Bunzli Handbook on the Physics and Chemistry of Rare Earths

1. Auflage 2009
ISBN: 978-0-08-093257-6
Verlag: Elsevier Science & Techn.
Format: EPUB
Kopierschutz: 6 - ePub Watermark

E-Book, Englisch, 622 Seiten

This continuing authoritative series deals with the chemistry, materials science, physics and technology of the rare earth elements in an integrated manner. Each chapter is a comprehensive, up-to-date, critical review of a particular segment of the field. The work offers the researcher and graduate student a complete and thorough coverage of this fascinating field.
AuthoritativeComprehensiveUp-to-dateCritical

Autoren/Hrsg.

Bunzli, Jean-Claude

Inhaltsverzeichnis

1;Front Cover;1
2;Handbook on the Physics and Chemistry of Rare Earths;4
3;Copyright Page;5
4;Preface;6
5;Contents;12
6;Contents of Volumes 1-39;14
7;Index of Contents of Volumes 1-40;26
8;Chapter 244: Magnetic Circular Dichroismof Lanthanides;34
8.1;1. Introduction;37
8.2;2. Qualitative Presentation of Magnetic Circular Dichroism (A, B and C terms);41
8.3;3. Quantitative Theoretical Treatment of the Absorption Theory;44
8.4;4. Quantitative Theoretical Treatment of MCD;79
8.5;5. Study Cases;98
8.6;6. The Cubic KY3F10 Crystal: A Special Case;108
8.7;7. Magnetic Circular Dichroism of Lanthanide Perchlorates in Aqueous Solution;112
8.8;8. Calculation of the alpha1/D ratio for the magnetic dipole transition 5D1 larr 7F0 in Eu3+ and its use as a standard;132
8.9;9. Conclusion;136
8.10;Acknowledgments;137
8.11;References;137
9;Chapter 245: Cluster Compounds of Rare-Earth Elements;142
9.1;1. Introduction;145
9.2;2. Clusters Obtained Under Nonhydrolytic Conditions;148
9.3;3. Lanthanide Clusters Obtained Under Hydrolytic Conditions;221
9.4;4. Summary and Outlooks;263
9.5;Acknowledgments;266
9.6;References;267
10;Chapter 246: Molecular Chemistry of the Rare-Earth Elements in Uncommon Low-Valent States;274
10.1;1. Introduction, Scope and Limitations of the Review;275
10.2;2. The Divalent State;277
10.3;3. Scandium Complexes;321
10.4;4. Zero-Valent Complexes;324
10.5;5. Conclusion and Perspectives;328
10.6;References;329
11;Chapter 247: Self-Assembled LanthanideHelicates: From BasicThermodynamics toApplications;334
11.1;1. Introduction;339
11.2;2. Mononuclear 4f Triple-Helical Precursors;355
11.3;3. Polynuclear Homometallic 4f Helicates;398
11.4;4. Polynuclear Bimetallic 4f Helicates;437
11.5;5. Modeling the Thermodynamic Stability of Helicates;456
11.6;6. Helicates as Luminescent Bioprobes;480
11.7;7. Bimetallic Polynuclear nd-4f Helicates;509
11.8;8. 4f- and 5f-Helicates with Other Ligands;559
11.9;9. Conclusions;573
11.10;References;575
12;Author Index;588
13;Subject Index;616