Industrial Arene Chemistry

Markets, Technologies, Sustainable Processes and Cases Studies of Aromatic Commodities, 4 Volume Set
1. Auflage 2023
ISBN: 978-3-527-34784-1
Verlag: WILEY-VCH

Buch, Englisch, 2416 Seiten, Format (B × H): 170 mm x 244 mm, Gewicht: 5131 g

Industrial Arene Chemistry
Explore the wide array of uses for aromatic hydrocarbons in this comprehensive reference
Aromatics are a class of compounds—normally but not exclusively organic—which tend to be produced as by-products of various industrial processes. Their importance as petrochemical materials in themselves, along with the range of inter-relations between different aromatic chemicals, creates a complex and opportunity-filled market for aromatics.
Industrial Arene Chemistry provides a thorough look at the conventional techniques required to use and produce these aromatic hydrocarbons. Beginning with an overview of the global aromatic market—including, but not limited to, manufacturers, markets of BTX, and downstream functional aromatics, aromatics derived from renewable sources, and economic forecasts—the book will also explore the impact shifting environmental factors will have on the future of aromatic chemistry. The text further explores BTX production processes differentiated according to the raw materials used. Importantly, this will establish the importance and growth of the biobased chemical industry.
Industrial Arene Chemistry readers will also find: - Case studies that describe major elements of specific technologies prototyped by contributors/companies as part of ongoing market development efforts
- Process chapters that include summaries of the conventional techniques and a more detailed discussion of recent high-impact studies
- Recent advances in conventional aromatic reactions, including alkylation, acylation and carboxylation, hydrogenation/reduction, oxidation, nitration/amination, sulfonation, and halogenation

Industrial Arene Chemistry is a useful reference for chemists and chemical engineers who work with aromatics.

Autoren/Hrsg.

Mortier, Jacques

Fachgebiete

• Technische Wissenschaften Verfahrenstechnik | Chemieingenieurwesen | Biotechnologie Verfahrenstechnik, Chemieingenieurwesen
• Technische Wissenschaften Verfahrenstechnik | Chemieingenieurwesen | Biotechnologie Chemische Verfahrenstechnik
• Naturwissenschaften Chemie Physikalische Chemie Chemische Reaktionen, Katalyse

Inhaltsverzeichnis

Volume 1

Foreword xxi

Preface xxv

Section 1 The Markets for Aromatic Commodities 1

1 The Fossil-Based BTX Market 3
Andy Nicholson

2 The Downstream Functional Aromatics Market 19
Andy Nicholson

3 Crude Oil to Chemicals: Industry Development and Strategic Implications 43
Rong J. Chang

Section 2 BTX, Naphthalene and Higher Aromatics from Fossil-Based Sources 71

4 BTX from Light Hydrocarbons 73
Minghui Tan, Li Tan, Guohui Yang, and Yisheng Tan

5 BTX Aromatics from Naphtha Hydrocarbons 111
Arno de Klerk

6 BTX Aromatics from Heavier Material than Naphtha 145
Arno de Klerk

7 BTX Aromatics from Other Conversion Processes 171
Arno de Klerk

8 Bi- and Tri-nuclear Aromatic Production 195
Arno de Klerk

9 Extraction Separation of Aromatics 209
Weize Wu

10 The Honeywell UOP CCR PlatformingTM Process for BTX Production (Case Study) 269
Bryan Egolf, David Lafyatis, Manuela Serban, Ka Lok, and Mark Lapinski

11 The Honeywell UOP ParexTM Process: Fifty Years of Growth for the Petrochemical Industry (Case Study) 297
Patrick C. Whitchurch and James A. Johnson

12 Forty Years of Xylene Isomerization Technology Deployment at ExxonMobil (Case Study) 327
Michel Molinier, Robert G. Tinger, Arnaud Cotte, and Jeevan S. Abichandani

13 ExxonMobil PxMaxSM Process: Production of Paraxylene (Case Study) 357
Michel Molinier and Jeevan S. Abichandani

14 BP/Amoco Paraxylene Crystallization Technology (Case Study) 383
Jeffrey A. Amelse

15 Reactions and Mechanisms of Xylene Isomerization and Related Processes 403
Jeffrey A. Amelse

16 Honeywell UOP Tatoray Process: Maximizing Feed Utilization for Aromatics Production (Case Study) 439
Raymond Shih and Eseoghene Jeroro

17 The Honeywell UOP MX SorbexTM Process: Enabling Growth of PET Resin Applications (Case Study) 453
James Johnson and Patrick Whitchurch

Section 3 Aromatics from Methanol and Synthesis Gas 479

18 Methanol-to-Aromatics Compounds (MTA) Process 481
Ning Wang, Huiqiu Wang, Hao Xiong, Wenlong Song, and Weizhong Qian

19 Carbon Monoxide and Carbon Dioxide for Aromatics Production 533
Yuebing Xu, Bing Liu, Feng Jiang, and Xiaohao Liu

Volume 2

Foreword xxiii

Preface xxvii

Section 4 The Chemistry of Downstream Functional Aromatics 555

Section 4.1 Alkylation 555

20 Homogeneous Friedel–Crafts Alkylation 557
Venkata D. B. C. Dasireddy, Gurwinder Singh, Stalin Joseph, Yoshihiro Sugi, and Ajayan Vinu

21 Heterogeneous Friedel–Crafts Alkylation 595
Yoichi Nishimura, Venkata D. B. C. Dasireddy, Stalin Joseph, Yoshihiro Sugi, and Ajayan Vinu

22 Badger Ethylbenzene Technology (Case Study) 645
Raghavender Bhoomi and Brian Maerz

23 Exelus Styrene Monomer (ExSyM) Process (Case Study) 673
Vamsi M. Vadhri, Tom Hickey, and Mitrajit Mukherjee

24 INEOS Phenol Cumene Chemistry (Case Study) 715
Ralf Bonmann, Manfred Weber, and Markus Weber

25 Linear Alkylbenzenes: An Overview of the Commercial HF and DetalTM Process Unit Alkylation Technology (Case Study) 729
Stephen Sohn and Phuong Do

26 Frontiers in Arene Chemistry: Direct Methylation of Benzene with Methane on Metal-Loaded Zeolites 747
Etsushi Tsuji and Naonobu Katada

Section 4.2 Acylation and Carboxylation 769

27 Acylation of Arenes 771
Chandrakanth R. Gadipelly, Gunjan Deshmukh, Suresh Bhargava, Selvakannan Periasamy, and Lakshmi Kantam Mannepalli

28 Carboxylation Reaction Based on the Direct and Indirect Uses of CO2: Sustainable Syntheses of C—CO2, O—CO2, and N—CO2 Bonds 807
Francesco Nocito and Angela Dibenedetto

Section 4.3 Reduction of Aromatic Nuclei 849

Über Autor(innen)

Jacques Mortier, PhD, is Professor of Organic Chemistry at Le Mans University (former University of Maine) in France, where he teaches classes on Industrial Organic Chemistry and Reaction Mechanisms in Aromatic and Heteroaromatic Chemistry. Dr. Mortier started his career as a research chemist in the crop protection industry. At Le Mans University, his research is focused on various topics dealing with polar organometallics, directed aromatic metalation methodologies, and the study of reaction mechanisms. He has extensive experience as a consultant for the chemical industry. In recognition of his research expertise, he was distinguished as a member of the University Institute of France (IUF).