Herrmann / Salzer Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 1, 1996

Volume 1: Literature, Laboratory Techniques, and Common Starting Materials
1. Auflage 2014
ISBN: 978-3-13-179161-0
Verlag: Thieme
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 192 Seiten, PDF

Designed as a benchtop tool, the series includes detailed and reliable experimental procedures for the preparation of common but imp ortant starting compounds, organized according to the periodic table. Properties of the compounds and additional references are also provided. In most cases, no strict borderline has been drawn between inorganic and organometallic compounds. Instead, the material is conveniently presented so that for every group of elements, the various aspects of the chemistry are combined. Several hundred in ternational specialists with established expertise in their respective fields have contributed, resulting in proven and reliable pre parations. In view of the enormous growth of organometallic chemistry, Synthetic Methods of Organometallic and Inorganic Chemistry p rovides you with a balanced compilation of carefully selected and representative examples for all classes of compounds. // The conte nt of this e-book was originally published in 1996.

Zielgruppe

Wissenschaftler

Autoren/Hrsg.

Salzer, Albrecht

Herrmann, Wolfgang A.

Fachgebiete

• Naturwissenschaften Chemie Organische Chemie Organometallchemie
• Naturwissenschaften Chemie Anorganische Chemie
• Naturwissenschaften Chemie Chemie Allgemein Chemische Labormethoden, Stöchiometrie

Inhaltsverzeichnis

1;Preface to the SeriesSynthetic Methods of Organometallic and Inorganic Chemistry;5
2;Preface to Volume 1;7
3;Contents;8
4;Chapter 1: Inorganic and Organometallic Chemical Literature;10
4.1;1.1 Introduction;11
4.2;1.2 Reference Books;11
4.3;1.3 The Inorganic Literature;12
4.3.1;1.3.1 General Textbooks;12
4.3.2;1.3.2 Handbooks and Review Articles on Synthetic Methods;12
4.3.3;1.3.3 Review Series — Books;14
4.3.4;1.3.4 Review Series — Journals;14
4.3.5;1.3.5 Journals;14
4.4;1.4 The Organometallic Literature;14
4.4.1;1.4.1 Textbooks on Main-Group and Transition-Element Organometallics;14
4.4.2;1.4.2 Textbooks on Transition-Metal Organometallics;15
4.4.3;1.4.3 Special Monographs;15
4.4.4;1.4.4 Review Series — Books;16
4.4.5;1.4.5 Journals;16
5;Chapter 2: Laboratory Techniques of Organometallic Chemistry;17
5.1;2.1 Introduction;18
5.2;2.2 The Purification of Inert Gases and Solvents;18
5.2.1;2.2.1 Inert Gases;18
5.2.2;2.2.2 The Purification and Deoxygenation of Solvents;20
5.3;2.3 The Manipulation of Air-Sensitive Compounds;24
5.3.1;2.3.1 General Remarks;24
5.3.2;2.3.2 Vacuum Line and Glove -Box Techniques;25
5.3.3;2.3.3 Schlenk Techniques;25
5.3.4;2.3.4 Handling Air-Sensitive Solutions;33
6;Chapter 3 Commonly Used Starting Materials;38
6.1;3.1 Introduction;39
6.2;3.2 High Pressure Reactions;40
6.3;3.3 Materials;41
6.3.1;3.3.1 Carbon and Graphite;41
6.3.2;3.3.2 Alkali Metal-Graphite Intercalation Compounds;43
6.3.3;3.3.3 Alkali and Alkaline Earth Metal Compounds and Alloys;45
6.4;3.4 Ligands;59
6.4.1;3.4.1 Carbon-Based Ligands;59
6.4.2;3.4.2 Silicon-Based Compounds;81
6.4.3;3.4.3 Silylene Transfer Reagents;85
6.4.4;3.4.4 Glass- and Silica Gel-Based Reagents;87
6.4.5;3.4.5 Germanium-Based Compounds;89
6.4.6;3.4.6 Nitrogen-, Phosphorus-, and Antimony-Based Compounds (Group 15 Ligands);89
6.5;3.5 Transition Metal Compounds and Complexes;99
6.5.1;3.5.1 Titanium (Ti), Zirconium (Zr), and Hafnium (Hf) Compounds;99
6.5.2;3.5.2 Selected Applications of Titanium Reagents;108
6.5.3;3.5.3 Lanthanide Complexes;114
6.5.4;3.5.4 Vanadium (V), Niobium (Nb), and Tantalum (Ta) Compounds;115
6.5.5;3.5.5 Chromium (Cr), Molybdenum (Mo), and Tungsten (W) Compounds;124
6.5.6;3.5.6 Manganese (Mn) and Rhenium (Re) Compounds;139
6.5.7;3.5.7 Iron (Fe), Ruthenium (Ru), and Osmium (Os) Compounds;144
6.5.8;3.5.8 Cobalt (Co), Rhodium (Rh), and Iridium Compounds;150
6.5.9;3.5.9 Nickel (Ni), Palladium (Pd), and Platinum (Pt) Compounds;161
6.5.10;3.5.10 Gold (Au) Compounds;178
7;Index;181