Danielli / Rosenberg / Cadenhead Progress in Surface and Membrane Science

Volume 7
1. Auflage 2013
ISBN: 978-1-4832-1973-8
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 350 Seiten, Web PDF

Progress in Surface and Membrane Science, Volume 7 covers the developments in the study of surface and membrane science. The book discusses the theoretical and experimental aspects of the van der Waals forces; the electric double layer on the semiconductor-electrolyte interface; and the long-range and short-range order in adsorbed films. The text also describes the hydrodynamical theory of surface shear viscosity; the structure and properties of monolayers of synthetic polypeptides at the air-water interface; and the structure and molecular dynamics of water. The role of glycoproteins in cell adhesion is also considered. Physicists, zoologists, molecular biologists, and scientists involved in the study of electrochemistry will find the book invaluable.

Autoren/Hrsg.

Danielli, J. F.

Rosenberg, M. D.

Cadenhead, D. A.

Inhaltsverzeichnis

1;Front Cover;1
2;Progress in Surface and Membrane Science;4
3;Copyright Page;5
4;Table of Contents;6
5;CONTRIBUTORS;10
6;CONTENTS OF PREVIOUS VOLUMES;12
7;CHAPTER 1. VAN DER WAALS FORCES: THEORY AND EXPERIMENT;18
7.1;I. THE FORCES BETWEEN ATOMS AND MOLECULES;19
7.2;II. VAN DER WAALS DISPERSION FORCES BETWEEN ATOMS, MOLECULES, AND SMALL PARTICLES;21
7.3;III. THE DRUDE OSCILLATOR MODEL;25
7.4;IV. DISPERSION FORCES BETWEEN ANISOTROPIC AND ASYMMETRIC MOLECULES;28
7.5;V. FORCES BETWEEN LARGE MOLECULES OR SMALL PARTICLES;31
7.6;VI. DISPERSION FORCES BETWEEN MACROSCOPIC BODIES;34
7.7;VII. DISPERSION FORCE BETWEEN AN ATOM OR SMALL PARTICLE AND A FLATSURFACE;37
7.8;VIII. DISPERSION FORCES BETWEEN HALF SPACES (FLAT SURFACES);39
7.9;IX. TEMPERATURE-DEPENDENT VAN DER WAALS FORCES;42
7.10;X. METHODS OF CALCULATING THE NONRETARDED FORCES BETWEEN LARGE BODIES;43
7.11;XI. FORCES BETWEEN LARGE SPHERICAL BODIES;53
7.12;XII. INTERACTIONS BETWEEN ANISOTROPIC MEDIA;54
7.13;XIII. DISPERSION FORCES BETWEEN BODIES WITH SURFACE LAYERS;55
7.14;XIV. EXPERIMENTAL WORK ON VAN DER WAALS FORCES;60
7.15;LIST OF SYMBOLS;69
7.16;REFERENCES;70
8;CHAPTER 2. ELECTRIC DOUBLE LAYER ON THE SEMICONDUCTOR–ELECTROLYTE INTERFACE;74
8.1;I. INTRODUCTION;74
8.2;II. THE THEORY OF THE DOUBLE LAYER ON THE SEMICONDUCTOR–ELECTROLYTE INTERFACE;76
8.3;III. METHODS OF STUDYING SURFACE PROPERTIES OF SEMICONDUCTOR ELECTRODES;87
8.4;IV. SOME SIGNIFICANT RESULTS OF EXPERIMENTAL STUDY OF SURFACE PROPERTIES OF SEMICONDUCTOR ELECTRODES;94
