Abe Measurement Techniques and Practices of Colloid and Interface Phenomena

1. Auflage 2019
ISBN: 978-981-13-5931-6
Verlag: Springer Singapore
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 145 Seiten, eBook

This book is a manual of measurement of colloids and interfaces designed especially for new researchers who have just begun research on these topics. The book is written by active researchers in the field of colloids and interfacial chemistry, based on the practical experience of the authors. In each chapter, the key points of measurement, how to analyze data correctly, points to be careful about, and merits of a particular method are concisely explained from the point of view of the readers.  Not only in industries such as cosmetics and pharmaceuticals but also in academic studies of nanotechnology, correct understanding of colloid and interface phenomena is vital because the properties of these items, however small, are affected by the nature of interfaces. This book will be particularly useful for researchers who are not yet fully confident of the measurement techniques that are clearly explained here. 

Masahiko Abe received his PhD degree from the University of Tokyo. He retired from the Faculty of Science and Technology, Tokyo University of Science in 2014, and is now a professor at the Institute for Science and Technology, at the same university. His interests include surfactant sciences, such as synthesis and properties of hybrid surfactant, Gemini surfactant, colloidal assemblies (micro emulsions, emulsions, liposomes, niosoaps, micro capsules, liquid crystals). His current research focuses on applying liposomes in non-DDS fields (upgrading of various polymers) and on glucose fuel batteries. 

Zielgruppe

Graduate

Autoren/Hrsg.

