Niedenzu / Zimmer Annual Reports in Inorganic and General Syntheses-1972

1. Auflage 2013
ISBN: 978-1-4832-1387-3
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 336 Seiten, Web PDF

Annual Reports in Inorganic and General Syntheses-1972 presents an organized annual summary of synthetic developments in inorganic chemistry and its related areas. The book discusses alkali and alkaline earth elements, alloys, silver, gold, zinc, cadmium, mercury, boron, aluminum, gallium, indium, thallium, yttrium, scandium, lanthanides, actinides, titanium, zirconium, hafnium, Group V and VI transition elements, manganese, technetium, rhenium, iron, cobalt, nickel, ruthenium, osmium, rhodium, and iridium. The text also describes the chemistry of palladium, platinum, silicon, germanium, tin, lead, nitrogen, phosphorus, arsenic, antimony, bismuth, chalcogenides, fluorine, halogens, pseudohalogens, noble gases, and simple and complex metal hydrides of main groups I, I, and III. New techniques and reagents in synthetic coordination chemistry, as well as the stabilizing effects of large counter-ions are also encompassed. Chemists, chemistry students, and people working in chemical laboratories will find the book invaluable.

Autoren/Hrsg.

Niedenzu, Kurt

Zimmer, Hans

Inhaltsverzeichnis

1;Front Cover;1
2;Annual Reports in Inorganic and General Syntheses - 1972;4
3;Copyright Page;5
4;Table of Contents;6
5;Preface;20
6;CHAPTER 1. ALKALI AND ALKALINE EARTH ELEMENTS;24
6.1;THE ELEMENTS;24
6.2;COMPLEXES WITH HALOGENS;24
6.3;COMPOUNDS WITH GROUP VI ELEMENTS;25
6.4;NITROGEN-CONTAINING COMPOUNDS;30
6.5;ORGANOMETALLIC COMPOUNDS;31
6.6;COMPOUNDS WITH TRANSITION METALS;32
6.7;REFERENCES;33
7;CHAPTER 2. COPPER;35
7.1;ALLOYS AND INTERMETALLIC COMPOUNDS;35
7.2;INORGANIC COPPER COMPOUNDS;35
7.3;COMPLEXES OF COPPER(I);36
7.4;COMPLEXES F COPPER(II);37
7.5;COPPER(III) COMPOUNDS;41
7.6;REFERENCES;41
8;CHAPTER 3. SILVER AND GOLD;48
8.1;GENERAL;48
8.2;PHOSPHINE COMPLEXES AND RELATED DERIVATIVES;48
8.3;SIMPLE SALTS AND OTHER COMPLEXES;52
8.4;MISCELLANEOUS ORGANOMETALLIC COMPOUNDS;54
8.5;REFERENCES;54
9;CHAPTER 4. ZINC, CADMIUM AND MERCURY;57
9.1;GENERAL AND COORDINATION COMPOUNDS;57
9.2;COMPOUNDS WITH METAL-METAL BONDS;59
9.3;ORGMTOMETALLIC COMPOUNDS;61
9.4;REFERENCES;64
10;CHAPTER 5. BORON;67
10.1;GENERAL;67
10.2;NEW PROCEDURES;67
10.3;ORGANOBORANES;68
10.4;METAL-BORON COMPOUNDS;70
10.5;THREE COORDINATE BORON;71
10.6;FOUR COORDINATE BORON;72
10.7;REFERENCES;72
11;CHAPTER 6. ALUMINUM, GALLIUM, INDIUM AND THALLIUM;78
11.1;INTRODUCTION;78
11.2;PROCEDURES FOR SYNTHESIS;78
11.3;REACTION OF ALUMINUM DERIVATIVES WITH EPOXIDES AND CARBONYLS;80
11.4;REACTION WITH OLEFINS;82
11.5;REACTIONS OF THALLIUM COMPOUNDS;83