8.5;V. CONCLUSIONS;106
8.6;REFERENCES;107
9;CHAPTER 3. LONG-RANGE AND SHORT-RANGE ORDER IN ADSORBED FILMS;112
9.1;I. INTRODUCTION;112
9.2;II. THEORY;115
9.3;III. EXPERIMENTAL MATERIALS AND TECHNIQUES;136
9.4;IV. EXPERIMENTAL RESULTS: "CLASSICAL" FILMS;140
9.5;V. EXPERIMENTAL RESULTS: HELIUM FILMS;150
9.6;REFERENCES;164
10;CHAPTER 4. THE HYDRODYNAMICAL THEORY OF SURFACE SHEAR VISCOSITY;168
10.1;I. INTRODUCTION;168
10.2;II. BASIC EXPERIMENTAL METHODS;169
10.3;III. BOUNDARY CONDITIONS AT A FREE INTERFACE;170
10.4;IV. THE CANAL SURFACE VISCOMETER;171
10.5;V. USEFUL APPROXIMATIONS FOR THE CANAL METHOD;175
10.6;VI. THE CANAL VISCOMETER OF EWERS AND SACK;176
10.7;VII. THE VISCOUS TRACTION CANAL VISCOMETER;177
10.8;VIII. ERRORS INHERENT IN THE VISCOUS TRACTION INSTRUMENT;181
10.9;IX. THE ROTATING RING SURFACE VISCOMETER;182
10.10;X. A CRITIQUE OF KNIFE-EDGE RING VISCOMETERS;185
10.11;XI. TORQUE THEORY;186
10.12;XII. VARIANTS IN THE DESIGN OF TORSION VISCOMETERS;187
10.13;XIII. NON-NEWTONIAN SURFACE VISCOSITY;190
10.14;XIV. THE BINGHAM PLASTIC MODEL;191
10.15;XV. THE DETERMINATION OF NON-NEWTONIAN SURFACE SHEAR VISCOSITY WITHOUT THE ASSUMPTION OF A MODEL;192
10.16;XVI. LIQUID-LIQUID INTERFACIAL VISCOSITIES;193
10.17;XVII. SUMMARY AND CONCLUSIONS;196
10.18;LIST OF SYMBOLS;196
10.19;REFERENCES;197
11;CHAPTER 5. THE STRUCTURE AND PROPERTIES OF MONOLAYERS OF SYNTHETIC POLYPEPTIDES AT THE AIR–WATER INTERFACE;200
11.1;I. INTRODUCTION;200
11.2;II. POLYPEPTIDE CONFORMATIONS AT INTERFACES;202
11.3;III. EXPERIMENTAL PROCEDURES;214
11.4;IV. EXPERIMENTAL RESULTS ON POLYMERS CONFORMING TO A GENERAL PATTERN;217
11.5;V. EXTENDED CONFORMATIONS IN MONOLAYERS;235
11.6;VI. MIXED MONOLAYERS;239
11.7;VII. REACTIONS IN MONOLAYERS;241
11.8;REFERENCES;244
12;CHAPTER 6. THE STRUCTURE AND MOLECULAR DYNAMICS OF WATER;248
12.1;I. INTRODUCTION;248
12.2;II. REVIEW OF WATER STRUCTURE MODELS;252
12.3;III. RECENT SPECTROSCOPIC STUDIES OF WATER STRUCTURE;265
12.4;IV. COMPUTER SIMULATION STUDIES OF THE STATIC AND DYNAMIC PROPERTIES OF WATER;272
12.5;V. THE ROLE OF WATER IN SOLUTIONS AND IN MEMBRANES;278
12.6;REFERENCES;284
13;CHAPTER 7. GLYCOPROTEINS IN CELL ADHESION;288
13.1;I. INTRODUCTION;288
13.2;II. EVIDENCE FOR THE OCCURRENCE OF HETEROSACCHARIDE MATERIALS AT THE CELL SURFACE;288
13.3;III. STRUCTURE OF MEMBRANE GLYCOPROTEINS;293
13.4;IV. EVIDENCE FOR GLYCOPROTEINS IN CELL ADHESION;301
13.5;V. THEORIES OF CELL ADHESION;315
13.6;VI. POSSIBLE ROLES FOR GLYCOPROTEINS IN CELL ADHESION;323
13.7;REFERENCES;330
14;AUTHOR INDEX;336
15;SUBJECT INDEX;347