Phenomenology and Thermodynamics
Buch, Englisch, 404 Seiten, Format (B × H): 160 mm x 241 mm, Gewicht: 793 g
ISBN: 978-1-4020-6123-3
Verlag: Springer Netherlands
This book is organized in three levels, such that from level to level the portion and importance of thermodynamics and mathematics are increased. On the first level, the book demonstrates that the basic principles of phase equilibria can be understood without the use of thermodynamics. The intermediate level provides an introduction to thermodynamics and culminates in the Gibbs energy as the arbiter for equilibrium. The third level places emphasis on binary systems, where one or more phases are solutions of the components. It derives explicit relationships between the variables for equilibria involving ideal mixtures and ideal dilute solutions, while non-ideal systems are treated from three different angles: geometrically, analytically, and numerically. Throughout, high priority is given to the thermodynamic assessment of experimental data and numerous end-of-chapter exercises and their solutions are included.
Zielgruppe
Graduate
Autoren/Hrsg.
Fachgebiete
- Naturwissenschaften Physik Thermodynamik
- Naturwissenschaften Physik Angewandte Physik Geophysik
- Naturwissenschaften Chemie Physikalische Chemie
- Geowissenschaften Geologie Geophysik
- Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Technische Thermodynamik
- Geowissenschaften Geologie Geodäsie, Kartographie, Fernerkundung
- Geowissenschaften Geographie | Raumplanung Geodäsie, Kartographie, GIS, Fernerkundung
Weitere Infos & Material
From the contents
level 0: Equilibrium.- The variables.- The rules.- Pure substances.- Binary and Ternary Systems.- Partition and Separation.- Chemical Equilibrium.- level 1: Differential expressions.- Work, heat, energy.- Heat capacity and enthalpy.- Ideal gas, expansion and compression.- Chemical energy.- Entropy.- Characteristic functions.- Gibbs energy and equilibrium.- Tables.- Pure Substances.- Chemical reactions.- level 2: Mixtures and partial quantities.- The open system, chemical potentials.- Change to molar quantities.- The ideal mixture.- Non-ideal behaviour.- Magic formulae.- Dilute solutions.- The solvent laws.- The solute laws.- Ideal equilibria.- Non-ideal systems - geometrically.- Non-Ideal Systems - Analytically.- Non-Ideal Systems - Numerically.