11.6;COMPOUNDS CONTAINING METAL-METAL BONDS;84
11.7;MISCELLANEOUS REACTIONS;85
11.8;REFERENCES;87
12;CHAPTER 7. YTTRIUM, SCANDIUM, LANTHANIDES AND ACTINIDES;90
12.1;HYDRIDES;90
12.2;OXIDES;90
12.3;FLUORIDES;90
12.4;BORIDES;91
12.5;CHACOGENIDES;91
12.6;ORGANO LANTHANIDES AND ACTINIDES;91
12.7;ß-DIKETONATO-COMPOUNDS;92
12.8;REFERENCES;95
13;CHAPTER 8. TITANIUM, ZIRCONIUM AND HAFNIUM;96
13.1;BORIDES;96
13.2;ALKOXIDES;96
13.3;PHOSPHONATO COMPLEXES;98
13.4;ORGANO TITANIUM, ZIRCONIUM AND HAFNIUM;99
13.5;REFERENCES;104
14;CHAPTER 9. GROUP V TRANSITION ELEMENTS;105
14.1;VANADIUM;105
14.2;NIOBIUM AND TANTALUM;106
14.3;REFERENCES;108
15;CHAPTER 10. GROUP VI TRANSITION ELEMENTS;112
15.1;CHROMIUM;112
15.2;MOLYBDENUM;113
15.3;TUNGSTEN;117
15.4;REFERENCES;119
16;CHAPTER 12. MANGANESE, TECHNETIUM AND RHENIUM;123
16.1;GENERAL;123
16.2;MANGANESE;123
16.3;TECHNETIUM;130
16.4;RHENIUM;131
16.5;REFERENCES;137
17;CHAPTER 13. IRON;142
17.1;GENERAL;142
17.2;HYDRIDES AND PHOSPHINE COMPLEXES;142
17.3;COMPOUNDS WITH IRON-CARBON BONDS;143
17.4;COMPOUND WITH NITROGEN DONORS;143
17.5;COMPOUND WITH OXYGEN DONORS;144
17.6;COMPLEXES WITH SULFUR LIGANDS;145
17.7;HALIDE COMPLEXES;145
17.8;MISCELLANEOUS;146
17.9;REFERENCES;146
18;CHAPTER 14. COBALT and NICKEL;150
18.1;LOW OXIDATION STATES - COBALT(-I), COBALT(0), and COBALT(I);150
18.2;LOW-VALENT NICKEL COMPLEXES;153
18.3;COBALT(II) AND NICKEL(II) COMPLEXES;155
18.4;COBALT(III) COMPLEXES;157
18.5;NICKEL IN HIGHER OXIDATION STATES - NICKEL(III) AND NICKEL(IV);161
18.6;COBALT(IV);162
18.7;REFERENCES;162
19;CHAPTER 15. THE PLATINUM METALS PART I: RUTHENIUM, OSMIUM, RHODIUM AND IRIDIUM;168
19.1;INTRODUCTION;168
19.2;THE CHEMISTRY OF RUTHENIUM AND OSMIUM;168
19.3;THE CHEMISTRY OF RHODIUM AND IRIDIUM;176
19.4;REFERENCES;186
20;CHAPTER 16. THE PLATINUM METALS PART II: PALLADIUM AND PLATINUM;191
20.1;INTRODUCTION;191
20.2;REFERENCES;199
21;CHAPTER 17. SILICON;203
21.1;GENERAL;203
21.2;SILICON-HALOGEN;203
21.3;SILICON-NONMETAL;204
21.4;SILICON-METAL;206
21.5;SILICON-SILICON;207
21.6;REFERENCES;208
22;CHAPTER 18. Germanium, Tin, and Lead;210
22.1;GENERAL;210
22.2;METAL-METAL BONDED COMPOUNDS;212
22.3;COORDINATION COMPOUNDS OF Ge,Sn,Pb;216
22.4;REFERENCES;217
23;CHAPTER 19. NITROGEN;224
23.1;GENERAL;224
23.2;COMPOUNDS WITH NO N-N BONDS;224
23.3;COMPOUNDS WITH ONE N-N BOND;226
23.4;COMPOUNDS WITH THREE LINKED NITROGENS;227
23.5;COMPOUNDS WITH CHAINS OF FOUR NITROGENS;229
23.6;REFERENCES;230
24;CHAPTER 20. PHOSPHORUS;232
24.1;INTRODUCTION;232
24.2;NEW SYNTHESES;232
24.3;PHOSPHORUS-BORON CCMPOUNDS;234
24.4;PHOSPHORUS-HALOGEN COMPOUNDS;234
24.5;PHOSPHORUS-METAL DERIVATIVES;235
24.6;PHOSPHORUS-PHOSPHORUS BONDS;235
24.7;PHOSPHORUS-OXYGEN COMPOUNDS;236
