Forrest / Rabine / Rouillard Organic Spectroscopy Workbook

1. Auflage 2011
ISBN: 978-1-119-97594-6
Verlag: John Wiley & Sons
Format: PDF
Kopierschutz: Adobe DRM (»Systemvoraussetzungen)

E-Book, Englisch, 272 Seiten, E-Book

Spectroscopy is used in physical and analytical chemistry for the identification of substances through the spectrum emitted from or absorbed by them. The derivation of structural information from spectroscopic data is now an integral part of many courses in chemistry and related subjects at most universities.
This workbook:
* Features exercises to help develop the student's understanding of how structures are determined from spectra and to promote the student's own interpretation of different spectra.
* Covers a large range of spectroscopic data, including mass spectrometry, infrared and ¯1H and ¯13C nuclear magnetic resonance, typically used in the routine analysis of small-sized organic molecules.
* Presents in full-color, in a workbook-friendly format the spectra for interpretation with explanations and analyses on the facing page.
Related to the workbook the authors have an online resource of the problems featured in the workbook, available at: htttp://spectros.unice.fr/ By using the print edition alongside the online spectra, students will be able to enhance their understanding of the interpretation of multiple spectra.

Autoren/Hrsg.

Forrest, Tom

Rabine, Jean-Pierre

Rouillard, Michel

Inhaltsverzeichnis

Preface vii
Acknowledgements ix
How to Use this Workbook 1
Preliminary Observations 2
Centres of Unsaturation 8
Exercises 1-100 10
Infrared Data 210
IR Frequencies: Display of Infrared Database by Frequency210
IR Groups: Display of Infrared Database by Functional Group216
1H NMR Data 221
General Tables of Functional Groups 221
Comparison of delta of Alkyl Groups Bearing aSubstituent in alpha or beta Position 225
Alkyl Groups with an alpha Substituent 226
Alkyl Groups with a beta Substituent 226
Tables of delta for -CH2- Doubly Substitutedin alpha Position 227
Tables of delta for Aromatics 229
Coupling Constants 230
13C NMR Data 233
General Ranges for CH3-, -CH2-,>CH-. . . 233
Chemical Shift Ranges for Functional Groups 234
Chemical Shift Estimations 234
Mass Spectrometry Data 240
Main Fragments Observed 240
Atomic Masses 242
Isotopic Abundances in % 243
Internet Resources 254
Glossary of Terms Used in the Exercises 255
Answers 257
Index 261

Über Autor(innen)

Tom Forrest
Department of Chemistry, Dalhousie University, Canada
Jean-Pierre Rabine
Centre de Développement Informatique Enseignement Chimie,Université de Nice Sophia-Antipolis, France
Michel Rouillard
Centre de Développement Informatique Enseignement Chimie,Université de Nice Sophia-Antipolis, France