Crabtree Handbook of Green Chemistry - Green Catalysis

Volume 1 - Homogeneous Catalysis
1. Auflage 2014
ISBN: 978-3-527-68838-8
Verlag: Wiley-VCH
Format: PDF
Kopierschutz: Adobe DRM (»Systemvoraussetzungen)

E-Book, Englisch, 414 Seiten, E-Book

Nicht nur in den westlichen Industrieländern ist Umweltschutz heute ein selbstverständlicher Bestandteil der gesellschaftlichen Existenz. Über die Entwicklung der Grünen Chemie und Technik informiert das 12-bändige "Handbook of Green Chemistry" (herausgegeben von Paul Anastas, dem Vater der Grünen Chemie), zu dem dieser vorliegende Band über Grüne Homogene Katalyse gehört. Ausführlich wie nie zuvor behandelt er alle Aspekte der umweltverträglichen und nachhaltigen homogenen Katalyse, wie zum Beispiel Atomökonomie, Oxidationen mit Wasserstoffperoxid, industrielle Prozesse und vieles weitere mehr.

Autoren/Hrsg.

Crabtree, Robert H.

Weitere Mitwirkende

Anastas, Paul T.

Inhaltsverzeichnis

ATOM ECONOMY - PRINCIPLES AND SOME EXAMPLES

Introduction

Principle of Atom Economy

Atom Economical by Design: Examples of Reactions Relying on C-H Activation

Conclusion

CATALYSIS INVOLVING FLUOROUS PHASES: FUNDAMENTALS AND DIRECTIONS FOR GREENER METHODOLOGIES

Introduction

Directions for Greener Fluorous Methodologies

Solvents for Fluorous Chemistry

Ponytails and Partition Coefficients

Specific Examples of Catalyst Recovery that Exploit Temperature-dependent Solubilities

Specific Examples of Catalyst Recovery that Exploit Fluorous Solid Phases

Summary and Perspective

CHEMISTRY AND APPLICATIONS OF IRON-TAML CATALYSTS IN GREEN OXIDATION PROCESSES BASED ON HYDROGEN PEROXIDE

Introduction

Properties of Fe-TAMLs and Mechanisms of Oxidation with Hydrogen Peroxide

Applications of Fe-TAMLs

Conclusion

MICROWAVE-ACCELERATED HOMOGENEOUS CATALYSIS IN WATER

Introduction

Suzuki-Miyaura Reactions

The Stille Reaction

The Hiyama Cross-Coupling Reaction

The Heck Reaction

Carbonylation Reactions

The Sonogashira Reaction

Aryl-Nitrogen Couplings

Aryl-Oxygen Couplings

Miscellaneous Transformations

Conclusion

IONIC LIQUIDS AND CATALYSIS: THE IFP BIPHASIC DIFASOL PROCESS

Introduction

The Solvent in Catalytic Reactions

The Catalytic Oligomerization of Olefins

The Biphasic Difasol Process

Conclusion

IMMOBILIZATION AND COMPARTMENTALIZATION OF HOMOGENEOUS CATALYSTS

Introduction

Soluble Dendrimer-bound Homogeneous Catalysts

Polymer-bound Homogeneous Catalysts

Conclusion and Outlook

INDUSTRIAL APPLICATIONS OF HOMOGENEOUS ENANTIOSELECTIVE CATALYSTS

Introduction and Scope

Critical Factors for the Technical Application of Homogeneous Enantioselective Catalysts

Industrial Processes: General Comments

Hydrogenation of C=C Bonds

Hydrogenation of C=O Bonds

Hydrogenation of C=N Bonds

Oxidation Processes

Miscellaneous Transformations (Isomerization, Addition Reactions to C=C, C=O and C=N Bonds, Opening of Oxacycles)

Conclusions and Future Developments

HYDROGENATION FOR C-C BOND FORMATION

By-product-free C-C Coupling and the Departure from Preformed Organometallic Reagents

Hydrogenative Vinylation of Carbonyl Compounds and Imines

Hydrogenative Allylation of Carbonyl Compounds

Hydrogenative Aldol and Mannich Additions

Hydrogenative Acyl Substitution (Reductive Hydroacylation)

Hydrogenative Carbocyclization

Future Directions

ORGANOCATALYSIS

Introduction

Catalysts

Reactions

Conclusion

PALLADACYCLES IN CATALYSIS

Introduction

Catalyst Precursors for C-C and C-X (Heteroatom) Coupling Reactions

Other Catalytic Reactions Catalyzed by Palladacycles

Conclusion

HOMOGENEOUS CATALYST DESIGN FOR THE SYNTHESIS OF ALIPHATIC POLYCARBONATES AND POLYESTERS

Introduction

Synthesis of Aliphatic Polycarbonates from Epoxides and Carbon Dioxide

Synthesis of Aliphatic Polyesters

THE AEROBIC OXIDATION OF p-XYLENE TO TEREPHTHALIC ACID: A CLASSIC CASE OF GREEN CHEMISTRY IN ACTION

Introduction

Methods of Making Terephthalic Acid Using Stoichiometric Reagents

Methods for Preparing Terephthalic Acid Using Cobalt Acetate and Dioxygen in Acetic Acid

Adding Bromide to Improve Terephthalic Acid Production Using Cobalt and Manganese Acetates in Acetic Acid

Potential Processes Using Water as a Solvent

Summary and Final Comments

Über Autor(innen)

Series Editor

Paul T. Anastas joined Yale University as Professor and serves as the Director of the Center for Green Chemistry and Green Engineering at Yale. From 2004-2006, Paul Anastas has been the Director of the Green Chemistry Institute in Washington, D.C. Until June of 2004 he served as Assistant Director for Environment at e White House Office of Science and Technology Policy where his responsibilities included a wide range of environmental science issues including furthering international public-private cooperation in areas of Science for Sustainability such as Green Chemistry. In 1991, he established the industry-government-university partnership Green Chemistry Program, which was expanded to include basic research, and the Presidential Green Chemistry Challenge Awards. He has published and edited several books in the field of Green Chemistry and is one of the inventors of the 12 principles of Green Chemistry.

 

Volume Editor

Bob Crabtree took his first degree at Oxford, did his Ph.D. at Sussex and spent four years in Paris at the CNRS. He has been at Yale since 1977. He has chaired the Inorganic Division at ACS, and won the ACS and RSC organometallic chemistry prizes. He is the author of an organometallic textbook, and editor-in-chief of the Encyclopedia of Inorganic Chemistry and Comprehensive Organometallic Chemistry. He has contributed to C-H activation, H2 complexes, dihydrogen bonding, and his homogeneous tritiation and hydrogenation catalyst is in wide use. More recently, he has combined molecular recognition with CH hydroxylation to obtain high selectivity with a biomimetic strategy.