Tailored Metal Catalysts

1986
ISBN: 978-90-277-1866-2
Verlag: Springer Netherlands

Buch, Englisch, Band 7, 333 Seiten, HC runder Rücken kaschiert, Format (B × H): 160 mm x 241 mm, Gewicht: 1460 g

Reihe: Catalysis by Metal Complexes

Well tailored metal catalysts are catalysts of the new generation resulting from scientific development at the boundary between homogeneous and hetero­ geneous chemistry. The main factors involved in making tailored metal catalysts are not those of traditional impregnation in which the chemistry is in general unknown and ill-defined, or of simple ion exchange which involves long-range forces with little control on the local structure through definite and special bond direction. Tailored Metal Catalysts thus has a rather different emphasis from normal review publications in the field of catalysis. Here we concentrate more on the distinct surface chemistry and catalytic properties of important established materials with well-characterized active structures or precursors, although at the same time providing a systematic presentation of relevant data. Many pioneering works have been undertaken in the field of tailored metal catalysts since the early research on polymer-attached homogeneous metal complexes by the British Petroleum Company Ltd. and the Mobil Oil Corpora­ tion around 1969; transition metal complexes attached on polymers by Grubbs (1971), Heinemann (1971), Manassen (1971), Pittman (1971), Bursian et al. (1972), Kagan (1973), Bailar (1974); transition metal complexes attached on inorganic oxides by Allum et al. (1972), Ballard (1973), Candlin and Thomas (1974), Murrell (1974), Yermakov (1974); metal carbonyls/polymers by Moffat (1970); metal carbonyls/inorganic oxides by Parkyns (1965), Davie et al. (1969), Banks et al. (1969), Howe (1973), Burwell (1975); metal carbonyl clusters/ polymers by Colhnan (1972); metal carbonyl clusters/inorganic oxides by Robertson and Webb (1974), Anderson (1974), Smith et al. (1975).

Zielgruppe

Research

Autoren/Hrsg.

Iwasawa, Y.

Fachgebiete

• Naturwissenschaften Chemie Physikalische Chemie Chemische Reaktionen, Katalyse
• Naturwissenschaften Chemie Organische Chemie Organometallchemie
• Naturwissenschaften Chemie Anorganische Chemie Nichtmetallische Chemie
• Naturwissenschaften Chemie Physikalische Chemie Elektrochemie, Magnetochemie

Inhaltsverzeichnis

Inorganic Oxide-attached Metal Catalysts.- 1. Introduction.- 2. General Features of Homogeneous and Heterogeneous Catalysts.- 3. General Aspects of the Development of Attached Metal Catalysts.- 4. Physical Techniques for the Characterization of Surface-attached Species.- 5. Polymers and Inorganic Oxides as Supports.- 6. Surface Hydroxyl Groups on Inorganic Oxides.- 7. The Functionalization of Inorganic Oxide Surfaces.- 8. Attached Metal Complex Catalysts.- 9. Tailored Metal Catalysts.- 10. Concluding Remarks.- References.- Polymer-attached Catalysts.- 1. Introduction.- 2. Polymer-anchored Catalysts.- 3. Polymer-protected Colloidal Catalysts.- 4. Concluding Remarks.- References.- The Preparation of Heterogeneous Catalysts from Mononuclear Carbonyl Complexes on Inorganic Supports.- General Aspects of Catalyst Preparation.- 3. Group VI Carbonyl Complexes.- 4. Group VIII Carbonyl Complexes.- 5. Group V Carbonyl Complexes.- 6. Concluding Remarks.- 7. Literature Update.- References.- Surface-supported Metal Clusters and their Catalysis in CO-based Reactions.- 1. Introduction.- 2. Preparation and Characterization of Surface-supported Metal Clusters.- 3. Selectivity Aspects of Fischer-Tropsch (F-T) Synthesis with Supported Metal Carbonyls.- 4. Carbonylation Reactions Catalyzed by Cluster-impregnated Catalysts.- 5. Synthesis of Oxygenated Carbon Compounds from Synthesis Gas.- References.- Asymmetrically Modified Nickel Catalysts.- 1. Introduction.- 2. General Considerations in Reactions Relating to MNi.- 3. MNi as a Practical Enantio-differentiating Hydrogenation Catalyst.- 4. MNi, its Structure and Mode of Action.- 5. Conclusions.- References.