E-Book, Englisch, 408 Seiten, Web PDF
Malone / Belcher / Anderson The Determination of Hydrazino-Hydrazide Groups
1. Auflage 2013
ISBN: 978-1-4831-5300-1
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark
Monographs in Organic Functional Group Analysis
E-Book, Englisch, 408 Seiten, Web PDF
ISBN: 978-1-4831-5300-1
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark
The Determination of Hydrazino-Hydrazide Groups discusses the analytical methods for the analysis of hydrazino, hydrazide, hydrazine, substituted hydrazines, and hydrazine derivatives. It also shows the usefulness of hydrazines and its derivatives as analytical reagents. The book presents a detailed examination of a variety of analytical methods used in determining hydrazines and hydrazides derivatives. These methods include oxidation, colorimetry and spectrophotometry, coulometry, polarography, and gasometric and acid-based methods. The book concludes by discussing the use of hydrazines as analytical reagents. The text is invaluable for everyone interested in hydrazides and hydrazines and their applications.
Autoren/Hrsg.
Weitere Infos & Material
1;Front Cover;1
2;The Determination of Hydrazino–Hydrazide Groups;4
3;Copyright Page;5
4;Table of Contents;8
5;Dedication;6
6;PREFACE;14
7;GENERAL INTRODUCTION;16
8;CHAPTER 1. OXIDATION METHODS;18
8.1;1. Use of Bromate;18
8.2;2. Use of Bromine;23
8.3;3. Use of N-Bromosuccinimide;25
8.4;4. Use of Ceric Sulfate;35
8.5;5. Use of Ceric Sulfate–Iodine Monochloride;36
8.6;6. Use of Diethylenetetraammonium Ceric Sulfate;39
8.7;7. Use of Chloramine-T;40
8.8;8. Use of Chloramine-T–Iodine Monochloride;41
8.9;9. Use of Chloramine-B;41
8.10;10. Use of Chloramine-B–Iodine Monochloride;42
8.11;11. Use of Copper Oxide;42
8.12;12. Use of Copper Oxide—Fehling's Solution;44
8.13;13. Use of Copper Sulfate;47
8.14;14. Use of Dichromate;47
8.15;15. Use of Potassium Ferricyanide–Ascorbic Acid;48
8.16;16. Use of Ferricyanide–Ceric Sulfate;48
8.17;17. Use of Ferricyanide–Zinc Sulfate;50
8.18;18. Use of Hypochlorous Acid;52
8.19;19. Use of Hypochlorite;55
8.20;20. Use of lodic Acid;56
8.21;21. Use of Iodine;58
8.22;22. Use of Iodate;69
8.23;23. Use of Periodate;97
8.24;24. Use of Periodate–Iodine Bromide;98
8.25;25· Use of Periodate–Iodine Cyanide;100
8.26;26. Use of Permanganate;101
8.27;27. Use of Selenious Acid;119
8.28;28. Use of Thallium;119
8.29;29. Use of Vanadic Acid;121
8.30;References;123
9;CHAPTER 2. GASOMETRIC METHODS;125
9.1;1. Use of Bromate;125
9.2;2. Use of Bromine–Hypobromite;127
9.3;3. Use of Cupric–Fehling's Solution;127
9.4;4. Use of Cupric Sulfate;128
9.5;5. Use of Ferricyanide;133
9.6;6. Use of Iodate;134
9.7;7. Use of Lead Oxide;150
9.8;8. Use of Mercuric Chloride;153
9.9;References;153
10;CHAPTER 3. COLORIMETRIC AND SPECTROPHOTOMETRIC METHODS;154
10.1;1. Determination of Isonicotinic Acid Hydrazide (INH);154
10.2;2. Determination of Maleic Hydrazide;182
10.3;3. Determination of Hydrazine;190
10.4;4. Determination of Hydrazine and Benzylhydrazine;199
10.5;5. Determination of 1,1-Dimethylhydrazine (UDMH);202
10.6;6. Determination of Monomethylhydrazine;214
10.7;References;220
11;CHAPTER 4. CHROMATOGRAPHIC METHODS;222
11.1;1. Ion Exchange Chromatography;222
11.2;2. Paper Chromatography;224
11.3;3. Thin Layer Chromatography;241
11.4;References;244
12;CHAPTER 5. COULOMETRIC METHODS;246
12.1;1. Determination of Hydrazine and Substituted Hydrazines;246
12.2;References;264
13;CHAPTER 6. POLAROGRAPHIC METHODS;265
13.1;1. Determination of Hydrazine, Phenylhydrazine, and
Semicarbazide;266
13.2;2. Determination of Isonicotinic Acid Hydrazide;267
13.3;3. Determination of p,p-Oxybis (Benzenesulfonyl) Hydrazide;267
13.4;References;272
14;CHAPTER 7. ACID–BASE METHODS;273
14.1;1. Aqueous Methods;273
14.2;2. Non-aqueous Methods;275
14.3;References;284
15;CHAPTER 8. THE ANALYSIS OF MIXTURES;285
15.1;1. Hydrazine–l,l-Dimethylhydrazine Mixtures;285
15.2;2. Hydrazine–Monomethylhydrazine Mixtures;304
15.3;3. Hydrazine–1,1-Dimethylhydrazine and Monomethylhydrazine–1,1-Dimethylhydrazine Mixtures;316
15.4;4. Hydrazine–Monomethylhydrazine–I,I- Dimethylhydrazine Mixtures;321
15.5;5. Hydrazine–Aniline Mixtures;325
15.6;6. Hydrazine–Ammonia Mixtures;328
15.7;7. Hydrazine–Ammoida–Hydrogen–Nitrogen–Argon Mixtures;334
15.8;8. Hydrazine–Hydroxylamine Mixtures;336
15.9;9. Hydrazine–Ammonium Hydroxide–Hydroxylamine Mixtures;346
15.10;10. Hydrazine–Hydrazine Nitrate Mixtures;353
15.11;11. Determination of Diethylenetriamine (DETA) with either Hydrazine, Monomethylhydrazine, or 1,1-Dimethylhydrazine;355
15.12;References;364
16;CHAPTER 9. OTHER QUALITATIVE AND QUANTITATIVE TESTS;366
16.1;1. Spot Tests;366
16.2;2. Microbiological Tests;368
16.3;3. Field Tests;371
16.4;References;374
17;CHAPTER 10. THE USE OF HYDRAZINES AS ANALYTICAL REAGENTS;375
17.1;1. Use of 1,1-Dimethylhydrazine;375
17.2;2. Use of 2,4-Dinitrophenylhydrazine;376
17.3;3. Use of 1,5-Diphenylcarbazide;379
17.4;4. Use of Hydrazine;381
17.5;5. Use of 2-Hydrazinobenzothiazole;387
17.6;6. Use of Isonicotinic Acid Hydrazide ;389
17.7;7. Use of Oxalyldihydrazide;389
17.8;8. Use of Phenylhydrazine;390
17.9;9. Use of Salicyloylhydrazide;392
17.10;10. Use of Semicarbazide;394
17.11;References;395
18;AUTHOR INDEX;398
19;SUBJECT INDEX;404
20;OTHER TITLES IN THE SERIES IN ORGANIC FUNCTIONAL GROUP ANALYSIS;410