Abe, Masahiko

Inhaltsverzeichnis

1;Foreword for English Translation;5
2;Preface;7
3;Contents;9
4;Chapter 1: Basics of Surface Chemistry;11
4.1;1.1 Introduction;11
4.2;1.2 Definition of Interface;12
4.3;1.3 Interface and Colloid;13
4.4;1.4 Reaction at Interfaces;14
4.5;1.5 Surfaces and Internal Areas;15
4.6;1.6 Fundamentals of Surfactants;15
4.6.1;1.6.1 Classification of Surfactants;15
4.6.2;1.6.2 Solubility of Surfactants;19
4.6.2.1;1.6.2.1 Krafft Point (KP);19
4.6.2.2;1.6.2.2 Cloud Point;20
4.7;References;21
5;Chapter 2: Static Surface Tension;22
5.1;2.1 Introduction;22
5.2;2.2 What You Get;24
5.3;2.3 Method;25
5.4;2.4 Essentials and Tips;25
5.5;2.5 Understanding Your Data;26
5.5.1;2.5.1 Example 1;27
5.6;2.6 What to Look Out for;30
5.7;2.7 Useful Hints;31
5.8;References;31
6;Chapter 3: Dynamic Surface Tension;32
6.1;3.1 Introduction;32
6.2;3.2 What You Get;34
6.3;3.3 Essentials and Tips;34
6.4;3.4 Understanding Your Data;35
6.5;3.5 Useful Hints;35
6.6;References;36
7;Chapter 4: Surface Pressure;37
7.1;4.1 Introduction;37
7.2;4.2 What You Get;38
7.3;4.3 Essentials and Tips;38
7.4;4.4 Understanding Your Data;39
7.5;4.5 What to Look Out for;40
7.6;4.6 Useful Hints;41
8;Chapter 5: Surface Viscosity;42
8.1;5.1 Introduction;42
8.2;5.2 What You Get;43
8.3;5.3 Essentials and Tips;43
8.4;5.4 Understanding Your Data;44
8.5;5.5 Useful Hints;45
8.6;5.6 What to Look Out for;45
9;Chapter 6: Interfacial Tension Between Water and Oil;46
9.1;6.1 Introduction;46
9.2;6.2 What You Get;47
9.3;6.3 Essentials and Tips;47
9.3.1;6.3.1 Wilhelmy Method;47
9.3.2;6.3.2 Pendant Drop Method;48
9.4;6.4 Understanding Your Data;49
9.5;6.5 What to Look Out for;50
9.5.1;6.5.1 Wilhelmy Method;50
9.5.2;6.5.2 Pendant Drop Method;50
9.6;6.6 Useful Hints;51
9.6.1;6.6.1 Wilhelmy Method;51
9.6.2;6.6.2 Pendant Drop Method;51
10;Chapter 7: Quartz Crystal Microbalance with Dissipation Monitoring (QCM-D);52
10.1;7.1 Introduction;52
10.2;7.2 What You Get;54
10.3;7.3 Essentials and Tips;55
10.4;7.4 Understanding Your Data;56
10.5;7.5 Useful Hints;57
10.6;References;57
11;Chapter 8: Atomic Force Microscope (AFM);58
11.1;8.1 Introduction;58
11.2;8.2 What You Get;60
11.3;8.3 Essentials and Tips;60
11.4;8.4 Understanding Your Data;61
11.5;8.5 Useful Hints;63
11.6;References;63
12;Chapter 9: Static Light Scattering (SLS);65
12.1;9.1 Introduction;65
12.2;9.2 What You Get;66
12.3;9.3 Essentials and Tips;66
12.3.1;9.3.1 Debye Plot Method;66
12.3.2;9.3.2 Zimm Plot Method;67
12.3.3;9.3.3 Estimation of Shape and Size;68
12.4;9.4 Understanding Your Data;68
12.5;9.5 Useful Hints;69
13;Chapter 10: Dynamic Light Scattering (DLS);71
13.1;10.1 Introduction;71
13.2;10.2 What You Get;72
13.3;10.3 Essentials and Tips;72
13.4;10.4 Understanding Your Data;73
13.4.1;10.4.1 Quality of Autocorrelation Function Graph;73
13.4.2;10.4.2 Types of Particle Size Distribution;74
13.5;10.5 What to Look Out for;74
13.6;10.6 Useful Hints;74
14;Chapter 11: Solubilization by Micelles;76
14.1;11.1 Introduction;76
14.2;11.2 Solubilization for Nonvolatile Materials;78
14.3;11.3 What to Look Out for;78
14.4;11.4 Solubilization of Volatile Chemicals Such as Fragrances;79
14.4.1;11.4.1 Determination of Solubilization Equilibrium Constant;79
14.5;11.5 Static Headspace Method [7, 8];80
14.6;11.6 Experiment Procedure for the Static Headspace Method;81
14.7;11.7 An Alternative Method to Determine the Solubilization Equilibrium Constant (K);82
14.8;References;83
15;Chapter 12: Rheology;84
15.1;12.1 Introduction;84
15.2;12.2 What You Get;85
15.3;12.3 Steps and Essentials;85
15.3.1;12.3.1 Selection of Viscosity-Measuring Apparatus;86
15.3.2;12.3.2 Search and Importance of Linear Region;86
15.4;12.4 Understanding Your Data;87
15.4.1;12.4.1 Flow Curves;87
15.4.2;12.4.2 Dynamic Viscoelasticity;88
15.5;12.5 Useful Hints;90
15.6;References;90
16;Chapter 13: Freeze-Fracture Transmission Electron Microscopy;91
16.1;13.1 Introduction;91
16.2;13.2 What You Get;92
16.3;13.3 Steps and Essentials;92
16.4;13.4 Understanding Your Data;94
16.5;13.5 Useful Hints;96
16.6;References;96
17;Chapter 14: Cryo-transmission Electron Microscopy;97
17.1;14.1 Introduction;97
17.2;14.2 What You Get;98
17.3;14.3 Steps and Essentials;98
17.4;14.4 Understanding Your Data;101
17.5;14.5 Useful Hints;102
17.6;References;102
18;Chapter 15: Zeta (zeta) Potential for Micelle and Microemulsion;104
18.1;15.1 Introduction;104
18.2;15.2 What Can Be Known from zeta Potential Measurement;104
18.3;15.3 Measurement of Zeta (zeta) Potential;105
18.4;15.4 Important Point for the Measurement;105
18.5;15.5 Basics of Electrical Interface Phenomenon [1];107
18.5.1;15.5.1 Interfacial Electrical Double Layers;107
18.5.2;15.5.2 Relationship Between Surface Electric Potential, (zeta) Potential, and Surface Charge Density;110
18.6;15.6 Calculation of Surface Electric Potential from the Measured Zeta (zeta) Potential;111
18.7;15.7 One-Point Merit for the Determination of Surface Electric Potential;112
18.8;Reference;112
19;Chapter 16: Electron Microscopy Observation of Solid Particles;113
19.1;16.1 Introduction;113
19.2;16.2 What You Get;114
19.2.1;16.2.1 Scanning Electron Microscopy (SEM);114
19.2.2;16.2.2 Transmission Electron Microscopy (TEM);115
19.3;16.3 Essentials and Tips;119
19.4;16.4 Useful Hints;119
19.5;Further Readings;120
19.6;References;120
20;Chapter 17: Gas Adsorption on Surface of Solid Materials;121
20.1;17.1 Introduction;121
20.2;17.2 What You Get;124
20.3;17.3 Essentials and Tips;125
20.4;17.4 Preparation of the Instrument;125
20.5;17.5 Preparation of Sample;125
20.6;17.6 Setting of Parameter;127
20.7;17.7 What to Look Out for;127
20.8;17.8 Understanding Your Data;127
20.9;17.9 Useful Hints;128
20.10;References;128
21;Chapter 18: Contact Angle Measurement for Solid Surface;130
21.1;18.1 Introduction;130
21.2;18.2 Wetting and Immersion;131
21.2.1;18.2.1 Spreading Wetting;131
21.2.2;18.2.2 Immersional Wetting;132
21.2.3;18.2.3 Adhesional Wetting;132
21.3;18.3 Measurement of the Contact Angle;133
21.3.1;18.3.1 ?/2 Method;133
21.3.2;18.3.2 Tangent Line Method;133
21.4;18.4 Determination of Critical Surface Tension;134
21.5;References;136
22;Chapter 19: Quality and Treatment of Water for Experiment Use;137
22.1;19.1 Impurity of Water for Experiment Use;137
22.2;19.2 Importance of the Quality of Water Used in Experiments;138
22.3;19.3 Types of Water Appropriate for Experiments;141
22.4;References;145