24.8;PHOSPHORUS-NITROGEN COMPOUNDS;237
24.9;PHOSPHORUS -HYDROGEN COMPOUNDS;242
24.10;RADICALS IN PHOSPHORUS CHEMISTRY;242
24.11;PHOSPHORUS CONTAINING CAGE COMPOUNDS;242
24.12;COMPLEXES WITH PHOSPHORUS CONTAINING LIGANDS;243
24.13;REFERENCES;243
25;CHAPTER 21. ARSENIC, ANTIMONY AND BISMUTH;248
25.1;GENERAL;248
25.2;ORGANOMETALLIC COMPOUNDS OF ARSENIC, ANTIMONY- AND BISMUTH;248
25.3;INORGANIC As, Sb AND Bi COMPOUNDS;253
25.4;"ACCEPTOR COMPOUNDS" INVOLVING THE GROUP V ELEMENTS;254
25.5;REFERENCES;255
26;CHAPTER 22. THE CHALCOGENTIDES;259
26.1;OXYGEN;259
26.2;SULFUR;260
26.3;SELENIUM;266
26.4;TELLURIUM;267
26.5;POLONIUM;269
26.6;REFERENCES;269
27;CHAPTER 23. FLUORINE;273
27.1;GENERAL;273
27.2;NEW FLUORINATING AGENTS AND TECHNIQUES;273
27.3;XENON-FLUORINE COMPOUNDS;273
27.4;CHLORINE-PLUORINE COMPOUNDS;274
27.5;SULFUR-FLUORINE COMPOUNDS;274
27.6;NITROGEM-FLUORINE CHEMISTRY;275
27.7;CARBON-FLUORINE COMPOUNDS;276
27.8;FLUORO POLYMERS;277
27.9;SILICON-FLUORINE CHEMISTRY;278
27.10;REFERENCES;279
28;CHAPTER 24. HALOGENS AND PSEUDOHALOGENS;281
28.1;GENERAL;281
28.2;HALOGENS;281
28.3;PSEUDOHALOGEN COMPOUNDS OF MAIN GROUP ELEMENTS;287
28.4;COMPOUNDS WITH TRANSITION METALS;289
28.5;COMPOUNDS WITH INKER TRANSITION METALS;292
28.6;REFERENCES;292
29;CHAPTER 25. NOBLE GASES;297
29.1;GENERAL REMARKS;297
29.2;ARGON, KRYPTON;297
29.3;XENON;297
29.4;REFERENCES;299
30;CHAPTER 26. SIMPLE AND COMPLEX METAL HYDRIDES OF MAIN GROUPS I, II AND III;300
30.1;INTRODUCTION;300
30.2;SIMPLE HYDRIDES OF GROUPS I AND II;300
30.3;COMPLEX HYDRIDES OF GROUPS I AND II;301
30.4;ALUMINUM HYDRIDE;302
30.5;AMINE ADDUCTS OF ALUMINUM HYDRIDE;303
30.6;GROUP I METAL HYDRIDOALUMINATES;303
30.7;GROUP II METAL HYDRIDOALUMINATES;304
30.8;HYDRIDOGALLATES;305
30.9;REFERENCES;305
31;CHAPTER 27. NEW TECHNIQUES AND REAGENTS IN SYNTHETIC COORDINATION CHEMISTRY;307
31.1;SYNTHESIS OF LOW-VALENT METAL COMPLEXES;307
31.2;METAL COMPLEXES IN NORMAL OXIDATION STATES;310
31.3;METAL COMPLEXES IN HIGHER OXIDATION STATES;313
31.4;REFERENCES;313
32;CHAPTER 28. STABILIZING EFFECTS OF LARGE COUNTER-IONS;316
32.1;LARGE CATIONS;318
32.2;HYDROGEN BONDED COMPLEX IONS;320
32.3;ANIONIC BORON COMPLEXES;322
32.4;NITRATO COMPLEXES;323
32.5;THE POLYHALIDE IONS;324
32.6;TELLUROCYANATE SALTS;325
32.7;COUNTER-ION EFFECTS IN LINKAGE ISOMERISM;325
32.8;SILVER COMPLEXES;326
32.9;INDIUM COMPLEXES;326
32.10;TRICOORDIMTED GROUP IV METALS AND THEIR COMPLEXES;327
32.11;PENTACOORDINATED GROUP IV METALS;328
32.12;GROUP V;328
32.13;GROUP VI;329
32.14;LANTHANATE COMPLEXES;329
32.15;ACTINTDES;329
32.16;CARBONYL AND CYANO COMPLEXES;330
32.17;TRANSITION METAL COMPLEXES;330
32.18;CATIONIC COMPLEXES;332
32.19;STABILITY;332
32.20;REFERENCES;333