
22.3;Compounds with Nitrogen Donors;218
22.4;Compounds with Oxygen Donors;221
22.5;Compounds with Sulfur Donors;222
22.6;Compounds with Halogen Donors;223
22.7;Miscellaneous;223
22.8;References;224
23;CHAPTER 18. COBALT AND NICKEL;231
23.1;General;231
23.2;Low Oxidation States - Cobalt(-1), Cobalt(O), and Cobalt(1);231
23.3;Low-Valent Nickel Complexes;233
23.4;Cobalt(11) and Nickel(11) Complexes;234
23.5;Cobalt (111) Complexes;237
23.6;Higher Oxidation States;240
23.7;References;241
24;CHAPTER 19. THE PLATINUM METALS. PART I: RUTHENIUM, OSMIUM, RHODIUM AND IRIDIUM;245
24.1;Introduction;245
24.2;The Chemistry of Ruthenium and Osmium 224 Group V11 Donors;245
24.3;The Chemistry of Rhodium and iridium .;252
24.4;References;258
25;CHAPTER 20. THE PLATINUM METALS, PART II: PALLADIUM AND PLATINUM;266
25.1;Introduction;266
25.2;References;277
26;CHAPTER 21. COPPER;284
26.1;General;284
26.2;Copper (1) Compounds;284
26.3;Copper (11);286
26.4;Copper(11) - Dimers and Polymers;290
26.5;Miscellaneous;292
26.6;References;293
27;CHAPTER 22. SILVER AND GOLD;300
27.1;General;300
27.2;Compounds Containing (Ag,Au)-C Bonds;300
27.3;Simple Salts and Other Complexes;304
27.4;Miscellaneous Compounds;306
27.5;References;306
28;CHAPTER 23. ZINC, CADMIUM AND MERCURY;309
28.1;General inorganic Compounds;309
28.2;Complex and Coordination Compounds;310
28.3;Organometallic Compounds;311
28.4;Compounds with Metal-Metal Bonds;314
28.5;References;315
29;CHAPTER 24. METALLOPORPHYRIN SYNTHESIS;318
29.1;Some Common Metalloporphyrins;319
29.2;Methods of Metalloporphyrin Synthesis;321
29.3;References;328