1. Basics of Surface Chemistry.- 2. Static Surface Tension.- 3. Dynamic Surface Tension.- 4. Surface Pressure.- 5. Surface Viscosity.- 6. Interfacial Tension between Water and Oils.- 7. Quartz Crystal Microbalance with Dissipation monitoring (QCM-D).- 8. Atomic Force Microscope (AFM).- 9. Static Light Scattering (SLS).- 10. Dynamic Light Scattering (DLS).- 11. Solubilization by Micelle.- 12. Rheology.- 13. Freeze-Fracture Transmission Electron Microscopy.- 14. Cryo-Transmission Electron Microscopy.- 15. Zeta(?)-potential for Micelle and Microemulsion.- 16. Electron Microscopy Observation of Solid Particles.- 17. Gas Adsorption on Surface of Solid Materials.- 18. Contact Angle Measurement for Solid Surface.- 19. Quality and treatment of water for experiment.

Über Autor(innen)

Masahiko Abe received his PhD degree from the University of Tokyo. He retired from the Faculty of Science and Technology, Tokyo University of Science in 2014, and is now a professor at the Institute for Science and Technology, at the same university. His interests include surfactant sciences, such as synthesis and properties of hybrid surfactant, Gemini surfactant, colloidal assemblies (micro emulsions, emulsions, liposomes, niosoaps, micro capsules, liquid crystals). His current research focuses on applying liposomes in non-DDS fields (upgrading of various polymers) and on glucose fuel batteries.